Materials Data on LiH6BrO7 by Materials Project
Li(H2O)3BrO4 crystallizes in the hexagonal P6_3mc space group. The structure is one-dimensional and consists of two hypobromous acid;trihydrate molecules and one Li(H2O)3 ribbon oriented in the (0, 0, 1) direction. In the Li(H2O)3 ribbon, Li is bonded to six equivalent O atoms to form face-sharing LiO6 octahedra. There are three shorter (2.16 Å) and three longer (2.18 Å) Li–O bond lengths. H is bonded in a single-bond geometry to one O atom. The H–O bond length is 0.98 Å. O is bonded in a distorted water-like geometry to two equivalent Li and two equivalent H atoms.
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