Materials Data on Mn(BMo)2 by Materials Project
Mn(MoB)2 crystallizes in the tetragonal P4/mbm space group. The structure is three-dimensional. Mo2+ is bonded in a distorted hexagonal planar geometry to six equivalent B3- atoms. There are two shorter (2.32 Å) and four longer (2.33 Å) Mo–B bond lengths. Mn2+ is bonded in a square co-planar geometry to four equivalent B3- atoms. All Mn–B bond lengths are 2.33 Å. B3- is bonded in a 9-coordinate geometry to six equivalent Mo2+, two equivalent Mn2+, and one B3- atom. The B–B bond length is 1.87 Å.