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Evaluation of Low-Energy Hydrogen Separation Method Using Metal-Organic Frameworks (MOFs) for Closed-Loop ECLSS Air Revitalization (CLEAR)

The State-of-the-Art (SOA) air revitalization architecture onboard the International Space Station (ISS) recovered approximately 50% of the oxygen (O 2 ) from metabolic carbon dioxide (CO 2 ) via the Sabatier process from 2011 to 2017. O 2 recovery is currently constrained by the limited availability of reactant hydrogen (H 2 ) preventing complete conversion of CO 2 to H 2 O. Increasing O 2 recovery within Closed-Loop ECLSS is essential to reducing resupply mass for long-duration manned missions; specifically focusing on water (H 2 O) which supplies H 2 for Sabatier via water electrolysis. Past ground test endeavors at Marshall Space Flight Center (MSFC) have attempted to recover H 2 from Sabatier-produced CH 4 using technologies such as carbon vapor deposition (CVD) and plasma pyrolysis. The byproducts of these technologies can act as a catalyst poison or reactor deadload to the Sabatier reactor. Hydrogen separation techniques must be utilized to maintain the Sabatier catalyst during gas recycling and must be scalable, non-energy intensive, and safe to operate in a habitation setting. Research indicated that metal-organic frameworks (MOFs) could meet these criteria and were tested for their capability to capture the various carbon-based gaseous products of CVD and plasma pyrolysis such as acetylene (C 2 H 2 ), ethylene (C 2 H 4 ), ethane (C 2 H 6 ), and carbon monoxide (CO) which would purify the hydrogen gas stream passing through the MOF. A sub-scale adsorption column was developed by Marshall Space Flight Center to test three MOF candidates against a synthetic gas mixture comprised of process-relevant carbonous gases and hydrogen to evaluate the separation capability of the MOFs. The results of the hydrogen separation capability, isothermal desorption capability, and demonstrated cyclic reuse of the MOF are presented in this paper.

Kagen Crawford

Acquisition and Reduction Procedures for MOF Doppler-Magnetograms

Defects in the first magneto-optical filter (MOF) magnetograms, particularly the problem of the apparent contamination between velocity and magnetic fields, are discussed. It is found that a correct acquisition and reduction procedure gives cleaner results. A vector magnetograph is suggested. The vector field at coronal levels is calculated, using one MOF longitudinal magnetogram.

Cacciani, Alessandro

Metal Hydrides, MOFs, and Carbon Composites as Space Radiation Shielding Mitigators

Recently, metal hydrides and MOFs (Metal-Organic Framework/microporous organic polymer composites - for their hydrogen and methane storage capabilities) have been studied with applications in fuel cell technology. We have investigated a dual-use of these materials and carbon composites (CNT-HDPE) to include space radiation shielding mitigation. In this paper we present the results of a detailed study where we have analyzed 64 materials. We used the Band fit spectra for the combined 19-24 October 1989 solar proton events as the input source term radiation environment. These computational analyses were performed with the NASA high energy particle transport/dose code HZETRN. Through this analysis we have identified several of the materials that have excellent radiation shielding properties and the details of this analysis will be discussed further in the paper.

Atwell, William

Applications of the magneto-optical filter to stellar pulsation measurements

A proposed method of employing the Cacciani magneto-optical filter (MOF) for stellar seismology studies is described. The method relies on the fact that the separation of the filter bandpasses in the MOF can be changed by varying the level of input power to the filter cells. With the use of a simple servosystem the bandpass of a MOF can be tuned to compensate for the changes in the radial velocity of a star introduced by the orbital motion of the Earth. Such a tuned filter can then be used to record intensity fluctuations through the MOF bandpass over an extended period of time for each given star. Also, the use of a two cell version of the MOF makes it possible to alternately chop between the bandpass located in the stellar line wing and a second bandpass located in the stellar continuum. Rapid interchange between the two channels makes it possible for atmospheric-introduced noise to be removed from the time series.

Rhodes, E. J., Jr.

Applications of the magneto-optical filter to stellar pulsation measurements

A proposed method of employing the Cacciani magneto-optical filter (MOF) for stellar seismology studies is described. The method relies on the fact that the separation of the filter bandpasses in the MOF can be changed by varying the level of input power to the filter cells. With the use of a simple servosystem the bandpass of a MOF can be tuned to compensate for the changes in the radial velocity of a star introduced by the orbital motion of the earth. Such a tuned filter can then be used to record intensity fluctuations through the MOF bandpass over an extended period of time for each given star. Also, the use of a two cell version of the MOF makes it possible to alternately chop between the bandpass located in the stellar line wing and a second bandpass located in the stellar continuum. Rapid interchange between the two channels makes it possible for atmospheric-introduced noise to be removed from the time series.

Rhodes, Edward J., Jr.

Full-disk magnetograms obtained with a Na magneto-optical filter at the Mount Wilson Observatory

The first full-disk magnetograms to be obtained with the Na magneto-optical filter (MOF) which is located at the 60 foot solar tower of the Mount Wilson Observatory are presented. This MOF was employed as a longitudinal magnetograph on June 18, 19, and July 1, 1987. On those three days the MOF was combined with a large format (1024 x 1024 pixel) virtual phase change coupled device camera and a high-speed data acquisition system. The combined system was used to record both line-of-sight magnetograms and Dopplergrams which covered the entire visible solar hemisphere. The pixel size of these magnetograms and Dopplergrams was 2.3 arcseconds. On each of the three days a time series of nine pairs of magnetograms and Dopplergrams was obtained at the rate of one pair every two minutes. On the same three day longitudinal magnetograms have one arcsecond pixels were obtained with the vacuum telescope at Kitt Peak. The MOF and vacuum tower magnetograms were compared at both the JPL Multi-Mission Image Processing Laboratory and at USC and have found the two sets of images to be well correlated both in spatial distribution and strength of the measured magnetic field. The simultaneously-obtained MOF Dopplergrams to remove the crosstalk which was present between the Doppler and Zeeman shifts of the NaD lines from the magnetograms from all three days and will also describe recent improvements to the system which allowed the obtaining of full-disk magnetograms as rapidly as one every 25 seconds.

Rhodes, Edward J., Jr.

Integrated Solar Disk Oscillation Measurements Using the Magneto-Optical Filter: Tests with a Two Station Network

The magneto-optical filter (MOF) was used to get high and intermediate l-modes of solar oscillations. For very low l-modes the imaging capability of the MOF is still attractive since it allows a pixel by pixel intensity normalization. However, a crude attempt to get very low l power spectra from Dopplergrams obtained at Mt. Wilson gave noisy results. This means that a careful analysis of all the factors potentially affecting high resolution Dopplergrams should be accomplished. In order to better investigate this problem, a nonimaging channel using the lock-in amplifier technique was considered. Two systems are now operational, one at JPL and the other at University of Rome. Observations in progress are used to discuss the MOF stability, the noise level, and the possible application in asteroseismology.

Cacciani, Alessandro

Preparation of a second station for the measurement of solar oscillations of low degree 'l'

An observing station to detect low-degree global solar oscillations is already operational at the Jet Propulsion Laboratory. A second station for continuative measurements of such oscillations has recently been installed and successfully tested in Rome. The high transmission and stability of the magneto-optical filter (MOF) coupled with the lock-in amplifier technique allow analog and real-time detection of oscillation modes with a noise level of only a few cm/s. Observing runs and estimates of the signal-to-noise ratio are shown in time and frequency domains. Routine observations will establish whether the MOF sensitivity and stability are suitable for the detection of stellar oscillations.

Cacciani, A.

Manned orbital facility: A user's guide

The salient conceptual features and expected evolution of the facility are discussed; the baseline design is offered as a model against which the reader can compare his needs. The overall program is discussed, supporting services and resources are described, and examples of typical payload applications are given. The general design features and configurations representing the baseline MOF developed and derived with due consideration given to applicable designs and subsystems such as those available in the Skylab, orbiter, and space lab vehicles.

Source record

Development of the instruments for the Gamma Ray Observatory

The Gamma Ray Observatory (GRO) is to be launched in 1988 by the STS. The GRO will feature four very large instruments: the Oriented Scintillation Spectrometer Experiment (OSSE), the Imaging Compton Telescope (COMPTEL), the Energetic Gamma Ray Experiment Telescope (EGRET) and the Burst and Transient Source Experiment (BATSE). The instruments weigh from 900-1200 kg each, and required the development of specialized lifting and dolly devices to permit their assembly, manipulation and testing. The GRO is intended a{s a tool for studying discrete celestial objects such as black holes, neutron stars and other gamma-ray emitting objects, scanning for nucleosynthesis processes, mapping the Galaxy and other, high energy galaxies in terms of gamma rays, searching for cosmological effects and observing gamma ray bursts. The instruments will be sensitive from the upper end mof X-rya wavelengths to the highest energies possible. Details of the hardware and performance specifications of each of the instruments are discussed.

Madden, J. J.

Dictionary Approaches to Image Compression and Reconstruction

This paper proposes using a collection of parameterized waveforms, known as a dictionary, for the purpose of medical image compression. These waveforms, denoted as lambda, are discrete time signals, where y represents the dictionary index. A dictionary with a collection of these waveforms Is typically complete or over complete. Given such a dictionary, the goal is to obtain a representation Image based on the dictionary. We examine the effectiveness of applying Basis Pursuit (BP), Best Orthogonal Basis (BOB), Matching Pursuits (MP), and the Method of Frames (MOF) methods for the compression of digitized radiological images with a wavelet-packet dictionary. The performance of these algorithms is studied for medical images with and without additive noise.

Ziyad, Nigel A.

Dictionary Approaches to Image Compression and Reconstruction

This paper proposes using a collection of parameterized waveforms, known as a dictionary, for the purpose of medical image compression. These waveforms, denoted as phi(sub gamma), are discrete time signals, where gamma represents the dictionary index. A dictionary with a collection of these waveforms is typically complete or overcomplete. Given such a dictionary, the goal is to obtain a representation image based on the dictionary. We examine the effectiveness of applying Basis Pursuit (BP), Best Orthogonal Basis (BOB), Matching Pursuits (MP), and the Method of Frames (MOF) methods for the compression of digitized radiological images with a wavelet-packet dictionary. The performance of these algorithms is studied for medical images with and without additive noise.

Ziyad, Nigel A.

Getting a Cohesive Answer from a Common Start: Scalable Multidisciplinary Analysis through Transformation of a Systems Model

One of the challenges of systems engineering is in working multidisciplinary problems in a cohesive manner. When planning analysis of these problems, system engineers must trade between time and cost for analysis quality and quantity. The quality often correlates with greater run time in multidisciplinary models and the quantity is associated with the number of alternatives that can be analyzed. The trade-off is due to the resource intensive process of creating a cohesive multidisciplinary systems model and analysis. Furthermore, reuse or extension of the models used in one stage of a product life cycle for another is a major challenge. Recent developments have enabled a much less resource-intensive and more rigorous approach than hand-written translation scripts between multi-disciplinary models and their analyses. The key is to work from a core systems model defined in a MOF-based language such as SysML and in leveraging the emerging tool ecosystem, such as Query/View/Transformation (QVT), from the OMG community. SysML was designed to model multidisciplinary systems. The QVT standard was designed to transform SysML models into other models, including those leveraged by engineering analyses. The Europa Habitability Mission (EHM) team has begun to exploit these capabilities. In one case, a Matlab/Simulink model is generated on the fly from a system description for power analysis written in SysML. In a more general case, symbolic analysis (supported by Wolfram Mathematica) is coordinated by data objects transformed from the systems model, enabling extremely flexible and powerful design exploration and analytical investigations of expected system performance.

Operational QVT

Analyses Made to Order: Using Transformation to Rapidly Configure a Multidisciplinary Environment

Aerospace problems are highly multidisciplinary. Four or more major disciplines are involved in analyzing any particular vehicle. Moreover, the choice of implementation technology of various subsystems can lead to a change of leading domain or reformation of the driving equations. An excellent example is the change of expertise required to consider aircraft built from composite or metallic structures, or those propelled by chemical or electrical thrusters. Another example is in the major reconfiguration of handling and stability equations with different control surface configuration (e.g., canards, t-tail v four-post tail). Combinatorial problems are also commonplace anytime that a major system is to be designed. If there are only 5 attributes of a design to consider with 4 different options, this is already 1024 options. Adding just 5 more dimensions to the study explodes the space to over one million. Even generous assumptions like the idea that only 10% of the combinations are physically feasible can only contain the problem for so long. To make matters worse, the simple number of combinations is only the beginning. Combining the issue of trade space size with the need to reformulate the design problem for many of the possibilities makes life exponentially more difficult. Advances in software modeling approaches have led to the development of model-driven architecture. This approach uses the transformation of models into inferred models (e.g. inferred execution traces from state machines) or the skeletons for code generation. When the emphasis on transformation is applied to aerospace, it becomes possible to exploit redundancy in the information specified in multiple domain models into a unified system model. F1urther, it becomes possible to overcome the combinatorial nature of specifying integrated system behavior by manually combining the equations governing a given component technology. Transformations from a system specification combined with a system-analysis mapping specification enable one-click combination of domain analyses. This is a flexibility that has been missing from many engineering codes, which often entangle design specification and physical examination much more than is required to conduct the analysis. This capability has been investigated and cultivated within the DARPA F6 program by a team of JPL and Phoenix Integration engineers building the Adapatable Systems Design and Analysis (ASDA) framework. By embracing system modeling with SysML and the Query-View-Transformation (QVT) language, the ASDA team has been able to build a flexible, easily reconfigurable framework for building up and solving large tradespaces. Examples of application and lessons learned in building the framework will be described in this paper. In addition, the motivation will be laid for various tool vendors to develop open model description standards while being able to maintain competitive advantage through proprietary algorithms and approaches. These standards will also be compared to the underpinnings of model-driven architecture and the OMG standards of the Meta-Object Facility (MOF), SysML, and QVT.

Cole, Bjorn

Getting a Cohesive Answer from a Common Start: Scalable Multidisciplinary Analysis through Transformation of a System Model

One of the challenges of systems engineering is in working multidisciplinary problems in a cohesive manner. When planning analysis of these problems, system engineers must tradeoff time and cost for analysis quality and quantity. The quality is associated with the fidelity of the multidisciplinary models and the quantity is associated with the design space that can be analyzed. The tradeoff is due to the resource intensive process of creating a cohesive multidisciplinary system model and analysis. Furthermore, reuse or extension of the models used in one stage of a product life cycle for another is a major challenge. Recent developments have enabled a much less resource-intensive and more rigorous approach than handwritten translation scripts or codes of multidisciplinary models and their analyses. The key is to work from a core system model defined in a MOF-based language such as SysML and in leveraging the emerging tool ecosystem, such as Query-View- Transform (QVT), from the OMG community. SysML was designed to model multidisciplinary systems and analyses. The QVT standard was designed to transform SysML models. The Europa Hability Mission (EHM) team has begun to exploit these capabilities. In one case, a Matlab/Simulink model is generated on the fly from a system description for power analysis written in SysML. In a more general case, a symbolic mathematical framework (supported by Wolfram Mathematica) is coordinated by data objects transformed from the system model, enabling extremely flexible and powerful tradespace exploration and analytical investigations of expected system performance.

Cole, Bjorn