Materials Data on LaTiSbO6 by Materials Project
LaTiSbO6 is beta Vanadium nitride-derived structured and crystallizes in the trigonal P312 space group. The structure is three-dimensional. La3+ is bonded to six equivalent O2- atoms to form LaO6 octahedra that share corners with six equivalent TiO6 octahedra and corners with six equivalent SbO6 octahedra. The corner-sharing octahedra tilt angles range from 53–54°. All La–O bond lengths are 2.47 Å. Ti4+ is bonded to six equivalent O2- atoms to form TiO6 octahedra that share corners with six equivalent LaO6 octahedra and edges with three equivalent SbO6 octahedra. The corner-sharing octahedral tilt angles are 53°. All Ti–O bond lengths are 1.99 Å. Sb5+ is bonded to six equivalent O2- atoms to form SbO6 octahedra that share corners with six equivalent LaO6 octahedra and edges with three equivalent TiO6 octahedra. The corner-sharing octahedral tilt angles are 54°. All Sb–O bond lengths are 2.01 Å. O2- is bonded in a distorted trigonal planar geometry to one La3+, one Ti4+, and one Sb5+ atom.