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Materials Data on LiSn4Rh by Materials Project

LiRhSn4 is Khatyrkite-derived structured and crystallizes in the tetragonal I4/mcm space group. The structure is three-dimensional. Li is bonded in a q6 geometry to two equivalent Rh and eight equivalent Sn atoms. Both Li–Rh bond lengths are 2.88 Å. All Li–Sn bond lengths are 2.97 Å. Rh is bonded in a distorted q6 geometry to two equivalent Li and eight equivalent Sn atoms. All Rh–Sn bond lengths are 2.84 Å. Sn is bonded in a 4-coordinate geometry to two equivalent Li and two equivalent Rh atoms.

36 MATERIALS SCIENCE↗

Materials Data on LiSn5Rh3 by Materials Project

LiRh3Sn5 crystallizes in the orthorhombic Pbcm space group. The structure is three-dimensional. Li is bonded in a 6-coordinate geometry to four Rh and five Sn atoms. There are a spread of Li–Rh bond distances ranging from 2.66–2.88 Å. There are a spread of Li–Sn bond distances ranging from 2.84–3.05 Å. There are two inequivalent Rh sites. In the first Rh site, Rh is bonded in a 1-coordinate geometry to one Li and seven Sn atoms. There are a spread of Rh–Sn bond distances ranging from 2.73–2.91 Å. In the second Rh site, Rh is bonded in a 8-coordinate geometry to two equivalent Li and six Sn atoms. There are a spread of Rh–Sn bond distances ranging from 2.66–2.81 Å. There are three inequivalent Sn sites. In the first Sn site, Sn is bonded in a 6-coordinate geometry to one Li, four Rh, and one Sn atom. The Sn–Sn bond length is 2.94 Å. In the second Sn site, Sn is bonded in a 5-coordinate geometry to one Li and four Rh atoms. In the third Sn site, Sn is bonded in a 5-coordinate geometry to one Li and four Rh atoms.

36 MATERIALS SCIENCE↗

Materials Data on LiSnRh2 by Materials Project

LiRh2Sn is Heusler structured and crystallizes in the cubic Fm-3m space group. The structure is three-dimensional. Li is bonded in a body-centered cubic geometry to eight equivalent Rh and six equivalent Sn atoms. All Li–Rh bond lengths are 2.69 Å. All Li–Sn bond lengths are 3.11 Å. Rh is bonded in a body-centered cubic geometry to four equivalent Li and four equivalent Sn atoms. All Rh–Sn bond lengths are 2.69 Å. Sn is bonded in a distorted body-centered cubic geometry to six equivalent Li and eight equivalent Rh atoms.

36 MATERIALS SCIENCE↗