Materials Data on LiBrO by Materials Project
LiOBr crystallizes in the orthorhombic Pmma space group. The structure is three-dimensional. Li is bonded in a 2-coordinate geometry to two equivalent O and four equivalent Br atoms. Both Li–O bond lengths are 1.95 Å. There are two shorter (2.73 Å) and two longer (2.95 Å) Li–Br bond lengths. O is bonded in a linear geometry to two equivalent Li atoms. Br is bonded in a distorted rectangular see-saw-like geometry to four equivalent Li atoms.
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