Materials Data on Li3VS3 by Materials Project
Li3VS3 crystallizes in the trigonal R3c space group. The structure is three-dimensional. Li1+ is bonded in a 4-coordinate geometry to four equivalent S2- atoms. There are a spread of Li–S bond distances ranging from 2.39–2.58 Å. V3+ is bonded to six equivalent S2- atoms to form face-sharing VS6 octahedra. All V–S bond lengths are 2.46 Å. S2- is bonded in a 6-coordinate geometry to four equivalent Li1+ and two equivalent V3+ atoms.
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