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At least 19 records
All sourcesNASA NTRSDOE OSTI
NASA NTRS1977

Metastable states of small rare gas crystallites

Metastable states of rare gas crystallites containing N atoms are investigated for N = 5,6,7, and 8. In particular, the stability, structures, structural transformation, and binding energy versus temperature are determined using a Monte Carlo method. The square pyramid isomer for N = 5 is found to be unstable at any finite temperature. The other metastable isomers are all found to make spontaneous transitions to the ground state if the temperature is greater than about one half that of meltings. Comparisons with previous work are also made

Etters, R. D.↗
NASA NTRS1992

Metastable State Relaxation in a Gravitational Field

A metastable state relaxation equation for a physical system placed into a gravitational field is constructed for non-critical supersaturated solutions which arc in the immediate neighborhood of the coexistence line. Solutions of this equation are obtained in two different regimes: stationary and dynamic. The sedimentation time which can be defined as the time of the subcritical solute cluster redistribution corresponding to the final steady state in the gravitational field is found. The formation of the concentration gradient is proved analytically and its expression through the model parameters is obtained. The following analysis gives the expression for the sedimentation time which does not depend on the column height. The law of the concentration change with respect to the column height is also found and analyzed.

Izmailov, Alexander F.↗
NASA NTRS1993

Theory of Metastable State Relaxation in a Gravitational Field for Non-Critical Binary Systems with Non-Conserved Order Parameter

A new mathematical ansatz is developed for solution of the time-dependent Ginzburg-Landau nonlinear partial differential equation describing metastable state relaxation in binary (solute+solvent) non-critical solutions with non-conserved scalar order parameter in presence of a gravitational field. It has been demonstrated analytically that in such systems metastability initiates heterogeneous solute redistribution which results in the formation of a non-equilibrium singly-periodic spatial solute structure in the new solute-rich phase. The critical radius of nucleation and the induction time in these systems are gravity-dependent. It has also been proved that metastable state relaxation in vertical columns of supersaturated non-critical binary solutions leads to formation of the solute concentration gradient. Analytical expression for this concentration gradient is found and analysed. It is concluded that gravity can initiate phase separation (nucleation or spinodal decomposition).

Izmailov, Alexander F.↗
NASA NTRS1978

Metastable states and mass loss in Be stars

Three strong asymmetric absorption features with short-wavelength wings extending 350 km/s from their respective line centers at 2061.6, 2068.2, and 2079.0 A appear in high-resolution UV spectral data (0.1 A) for the Be star Phi Per (B2 Ve4) obtained with the Balloon-borne Ultraviolet Stellar Spectrometer (BUSS) on the evening of September 16, 1976. These transitions are not resonance lines and have been identified as transitions of Fe III (UV 48) originating from a metastable state with an excitation of 5.01 eV. The relative populations of the metastable and ground states are independent of the dilution factor, allowing calculation of the mass-outflow rate for a generalized model. Thus, a mass-outflow rate of 5 hundred-billionths of a solar mass per year is obtained. These transitions are observable with IUE and represent an important tool for studying mass outflow in Be and shell stars.

Bruhweiler, F. C.↗
NASA NTRS1973

Metastable states of highly excited heavy ions

Description of the method used and results obtained in an experimental study of the metastable states of highly stripped heavy ions, aimed at determining the lifetimes of such states by the rates of autoionization and radiation. The significance and limitations of the results presented are discussed.

Pegg, D. J.↗
NASA NTRS1993

Theory of Metastable State Relaxation for Non-Critical Binary Systems with Non-Conserved Order Parameter

A new mathematical ansatz for a solution of the time-dependent Ginzburg-Landau non-linear partial differential equation is developed for non-critical systems such as non-critical binary solutions (solute + solvent) described by the non-conserved scalar order parameter. It is demonstrated that in such systems metastability initiates heterogeneous solute redistribution which results in formation of the non-equilibrium singly-periodic spatial solute structure. It is found how the time-dependent period of this structure evolves in time. In addition, the critical radius r(sub c) for solute embryo of the new solute rich phase together with the metastable state lifetime t(sub c) are determined analytically and analyzed.

Izmailov, Alexander↗
NASA NTRS1973

Time-of-flight measurements of metastable state lifetimes.

A time-of-flight method for measurement of the lifetime of metastable molecules is described. The method is applicable to a molecular beam that has molecules in several different metastable excited states. As compared to methods used previously, the method has the advantages that it does not require selective excitation or quenching of the different states; moreover, it does not require a determination of the relative populations or velocity distributions of molecules in the excited states.

Kaslow, D. E.↗
NASA NTRS1982

Radiative lifetime of the 5S2 metastable state of N/+/

The radiative lifetime of metastable N(+)(5S2) has been measured to be 4.2 + or - 0.6 msec, a value generally in agreement with theory, by direct monitoring of the spontaneous emission from approximately 1,000,000 ions stored in a radio-frequency ion trap. Additional measurements were made of the quenching rate coefficient (2.5 x 10 to the -9th cu cm/sec) and the production cross section (greater than or equal to 10 to the -18th sq cm) of N(+)(5S2) in N2. This work supports the interpretation of the 2145-A feature in the spectrum of aurorae as being due to N(+)(5S2) emission.

Knight, R. D.↗
NASA NTRS1977

Measurements of copper ground-state and metastable level population densities in a copper-chloride laser

The population densities of both the ground and the 2D(5/2) metastable states of copper atoms in a double-pulsed copper-chloride laser are correlated with laser energy as a function of time after the dissociation current pulse. Time-resolved density variations of the ground and excited copper atoms were derived from measurements of optical absorption at 324.7 and 510.6 nm, respectively, over a wide range of operating conditions in laser tubes with diameters of 4 to 40 mm. The minimum delay between the two current pulses at which lasing was observed is shown to be a function of the initial density and subsequent decay of the metastable state. Similarly, the maximum delay is shown to be a function of the initial density and decay of the ground state.

Nerheim, N. M.↗
NASA NTRS1995

Pressure Dependence and Metastable State Formation in the Photolysis of Dichlorine Monoxide (Cl2O)

Physics%K photolysis, dichlorine monoxide, pressure%U http://techreports.jpl.nasa.gov/1995/95-0924.pdfThe photodissociation of dichlorine monoxide (Cl2O) was studied using broadband flash photolysis to investigate the influence of variations in the photolysis wavelength domain, bath gas pressure, and bath gas identity on the yield and temporal dependence of the ClO product. ClO yields were independent of bath gas pressure when the photolysis spectral band extended to 200 nm (quartz cutoff) but for photolysis restricted to wavelengths longer than about 250 nm, ClO yields decreased with increasing bath gas pressure and there was a pressure-dependent delay in the formation of ClO.!.

photolysis↗
NASA NTRS1981

Reactions of ground-state and metastable O/2+/ ions with He, O2, N2, and CO2 at thermal energies

Evidence is presented that some previous studies of reactions of O(2+) ions with various atoms and molecules referred to ion samples composed in part of ions in metastable (1D and/or 1S) states. This finding resolves the 3 orders of magnitude discrepancy between previous experimental and calculated rate coefficients for the O(2+)(3P) + He charge transfer process. Using a drift tube to distinguish, via arrival time differences, groundstate O(+)(3P) and metastable ions, a rate coefficient of (3.5 plus or minus 1.5) x 10 to the -11th cu cm/sec is obtained for the reaction, in good agreement with that obtained from ab initio theoretical calculations. Previous conclusions concerning reactions of O(2+) with O2 and N2, however, remain valid since the difference in reactivity of ground-state and metastable O(2+) ions appears to be negligible in this case. The rate coefficient for the reaction O(2+) + CO2 has been determined to be (2 plus or minus 0.5) x 10 to the -9th cu cm/sec for ions either in the ground-state or in metastable states.

Johnsen, R.↗
NASA NTRS1975

Resonance line transfer with partial redistribution. IV - A generalized formulation for lines with common upper states. V - The solar Ca II lines

A generalized formulation is given for treating partial redistribution effects in transfer problems in resonance lines with common upper states. The formulation allows explicitly for the possibility that several spectral lines may arise in transitions from a given upper level to several sharp lower levels, including, for example, the ground state and metastable states. Line profiles for the Ca II H and K lines have been calculated, accounting for the partial frequency coherence of scattered photons. These profiles are compared with calculations made with identical atomic and atmospheric models but assuming complete redistribution. Very significant differences between the profiles obtained using these two different physical descriptions of the scattering process are found, and it is now apparent that the assumption of complete redistribution is a serious oversimplification of the actual physical situation. The results question the validity of equating brightness temperatures observed at K(sub 1) in stellar spectra with minimum temperatures in stellar chromospheres; it appears likely that such a procedure will systematically underestimate the value of T-min.

Milkey, R. W.↗