Materials Data on La2(PRh)3 by Materials Project
La2(RhP)3 crystallizes in the tetragonal P4/mmm space group. The structure is one-dimensional and consists of one La2(RhP)3 ribbon oriented in the (0, 0, 1) direction. La is bonded in a linear geometry to one Rh and one P atom. The La–Rh bond length is 2.17 Å. The La–P bond length is 2.80 Å. There are two inequivalent Rh sites. In the first Rh site, Rh is bonded in a linear geometry to one La and one P atom. The Rh–P bond length is 2.32 Å. In the second Rh site, Rh is bonded in a linear geometry to two equivalent P atoms. Both Rh–P bond lengths are 2.15 Å. There are two inequivalent P sites. In the first P site, P is bonded in a linear geometry to one La and one Rh atom. In the second P site, P is bonded in a linear geometry to two equivalent Rh atoms.