Materials Data on LiAgO by Materials Project
LiAgO crystallizes in the tetragonal I4/mmm space group. The structure is three-dimensional. Li1+ is bonded in a distorted see-saw-like geometry to four equivalent O2- atoms. There are two shorter (1.96 Å) and two longer (2.10 Å) Li–O bond lengths. Ag1+ is bonded in a linear geometry to two equivalent O2- atoms. Both Ag–O bond lengths are 2.12 Å. O2- is bonded to four equivalent Li1+ and two equivalent Ag1+ atoms to form a mixture of corner and edge-sharing OLi4Ag2 octahedra. The corner-sharing octahedra tilt angles range from 0–23°.
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