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DE-FE0031180 Final Report - LGFCS Prototype System Testing - R0

In the project, LGFCS assembled and tested its modular SOFC Power System that incorporates all critical technology improvements identified for its “product-like” demonstration. This product demonstrator is expected to meet customer and LGFCS performance expectations for operation, availability, durability and serviceability. The principal technology improvements are aimed at increasing the fuel cell power output and reducing the stack degradation rate. Improvements were also made for added system robustness and increased reliability. The objective of this program is to test a 250kWe thermally self-sustaining modular solid oxide fuel cell (SOFC) Power System for a minimum of 5,000 hours while advancing this commercial prototype product demonstrator to a Technical Readiness Level (TRL) 7. The SOFC system was tested on a site provided by Stark State College in North Canton, Ohio. System performance and degradation as well as cost estimates were compared to established SOFC Program performance metrics to assess progress. The major achievements were to assemble, and QA qualify 70 fuel cell strips for 12 integrated blocks into a fuel cell vessel and install it into a generator module with the fuel and power electronics modules on the test site. Performance to date included over 1800 hours on load at 250 KW-AC to the grid with a DC efficiency of 61% and AC efficiency of 55%. Power degradation was less than 0.4% per 1000 hours and NOx emissions met standards. The LGFCS SOFC Prototype System (GEN0) was demonstrated in an operational environment and therefore achieving Technical Readiness Level 7. The work presented here represents the efforts of all the employees of LG Fuel Cell Systems. Their dedication and hard work made GEN0 possible and successful.

03 NATURAL GAS↗

LGFCS Prototype System Testing (Final Report)

In the project, LGFCS assembled and tested its modular SOFC Power System that incorporates all critical technology improvements identified for its “product-like” demonstration. This product demonstrator is expected to meet customer and LGFCS performance expectations for operation, availability, durability and serviceability. The principal technology improvements are aimed at increasing the fuel cell power output and reducing the stack degradation rate. Improvements were also made for added system robustness and increased reliability. The objective of this program is to test a 250kWe thermally self-sustaining modular solid oxide fuel cell (SOFC) Power System for a minimum of 5,000 hours while advancing this commercial prototype product demonstrator to a Technical Readiness Level (TRL) 7. The SOFC system was tested on a site provided by Stark State College in North Canton, Ohio. System performance and degradation as well as cost estimates were compared to established SOFC Program performance metrics to assess progress. The major achievements were to assemble, and QA qualify 70 fuel cell strips for 12 integrated blocks into a fuel cell vessel and install it into a generator module with the fuel and power electronics modules on the test site. Performance to date included over 1800 hours on load at 250 KWAC to the grid with a DC efficiency of 61% and AC efficiency of 55%. Power degradation was less than 0.4% per 1000 hours and NOx emissions met standards. The LGFCS SOFC Prototype System (GEN0) was demonstrated in an operational environment and therefore achieving Technical Readiness Level 7. The work presented here represents the efforts of all the employees of LG Fuel Cell Systems. Their dedication and hard work made GEN0 possible and successful.

03 NATURAL GAS↗

Techno-Economic Analysis of an LGFCS MWe-Class SOFC System (Final Report)

The objective of this project is to perform a range of technical, cost and economic analyses of a MW-scale natural gas fired Solid Oxide Fuel Cell (SOFC) distributed power generation system design. The information generated will provide evidence of the tracking of technology and manufacturing readiness supportive of Technology Readiness Level 7 (TRL7) system testing in the 2022 timeframe that meets the Department of Energy’s (DOE) targets for cost (<$6000/kW) and durability (<0.5% power degradation/1000 hours).

01 COAL, LIGNITE, AND PEAT↗

Techno Economic Analysis of an LGFCS MWE Class SOFCT System (Final Scientific/Technical Report)

The objective of this project is to perform a range of technical, cost and economic analyses of a MWscale natural gas fired Solid Oxide Fuel Cell (SOFC) distributed power generation system design. The information generated will provide evidence of the tracking of technology and manufacturing readiness supportive of Technology Readiness Level 7 (TRL7) system testing in the 2022 timeframe that meets the Department of Energy’s (DOE) targets for cost (<$6000/kW) and durability (<0.5% power degradation/1000 hours).

20 FOSSIL-FUELED POWER PLANTS↗

DE-FE0026098 Final Report - Advanced Materials and Manufacturing Processes for SOFC Power Systems Revision 1

The aim of the project is to qualify an integrated material set and processing solution for selected metallic components of an advanced integrated stack block. As the integrated stack block is the “engine” of the solid oxide fuel cell power system, the project will also support significant cost reductions, increased reliability, and improved performance of the LG Fuel Cell Systems Inc. (“LGFCS”) cell and stack technology to be included in the initial commercial product offering. In the proposed work an integrated material set, and processing solution will be developed using powder metals processing which has been proven to be an enabling technology capable of delivering net or near net shape components, as well as for creating compositions, microstructures, and properties that are otherwise unattainable. Several advanced manufacturing processes will be screened to select one or more that are most advantageous for the selected metallic components when produced at commercial volumes. This work will be accomplished through the integration of metallurgists and processing engineers from Carpenter Technology, with the product design and cost engineers from LGFCS. The expected outcome of the proposed work is an optimized material set and processing solution that will reduce the current cost.

03 NATURAL GAS↗

Development and Characterization of High Performance and Robust Mixed Conducting Cathodes Supportive of Lower Cost Solid Oxide Fuel Cells (Final Report)

The objective of the proposed research is to advance an existing partnership between the University of South Carolina (USC) and LG Fuel Cell Systems, Inc. (LGFCS) to research and develop mixed electronic and ionic conducting cathode materials for durable and robust low-cost solid oxide fuel cells (SOFCs). The first task is to develop mixed ionic and electronic conducting doped (Pr,Nd)NiO 4 (PNNO)-based cathodes. This task is built on a prior collaborative work with LG Fuel Cell System, which showed that doped PNNO could exhibit phase stability at high temperatures. The initial focus will be on investigating the durability and endurance of its electrochemical performance and the temporal evolution of microstructures. In-situ high temperature neutron diffraction and x-ray diffraction will be used to study the structures of these phase stable compounds. PNNO doped with Ca and transition metal elements will be synthesized. Physical properties of these materials with respect to coefficient of thermal expansion, electrical conductivity, diffusion coefficient, and nonstoichiometry will be measured. The benefits of dense versus porous barriers will be studied and the role of barrier layer will be identified and a guideline will be provided to choose the maximum porosity for durable and robust cathode performance with co-doped PNNO as the cathodes. LSCF6428 will be used to compare its power density with that of co-doped PNNO in the absence of Cr, but some studies comparing Cr tolerance will be performed towards the end of the project. The conditions at which preferred nickelate phases are stable will be defined, including sintering temperature, operating temperature, and composition range. The second task will focus on the investigation of the location of degradation by using differential relaxation time (DRT) analysis, coupled with least squares fitting and systematical post analyses. DRT analysis can provide (1) a direct access to the kinetic parameters of the underlying processes in both cathode and anode, and (2) a clearer picture of SOFC operation, which allows loss factors to the changes of microstructures or activities of either electrode to be distinguished, and a better target fuel cell development to be enabled. The third task aims at applying the accelerated testing protocol to investigate the microstructural evolution of the cathode candidates identified in this research. Technical approaches will be developed to mitigate and improve the durability of cathode materials by choosing the right chemistry and tuning cathode microstructures.

36 MATERIALS SCIENCE↗

Improved Reliability of Solid Oxide Fuel Cell Systems. Final scientific/technical report

This program is furthering the development of SOFC technology to meet the durability requirements required by the market for the service life and costs for such a power generation technology. SOFC technology provides an environmentally friendly and highly efficient power generation. LGFCS is developing a 1MW pressurized SOFC system for distributed power generation. The planned commercial product is expected to have an efficiency of ~60% (net AC) and fueled by natural gas. The lower carbon content of natural gas combined with the efficient power generation results in significant environmental benefits (lower CO2 greenhouse emissions). The SOFC technology provides a means for efficient utilization of the large US reserves of natural gas and enhances national energy independence. The SOFC technology will initially serve the distributed power generation market and gain market acceptance and smaller power system sizes. The technology is well suited to carbon sequestration given the separated air and fuel streams. The Department of Energy (DOE) envisions a centralized power generation technology that could use coal gasification as an integrated gasification fuel cell (IGFC) power plant at the >100MW scale with CO2 capture.

25 ENERGY STORAGE↗