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Mg(H2O)6(H2PO2)2 crystallizes in the tetragonal I4_1/acd space group. The structure is zero-dimensional and consists of sixteen 6303-21-5 molecules and eight magnesium;hexahydrate molecules.
Mg(H2O)6(H2PO2)2 crystallizes in the tetragonal P4_2/nmc space group. The structure is zero-dimensional and consists of four 6303-21-5 molecules and two magnesium;hexahydrate molecules.