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LiY2Zn crystallizes in the orthorhombic Immm space group. The structure is one-dimensional and consists of two LiY2Zn ribbons oriented in the (1, 0, 0) direction. Li is bonded in a linear geometry to two equivalent Y atoms. Both Li–Y bond lengths are 3.17 Å. Y is bonded in a linear geometry to one Li and one Zn atom. The Y–Zn bond length is 2.87 Å. Zn is bonded in a linear geometry to two equivalent Y atoms.
LiYZn2 crystallizes in the orthorhombic Immm space group. The structure is one-dimensional and consists of two LiYZn2 ribbons oriented in the (1, 0, 0) direction. Li is bonded in a linear geometry to two equivalent Zn atoms. Both Li–Zn bond lengths are 2.65 Å. Y is bonded in a linear geometry to two equivalent Zn atoms. Both Y–Zn bond lengths are 2.94 Å. Zn is bonded in a linear geometry to one Li and one Y atom.