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Materials Data on Mg(RhO2)2 by Materials Project

MgRh2O4 is Spinel structured and crystallizes in the cubic Fd-3m space group. The structure is three-dimensional. Mg2+ is bonded to four equivalent O2- atoms to form MgO4 tetrahedra that share corners with twelve equivalent RhO6 octahedra. The corner-sharing octahedral tilt angles are 58°. All Mg–O bond lengths are 2.03 Å. Rh3+ is bonded to six equivalent O2- atoms to form RhO6 octahedra that share corners with six equivalent MgO4 tetrahedra and edges with six equivalent RhO6 octahedra. All Rh–O bond lengths are 2.08 Å. O2- is bonded to one Mg2+ and three equivalent Rh3+ atoms to form a mixture of distorted edge and corner-sharing OMgRh3 trigonal pyramids.

36 MATERIALS SCIENCE↗