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Rotational excitation and de-excitation of magnesium mono-sulphide (MgS) by He collisions

ABSTRACT Magnesium mono-sulphide (MgS) plays a crucial role in astrochemical processes, particularly in the interstellar medium (ISM), where metal-sulphur chemistry influences molecular formation and evolution. This work presents a detailed study of the rotational excitation and de-excitation of MgS through collisions with helium (He) atoms, the second most abundant species in the ISM after hydrogen, which includes both atomic (H) and molecular forms (H2). The focus on MgS–He collisions arises from He's high abundance, chemical inertness, and simpler electronic structure, which make it well suited for quantum scattering calculations. These characteristics establish He as an ideal candidate for initial studies, providing fundamental data for future investigations involving H2. The study uses quantum scattering methods to calculate the collisional rate coefficients over a broad temperature range. These rates are critical for interpreting observational data on MgS and predicting its abundance in space. The interaction potential between MgS and He is calculated using the rigid rotor approximation and the Jacobi coordinate system, employing the CCSD(T)-F12a/aug-cc-pVTZ method for accurate two-dimensional potential energy surface. The study explores the anisotropic nature of the MgS–He interaction, which favours odd Δj rotational transitions at low collision energies. The inelastic cross-sections for rotational transitions involving up to 16 rotational levels of MgS were computed up to 1000 cm−1, enabling the calculation of rate coefficients up to 150 K for Δj = ±1, ±2, and ± 3 rotational transitions. The results show that Δj = 1 transitions dominate at low temperatures, while Δj = 2 transitions become more significant at higher temperatures. This study provides valuable data for interpreting future astrophysical observations of MgS. The findings also propose new rotational transitions for MgS detection in space, enhancing our ability to track and study this molecule in various cosmic environments.

Hendaoui, Hamza (ORCID:0000000218641872)

Relative Sputtering Rates of FeS, MgS, and Mg Silicates: Implications for ISM Gas Phase Depletions of Rock-Forming Elements

Astronomical measurements of S abundances in the diffuse interstellar medium (ISM) indicate ionized S is a dominant species with little (< 5%) S residing in grains (e.g. Jenkins 2009). This is an enigmatic result, given that abundant Fe-sulfide grains are observed in dust around pre- and post-main sequence stars and are also observed as major components of primitive meteoritic and cometary samples. These disparate observations suggest that the lifetime of sulfide grains in the ISM is short because of destruction processes. Our previous work has shown that FeS and MgS retain their crystallinity and do not amorphize during radiation processing, whereas enstatite and forsterite are readily amorphized. We have extended this study to measure the relative sputtering rates of FeS and MgS compared to enstatite and forsterite. Irradiation of FeS with 4 keV He+ results in preferential sputtering of S and the formation of a thin 2-3 nm, compact Fe metal layer that armors the surface. The zone of S loss extends to a depth of ~8-10 nm below the exposed surface. Despite this S loss, the FeS retains its crystallinity and shows no sign of incipient amorphization. Irradiation of FeS with 5kV Ga+ in a focused ion beam (FIB) instrument resulted in preferential sputtering of S and the formation of a 5-8-nm thick surface layer of nanophase Fe metal. X-ray mapping shows that the zone of S sputtering extends to a depth of nearly 20 nm, but there is no evidence for FeS amorphization, consistent with our previous work. The irradiation experiments show that the relative sputtering rate of FeS and MgS are much higher than olivine or enstatite. Sputtering experiments utilizing 30 kV and 5 kV Ga ions in the FIB produced volume loss in troilite that was ~4X greater than in enstatite or forsterite. The sputter yield under these conditions is such that for every Si atom sputtered from enstatite, ~14 S atoms are sputtered from FeS. We have performed similar sputtering experiments on Fe-bearing niningerite (MgS) and co-existing enstatite from the ALH 84170 EH3 chondrite. MgS also sputters much more rapidly than enstatite with a relative Si:S sputter yield of 1:8. For MgS, sulfur is highly depleted at the surface and the S-depletion zone extends to a depth of ~15 nm (using 5 kV Ga+). There is a corresponding zone of Mg and especially Fe enrichment that extends from 5 to ~10 nm below the surface, respectively. The dominant grain destruction mechanism in the ISM is sputtering from passage of supernova-generated shock waves. This process also results in the amorphization of crystalline silicates in the ISM. Our results indicate that FeS and MgS grains produced in evolved stars and injected into the ISM will be destroyed more rapidly than crystalline silicates. This process may account for the lack of significant depletion of S from the gas phase in the ISM. However, rare nanophase FeS grains occur as inclusions in circumstellar amorphous silicate grains found in comet dust particles analyzed in the laboratory. These results show that a finite amount of S in the ISM is sequestered in solid grains.

SPUTTERING RATES

Gravity Field Mapping of Mars with MGS

Tracking of the MGS spacecraft in orbit at Mars by the Deep Space Network since last September has provided doppler and range measurements that are being used to improve the model of the Mars gravity field. During most of October 1997, April 1998, and June thru August 1998 high quality tracking data were obtained while the periapse was in the northern hemisphere at altitudes in the 170 to 190 km range. The eccentric orbit had a period of about 11.5 hrs and an inclination of about 96.2 degrees so that low altitude tracking was obtained over most of the northern hemisphere, including the north polar icecap. Data from the earlier Mariner 9 and Viking missions have been added to the MGS data and a series of experimental gravity models developed from the combined datasets. These models have generally been of degree and order 70 and are a significant improvement over earlier models that did not include the MGS data. Gravity anomalies over the north polar cap region of Mars are generally less than 50 to 100 mgals and show no obvious correlation with the topography. Successive MGS orbits derived using these new models are showing agreement at the 100 meter level, and this has been confirmed with the laser altimeter (MOLA) on MGS These comparisons are expected to improve significantly as more tracking data get included in the solution and the MGS orbit becomes more circular giving a more balanced geographical distribution of data at low altitude. This will happen early in 1999 as the orbit approaches the mapping configuration of a circular orbit at about 400 Km.

Smith, David E.

Accelerated Adaptive MGS Phase Retrieval

The Modified Gerchberg-Saxton (MGS) algorithm is an image-based wavefront-sensing method that can turn any science instrument focal plane into a wavefront sensor. MGS characterizes optical systems by estimating the wavefront errors in the exit pupil using only intensity images of a star or other point source of light. This innovative implementation of MGS significantly accelerates the MGS phase retrieval algorithm by using stream-processing hardware on conventional graphics cards. Stream processing is a relatively new, yet powerful, paradigm to allow parallel processing of certain applications that apply single instructions to multiple data (SIMD). These stream processors are designed specifically to support large-scale parallel computing on a single graphics chip. Computationally intensive algorithms, such as the Fast Fourier Transform (FFT), are particularly well suited for this computing environment. This high-speed version of MGS exploits commercially available hardware to accomplish the same objective in a fraction of the original time. The exploit involves performing matrix calculations in nVidia graphic cards. The graphical processor unit (GPU) is hardware that is specialized for computationally intensive, highly parallel computation. From the software perspective, a parallel programming model is used, called CUDA, to transparently scale multicore parallelism in hardware. This technology gives computationally intensive applications access to the processing power of the nVidia GPUs through a C/C++ programming interface. The AAMGS (Accelerated Adaptive MGS) software takes advantage of these advanced technologies, to accelerate the optical phase error characterization. With a single PC that contains four nVidia GTX-280 graphic cards, the new implementation can process four images simultaneously to produce a JWST (James Webb Space Telescope) wavefront measurement 60 times faster than the previous code.

Lam, Raymond K.

MGS View of Martian Magnetosphere

The solar wind's interaction with Mars has been studied for several decades. However, the scientific results from the Mars Global Surveyor (MGS) mission represented a very significant step forward in our understanding in this subject. Missions since MGS, including missions currently under development such as MAVEN, have built on MGS' results. In this presentation, I briefly discuss the historical context of MGS' results regarding the induced Martian magnetosphere. I then highlight the major scientific results from the MGS observations and showcase ongoing investigations using MGS data.

Espley, Jared

MGS and Odyssey - Relay Satellites for the MER Mission

Both Mars Global Surveyor (MGS) and Mars Odyssey are currently in low altitude, nearly circular and highly inclined orbits about Mars. Thus, they are available and compatible to serve as relay satellites for the Mars Exploration Rover (MER) mission. Consequently, the MER project developed requirements for MGS to be overhead, at a specific time with a 30 second tolerance, during the atmospheric entry, descent and landing (EDL) phase of both MER vehicles. The result, after execution of a single orbit synchronization maneuver (OSM) on 10/03/03, 92.4 days or 1130 orbits before Spirit's EDL, was that MGS was over Spirit 8 seconds past the required time. This maneuver, with a delta-velocity of 0.534 m/s, caused the orbital period to change by 3.34 s and resulted in a time-phasing change of 62 min 19 s in order to achieve the EDL overflight. Based on the navigation and execution of an OSM on 01/04/04, MGS was overhead for the Opportunity EDL on 01/25/04,3.5 seconds after the required epoch. Requirements also existed for the Odyssey over-flight of the MER rovers after landing and various equipment deployments had been completed. Thus, these requirements were that Odyssey should rise no earlier than specified times with respect to each of the landing sites. The Odyssey over-flights of both Spirit and Opportunity on sol 1 were equally successful. This paper will present the navigation plan, trajectory propagation accuracy and maneuver execution for the successful MGS and Odyssey over-flights of both the MER rovers.

Mars Global Surveyor (MGS)

Preliminary Global Topographic Model of Mars Based on MOLA Altimetry, Earth-Based Radar, and Viking, Mariner and MGS Occultations

The recent altimetry data acquired by MOLA over the northern hemisphere of Mars have been combined with the Earth-based radar data obtained between 1971 and 1982, and occultation measurements of the Viking 1 and 2 Orbiters, Mariner 9, and MGS to derive a global model of the shape and topography of Mars. This preliminary model has a horizontal resolution of about 300 km. Vertical accuracy is on average a few hundred meters in the region of the data. Datasets: The altimetry and radar datasets were individually binned in 1.25 degree grids and merged with the occultation data. The Viking and Mariner occultation data in the northern hemisphere were excluded from the combined dataset where MOLA altimetry were available. The laser altimetry provided extensive and almost complete coverage of the northern hemisphere north of latitude 30 while the radar provided longitudinal coverage at several latitude bands between 23N and 23S. South of this region the only data were occultations. The majority of the occultations were obtained from Mariner 9, and the rest from Viking 1 & 2, and MGS. Earlier studies had shown that the Viking and Mariner occultations were on average only accurate to 500 meters. The recent MGS occultations are accurate to a few tens of meters. However, the highest southern latitude reached by the MGS occultations is only about 64S and data near the target region for the Mars 98 lander is limited to a few Viking and Mariner observations of relatively poor quality. In addition to the above datasets the locations of the Viking 1, Viking 2, and Pathfinder landers, obtained from the radio tracking of their signals, were included.

Smith, David E.

Water Ice Clouds in the Martian Atmosphere: A View from MGS TES

We use the method of Tamppari et al. to map water ice clouds in the Martian atmosphere. This technique was originally developed to analyze the broadband Viking IRTM channels and we have now applied it to the TES data. To do this, the TES spectra are convolved to the IRTM bandshapes and spatial resolutions, enabling use of the same processing techniques as were used in Tamppari et al.. This retrieval technique relies on using the temperature difference recorded in the 20 micron and 11 micron IRTM bands (or IRTM convolved TES bands) to map cold water ice clouds above the warmer Martian surface. Careful removal of surface contributions to the observed radiance is therefore necessary, and we have used both older Viking-derived basemaps of the surface emissivity and albedo, and new MGS derived basemaps in order the explore any possible differences on cloud retrieval due to differences in surface contribution removal. These results will be presented in our poster. Our previous work has concentrated primarily on comparing MGS TES to Viking data; that work saw that large-scale cloud features, such as the aphelion cloud belt, are quite repeatable from year to year, though small scale behavior shows some variation. Comparison of Viking and MGS era cloud maps will be presented in our poster. In the current stage of our study, we have concentrated our efforts on close analysis of water ice cloud behavior in the northern summer of the three MGS mapping years on relatively small spatial scales, and present our results below. Additional information is included in the original extended abstract.

Hale, A. S.

The Gravity Field of Mars From MGS, Mars Odyssey, and MRO Radio Science

The Mars Global Surveyor (MGS), Mars Odyssey (ODY), and Mars Reconnaissance Orbiter (MRO) missions have enabled NASA to conduct reconnaissance and exploration of Mars from orbit for sixteen consecutive years. These radio systems on these spacecraft enabled radio science in orbit around Mars to improve the knowledge of the static structure of the Martian gravitational field. The continuity of the radio tracking data, which cover more than a solar cycle, also provides useful information to characterize the temporal variability of the gravity field, relevant to the planet's internal dynamics and the structure and dynamics of the atmosphere [1]. MGS operated for more than 7 years, between 1999 and 2006, in a frozen sun-synchronous, near-circular, polar orbit with the periapsis at approximately 370 km altitude. ODY and MRO have been orbiting Mars in two separate sun-synchronous orbits at different local times and altitudes. ODY began its mapping phase in 2002 with the periapis at approximately 390 km altitude and 4-5pm Local Solar Time (LST), whereas the MRO science mission started in November 2006 with the periapis at approximately 255 km altitude and 3pm LST. The 16 years of radio tracking data provide useful information on the atmospheric density in the Martian upper atmosphere. We used ODY and MRO radio data to recover the long-term periodicity of the major atmospheric constituents -- CO2, O, and He -- at the orbit altitudes of these two spacecraft [2]. The improved atmospheric model provides a better prediction of the annual and semi-annual variability of the dominant species. Therefore, the inclusion of the recovered model leads to improved orbit determination and an improved gravity field model of Mars with MGS, ODY, and MRO radio tracking data.

Mars

MgS grain component in circumstellar shells

In this letter, far-infrared spectrophotometry (30-55 microns) and photometry (53-200 microns) are presented which define, for the first time, the long wavelength limit of the previously unidentified 30 micron emission feature found in certain extreme carbon star spectra. The spectral similarities are sufficiently similar to those of solid MgS that MgS is proposed to be the band carrier. This is interpreted as the first direct evidence that chemical surface reactions occur on dust grains in circumstellar environments. The presence of MgS indicates that either the oxygen abundance is relatively low and/or the sulfur abundance is high in extreme carbon stars.

Goebel, J. H.

The Measurement of Mars Rotation Rate and Pole Position with MGS

Laser altimeter data and microwave tracking of the MGS (Mars Global Surveyor) spacecraft have been used to estimate rotation parameters for Mars. With the recent development of new high resolution gravity models for Mars and the determination of the orbit of the MGS spacecraft to the few meter level it has become possible to obtain rotational information about the planet. Perturbations of the spacecraft orbit by the planet's gravity field permit the gravity field to be estimated from the tracking data. But the perturbations arising from the non-zonal components of the gravity field have a periodicity related to the rotation of Mars on its axis and these perturbations enable the rotation rate and direction of the rotation pole in inertial space to be measured with respect to the orbit of the spacecraft. It is the anomalies in the gravity field that permit these parameters to be obtained. Similarly, altimetry data are sensitive to errors in the orbital altitude at orbital cross-over locations and the locations themselves are a function of the rotation of the planet. Thus, altimetric measurements by MOLA provide a geometric constraint on the rotation of the planet through the timing of the orbital cross-over pattern as well as information that improves the orbit determination. For a few months in 1999 MGS tracking and altimetry data have been used in a preliminary experiment to estimate the rotation rate of Mars and the right ascension and declination of the pole from an orbiting spacecraft. These preliminary results appear to have sufficient accuracy to permit detection of seasonal changes in rotation rate and also precession of the pole thus leading to a possible eventual measurement of the moment of inertia.

Smith, David E.

Structure and Dynamics of the Polar Regions of Mars from MGS Topography and Gravity

The Mars Global Surveyor (MGS) spacecraft has been engaged in systematic mapping of Mars since insertion into Mars orbit in September, 1997. The objectives of the MGS mission are to globally map Mars as well as to quantify seasonal changes on the planet. MGS geophysical/geodetic observations of topography from the Mars Orbiter Laser Altimeter (MOLA) and gravity from the Radio Science investigation are providing significant new insights on both static and time-varying aspects of the polar regions of Mars. These observations have implications for polar processes on diurnal seasonal and climatic timescales. Thus far, MOLA has collected over 300 million precise measurements of Martian topography and cloud heights. The instrument has also provided measurements of the width of the backscattered optical pulse and of the 1064 nm reflectivity of the Martian surface and atmosphere. The along-track resolution of MOLA ground shots is approx. 300 m and the across-track spacing in the polar regions is a maximum of about four kilometers. The vertical accuracy of the topography is determined by the precision recovery of spacecraft orbits from the Radio Science investigation, which includes MOLA altimetry in the form of crossovers. This accuracy is currently approx. one meter. The gravity field is derived from X-band Doppler tracking with typical accuracy of 0.03 to 0.05 mm/s averaged over ten seconds. Current Mars gravity fields are to approximately degree and order 80 but are interpretable to the approximate degree and order 60 (spatial resolution < 180 km), which represents an estimate of the approximate coefficient limit of a field that can be produced without a power law constraint on the gravitational field inversion, which is commonly imposed for solution stability. Additional information is contained in the original extended abstract.

Zuber, Maria T.

Martian Crustal Magnetism: What Have We Learned After Approximately 6 Years of MGS Observations?

The MAG/ER investigation aboard the Mars Global Surveyor (MGS) has established conclusively that an internal, dynamo-generated field does not currently exist at Mars and discovered, unexpectedly, strong magnetization in the crust. An estimate of the upper limit of the current Mars dipole moment derived from the MGS data yields M < ~2 x 10(exp 17) A-m2, which corresponds to a surface equatorial field strength of < 0.5 nT. The intense magnetization of the crust is closely associated with the ancient, heavily cratered high terrain, which lies south of Mars dichotomy boundary. The correlation of magnetization with the old terrain and the role of impacts, which have modified the magnetic properties of the crust, constitute a new and powerful diagnostic tool that is providing a unique view into the early thermal history of the planet, which was almost totally unknown prior to the arrival of MGS. Data from the Lunar Prospector mission complement contemporary analyses and interpretation of crustal magnetism in planetary system bodies that do not currently possess core dynamos. The observation of magnetic lineations over Terra Sirenum (Sirenum Fossae) and Terra Cimmeria, are suggestive of tectonic processes observed at Earth in association with sea-floor spreading and geomagnetic field reversals. If this association is correct, it would indicate the possible existence of plate tectonics and magnetic field reversals in Mars' early history. Alternative models involving fault/graben formation associated with the fracturing of a thin, magnetized crustal layer by tectonic or volcanism-induced stresses, yield equally valid interpretations. To date, no reliable correlation between topography, geology and crustal magnetism has been established and the origin of these remarkable Martian magnetic anomalies remains a mystery.

M H Acuna

MGS 2-Cell CPV NiH2 Batteries

The Nickel Hydrogen batteries used aboard the Mars Global Surveyor (MGS) is described. The mission itself is briefly described. This is followed by a description of the full electric power subsystem, and the design of the MGS 20 AH cell design. Graphic presentations show characteristics of the battery's performance. In summary, even though the charge control seems to be well, the method used is not recommended, due to an unexpected increase in pressure observed in flight. The operations have been modified to further minimize overcharge, and the pressure increase is not expected to impact the mission.

DiStefano, Sal

Atmospheric Results from the MGS Horizon Science Experiment

The Horizon Science Experiment (HORSE) utilizes the Mars Horizon Sensor Assembly (MHSA) on the Mars Global Surveyor (MGS) orbiter to measure 15-micron band thermal emission from the Martian atmosphere. During the first two phases of aerobraking, from September 1997 to May 1998, and from September 1998 to March 1999, one of the four MGS quadrants was pointed well onto the planet consistently during the near-periapsis aerobraking passes, allowing the device to obtain data on the latitudinal variation of middle atmospheric temperature (0.2 - 2.0 mbar). Of particular interest during the first phase (L(sub s) = 182 - 300 deg) were the effects of a prominent dust storm at L(sub s) =224 deg, and wavelike behavior in the strong temperature gradient near the north polar cap. Additional information is contained in the original extended abstract.

Martin, T. Z.

Aeroheating Thermal Model Correlation for Mars Global Surveyor (MGS) Solar Array

The Mars Global Surveyor (MGS) Spacecraft made use of aerobraking to gradually reduce its orbit period from a highly elliptical insertion orbit to its final science orbit. Aerobraking produces a high heat load on the solar arrays, which have a large surface area exposed to the airflow and relatively low mass. To accurately model the complex behavior during aerobraking, the thermal analysis needed to be tightly coupled to the spatially varying, time dependent aerodynamic heating. Also, the thermal model itself needed to accurately capture the behavior of the solar array and its response to changing heat load conditions. The correlation of the thermal model to flight data allowed a validation of the modeling process, as well as information on what processes dominate the thermal behavior. Correlation in this case primarily involved detailing the thermal sensor nodes, using as-built mass to modify material property estimates, refining solar cell assembly properties, and adding detail to radiation and heat flux boundary conditions. This paper describes the methods used to develop finite element thermal models of the MGS solar array and the correlation of the thermal model to flight data from the spacecraft drag passes. Correlation was made to data from four flight thermal sensors over three of the early drag passes. Good correlation of the model was achieved, with a maximum difference between the predicted model maximum and the observed flight maximum temperature of less than 5%. Lessons learned in the correlation of this model assisted in validating a similar model and method used for the Mars Odyssey solar array aeroheating analysis, which were used during onorbit operations.

Amundsen, Ruth M.

Analysis of Properties of the North Polar Layered Deposits: THEMIS Data in Context of MGS Data

One of the many questions of Martian exploration is to uncover the history of Mars, through analysis of the polar layered deposits (PLD). Martian polar ice caps hold most of the exposed water on the surface on Mars and yet their history and physical processed involved in their formation are unclear. We will attempt to contribute to our knowledge of the composition and stratigraphy of the polar deposits. In this work we present the latest imaging data acquired by the Mars Odyssey THermal EMission Imaging System (THEMIS) and place it into context of the Mars Global Surveyor (MGS) data. THEMIS provides capabilities for imaging in both thermal IR and visible color wavelengths. These observations are affected by atmospheric scattering and topography. The Mars Orbiter Laser Altimeter (MOLA) and Thermal Emission Spectrometer (TES) instruments on board of the MGS spacecraft can provide context information for THEMIS data. Of particular interest are Mars Orbiter Camera (MOC) images, which provide high resolution data. We are primarily interested in the seasonal evolution of ice cap temperatures during the first northern summer of THEMIS observations. Morphology, stratigraphy and composition of the layered deposits can be addressed by THEMIS VIS color images, along with MOC high resolution data and MOLA Digital Elevation Models (DEM). This work is intentionally descriptive. Based on the knowledge obtained by the orbiting spacecraft and described here, we will attempt to expose major directions for modeling and further understanding of of the physical processes involved in the formation of the polar layered terrain 2 Available data 2.1 THEMIS IR The THEMIS IR camera has 10 bands from 6 to 15 m. Due to to signal-to-noise restrictions the most useful band for polar observations is band 9 (12.57 m ). Band 10 (14.88 m ) data can be used for atmospheric calibration. An example of seasonal evolution observed by the THEMIS IR subsystem is shown in Figure 1. We have projected all IR images, covering a small area near 86N and 90E into a polar stereographic projection and then sampled time dimension in order to look at temperature evolution over the course of the summer. We are plotting averaged temperature data over two 1km2 regions of interest: layered material inside the trough and the surface of the residual ice cap. High resolution THEMIS IR data allows us to distinguish properties of bulk of layered terrain and ice. We were not able yet to distinguish properties of individual layers.

A B Ivanov

An Investigation of the Correlation of Water-Ice and Dust Retrievals Via the MGS TES Data Set

Water-ice in the Martian atmosphere was first identified in the Mariner 9 Infrared Interferometer Spectrometer (IRIS) spectra. The Viking Imaging Subsystem (VIS) instruments aboard the Viking orbiter also observed water-ice clouds and hazes in the Martian atmosphere. The MGS TES instrument is an infrared inferometer/spectrometer which covers the spectral range 6-50 micron with a selectable sampling resolution of either 5 or 10 per cm. Using the relatively independent and distinct spectral signatures for dust and water-ice, these two retrieved quantities have been retrieved simultaneously. Although the interrelations among the two quantities have been analyzed by Smith et al. and the retrievals are thought to be robust, understanding the impact of each quantity on the other during their retrievals as well as the impact from the surface for retrievals is important for correctly interpreting the science, and therefore requires close examination. An understanding of the correlation or a-correlation between dust and water-ice would aid in understanding the physical processes responsible for the transport of aerosols in the Martian atmosphere. In this presentation, we present an investigation of the correlation between water-ice and dust in the MGS TES data set.

Qu, Z.