Materials Data on LiPtF6 by Materials Project
LiPtF6 is Upper Bainite-derived structured and crystallizes in the trigonal R-3 space group. The structure is three-dimensional. Li1+ is bonded to six equivalent F1- atoms to form LiF6 octahedra that share corners with six equivalent PtF6 octahedra. The corner-sharing octahedral tilt angles are 43°. All Li–F bond lengths are 2.07 Å. Pt5+ is bonded to six equivalent F1- atoms to form PtF6 octahedra that share corners with six equivalent LiF6 octahedra. The corner-sharing octahedral tilt angles are 43°. All Pt–F bond lengths are 1.93 Å. F1- is bonded in a distorted bent 150 degrees geometry to one Li1+ and one Pt5+ atom.
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