MgPd 2 Sb : A Mg-based Heusler-type superconductor
Here, we report the synthesis and physical properties of a full Heusler compound, MgPd 2 Sb, which we found to show superconductivity below T c = 2.2 K . MgPd 2 Sb was obtained by a two-step solid-state reaction method and its purity and cubic crystal structure [Fm-3m, a = 6.4523(1) Å ] were confirmed by powder x-ray diffraction. Normal and superconducting states were studied by electrical resistivity, magnetic susceptibility, and heat capacity measurements. The results show that MgPd 2 Sb is a type-II, weak coupling superconductor ( λ e-p = 0.53 ). The observed pressure dependence of T c (ΔT c /p ≈ -0.23 K / GPa ) is one of the strongest reported for a superconducting Heusler compound. The electronic structure, phonons, and electron-phonon coupling in MgPd 2 Sb were theoretically investigated. The obtained results are in agreement with the experiment, confirming the electron-phonon coupling mechanism of superconductivity. We compare the superconducting parameters to those of all reported Heusler-type superconductors.