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Results for “Marcus equation”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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18 records
All sourcesNASA NTRSDOE OSTI
NASA NTRS2007

Pressure and Temperature Dependence of the Reaction of Vinyl Radical with Ethylene

This work reports measurements of absolute rate coefficients and Rice-Ramsperger-Kassel-Marcus (RRKM) master equation simulations of the C2H3 + C2H4 reaction. Direct kinetic studies were performed over a temperature range of 300-700 K and pressures of 20 and 133 mbar. Vinyl radicals (H2C=CH) were generated by laser photolysis of vinyl iodide (C2H31) at 266 nm, and time-resolved absorption spectroscopy was used to probe vinyl radicals through absorption at 423.2 nm. Measurements at 20 mbar are in good agreement with previous determinations at higher temperature. A weighted three-parameter Arrhenius fit to the experimental rate constant at 133 mbar, with the temperature exponent fixed, gives k = (7 +/- 1) x 10(exp -l4) cu cm/molecule/s (T/298 K)(exp 2) exp[-(1430 +/- 70) K/T]. RRKM master equation simulations, based on G3 calculations of stationary points on the C4H7 potential energy surface, were carried out to predict rate coefficients and product branching fractions. The predicted branching to 1-methylallyl product is relatively small under the conditions of the present experiments but increases as the pressure is lowered. Analysis of end products of 248 nm photolysis of vinyl iodide/ethylene mixtures at total pressures between 27 and 933 mbar provides no direct evidence for participation of I -methylallyl.

Ismail, Huzeifa↗
NASA NTRS2017

Reachability Subspace Exploration Using Continuation Methods

Reachability manifold computation suffers from the curse of dimensionality and for large state spaces is computationally intractable. This paper examines the use of continuation methods to address this issue by formulating the reachability sub-space manifold calculation into a number of initial valued problems. As a result of computing the reachability manifold for a subspace of interest, an exponential improvement in computational cost occurs. This concept is applied to a position subspace reachability problem of a spacecraft in a Keplerian orbit under maximum thrust constraints. Future work includes a comparison of the proposed method with computing reachability manifolds using viscosity solutions of the Hamilton Jacobi Bellman partial differential equation.

orbital mechanics↗
NASA NTRS1973

Space shuttle GN and C equation document: Entry and transition guidance

The entry-guidance routine presented is designed to take the orbiter vehicle from entry interface through the critical heating phase of entry down to the start of the approach phase. The material includes: (1) a functional flow diagram, (2) input and output variables, (3) a description of equations, and (4) detailed flow diagrams.

Marcus, F. J.↗
NASA NTRS1981

Effects of truncation in modal representations of thermal convection

The Galerkin equations for convection in a sphere are examined to determine which physical processes are neglected by the severe truncation of the equations of motion. It is demonstrated that the gross features of the flow are affected by truncation in the horizontal direction, with all of the models considered being well resolved in the vertical direction. One of the effects of truncation is to enhance the high-wave number end of the kinetic energy and thermal variance spectra. The examples cited indicate that as long as the kinetic energy spectrum decreases with wave number, a truncation gives a qualitatively correct solution. Conclusions are tested by calculating solutions to the equations of motion for several values of the Rayleigh number and the limit of horizontal spatial resolution.

Marcus, P. S.↗
NASA NTRS1975

Estimation and Analysis of Nonlinear Stochastic Systems

The algebraic and geometric structures of certain classes of nonlinear stochastic systems were exploited in order to obtain useful stability and estimation results. The class of bilinear stochastic systems (or linear systems with multiplicative noise) was discussed. The stochastic stability of bilinear systems driven by colored noise was considered. Approximate methods for obtaining sufficient conditions for the stochastic stability of bilinear systems evolving on general Lie groups were discussed. Two classes of estimation problems involving bilinear systems were considered. It was proved that, for systems described by certain types of Volterra series expansions or by certain bilinear equations evolving on nilpotent or solvable Lie groups, the optimal conditional mean estimator consists of a finite dimensional nonlinear set of equations. The theory of harmonic analysis was used to derive suboptimal estimators for bilinear systems driven by white noise which evolve on compact Lie groups or homogeneous spaces.

Marcus, S. I.↗
NASA NTRS1976

Analysis of bilinear noise models in circuits and devices

There are a number of applications in which linear noise models are inappropriate. In the paper, the use of bilinear noise models in circuits and devices is considered. Several physical problems are studied in this framework. These include circuits involving varying parameters (such as variable resistance circuits constructed using field-effect transistors), the effect of switching jitter on sampled data system performance and communication systems involving voltage-controlled oscillators and phase-lock loops. In addition, several types of analytical techniques for stochastic bilinear systems are considered. Specifically, the moment equations of Brockett for bilinear systems driven by white noise are discussed, and closed-form expressions for certain bilinear systems (those that evolve an Abelian or solvable Lie groups) driven by white or colored noise are derived. In addition, an approximate statistical technique involving the use of harmonic expansions is described.

Willsky, A. S.↗
NASA NTRS1979

Stellar convection 2: A multi-mode numerical solution for convection in spheres

The convective flow of a self gravitating sphere of Boussinesq fluid for small Reynolds and Peclet numbers is numerically determined. The decomposition of the equations of motion into modes is reviewed and a relaxation method is developed and presented to compute the solutions to these equations. The stable equilibrium flow for a Rayleigh number of 10 to the 4th power and a Prandtl number of 10 is determined. The 2 and 3 dimensional spectra of the kinetic and thermal energies and the convective flux as a function of wavelengths are calculated in terms of modes. The anisotropy of the flow as a function of wavelength is defined.

Marcus, P. S.↗
NASA NTRS1977

Finite element solutions of free surface flows

A procedure is presented for using NASTRAN to determine the flow field about arbitrarily shaped bodies in the presence of a free surface. The fundamental unknown of the problem is the velocity potential which must satisfy Laplace's equation in the fluid region. Boundary conditions on the free surface may involve second order derivatives in space and time. In cases involving infinite domains either a tractable radiation condition is applied at a truncated boundary or a series expansion is used and matched to the local finite elements. Solutions are presented for harmonic, transient, and steady state problems and compared to either exact solutions or other numerical solutions.

Zarda, P. R.↗
NASA NTRS1979

Effects of truncation in modal representations of thermal convection

The Galerkin (including single-mode and Lorenz) equations were examined for convection in a sphere to determine which physical processes are neglected when the equations of motion are truncated too severely. The conclusions were tested by calculating solutions to the equations of motion for different values of the Rayleigh number and for different values of the limit of the horizontal spatial resolution. It was shown that the transitions from steady state to periodic, then to aperiodic convection depend not only on the Rayleigh number but also very strongly on the horizontal resolution. One of the effects of truncation is to enhance the high wavenumber end of the kinetic energy and thermal variance spectra. The numerical examples indicate that as long as the kinetic energy spectrum decreases with wavenumber, a truncation gives a qualitatively correct solution.

Marcus, P. S.↗
NASA NTRS2001

Modulation of the seasonal cycle in length-of-day and atmospheric angular momentum

Global warming, by definition, changes the atmospheric temperature field. This temperature change is not expected to be uniform, either geographically, or with height in the atmosphere. By the thermal wind equation. changes in the pole-to-equator temperature gradient will cause changes in the atmospheric zonal winds. Numerous previous studies have shown that observed length-of-day (LOD) variations on time scales of a few days to a few years are largely caused by atmospheric zonal wind fluctuations. In particular, seasonal variations in LOD have been previously shown to be dominantly caused by seasonal variations in the atmospheric zonal winds. Here, observed changes in the strength of seasonal LOD and wind-driven atmospheric angular momentum signals during 1962 to 2000 are analyzed and shown to be significantly correlated with each other and with the Southern Oscillation Index.

length of day↗
NASA NTRS2003

Coherent interannual and decadal variations inthe atmosphere-ocean system

We investigate the source of poleward propagating atmospheric zonal wind anomalies, originating at the equator and penetrating to high latitudes in both hemispheres in conjunction with ENSO [Dickey et al.,1992], and report the discovery of similar variability on decadal and longer timescales. Since atmospheric dissipation times are generally on the order of a month or less, we examine the ocean as a 'memory' source for these globally coherent anomalies. This hypothesis is substantiated by the observation of complementaryoscillation in the sea surface temperature (SST) field; further, we detect a robust decadal variability (~1012 yrs)in both the SST and contemporaneous atmospheric angular momentum (AAM) series. Analyzing GISST SST data beginning in 1902, we confirm this decadal mode and find signatures of longer (multidecadal) SST variability centered in the equatorial and North Pacific.

coherent decadal meridional↗
NASA NTRS1995

Local multiplicative Schwarz algorithms for convection-diffusion equations

We develop a new class of overlapping Schwarz type algorithms for solving scalar convection-diffusion equations discretized by finite element or finite difference methods. The preconditioners consist of two components, namely, the usual two-level additive Schwarz preconditioner and the sum of some quadratic terms constructed by using products of ordered neighboring subdomain preconditioners. The ordering of the subdomain preconditioners is determined by considering the direction of the flow. We prove that the algorithms are optimal in the sense that the convergence rates are independent of the mesh size, as well as the number of subdomains. We show by numerical examples that the new algorithms are less sensitive to the direction of the flow than either the classical multiplicative Schwarz algorithms, and converge faster than the additive Schwarz algorithms. Thus, the new algorithms are more suitable for fluid flow applications than the classical additive or multiplicative Schwarz algorithms.

Cai, Xiao-Chuan↗
NASA NTRS2022

Validation of a High-Fidelity Supersonic Parachute Inflation Dynamics Model and Best Practice

The parachute inflation dynamics (PID) of a Disk-Gap-Band (DGB) parachute system travelling at supersonic velocities in the high-altitude Earth atmosphere is simulated using a high-fidelity, multiphysics, massively-parallel computational framework. The sensitivity of the simulation results with respect to critical modelling and simulation parameters, including the fluid mechanical governing equations (Euler vs Navier-Stokes with RANS turbulence closure vs Navier-Stokes with LES turbulence closer), the interaction between the flow and the suspension lines (accounted for vs not accounted for), the dynamics of the payload (restrained vs free), and the material model of the heterogeneous fabric canopy (Saint-Venant Kirchoff vs mechanics-informed multiscale neural network), is extensively investigated. The parameter investigation is enabled by advancements to the state-of-the-art in the modelling and simulation of the supersonic parachute inflation process, which are presented as part of the computational framework. The predictive quality of the computational framework in the context of supersonic PID is validated by comparison of the simulation results with the experimental results from NASA’s Advanced Supersonic Parachute Research (ASPIRE) project. Through the validation, best practices for the modelling and simulation of supersonic PID are developed and proposed.

Rabinovitch, Jason↗