Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “KSO6”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

2 records
All sourcesNASA NTRSDOE OSTI
DOE OSTI2020

Materials Data on KSO6 by Materials Project

KSO6 crystallizes in the monoclinic C2/c space group. The structure is two-dimensional and consists of two KSO6 sheets oriented in the (1, 0, 0) direction. K is bonded in a 10-coordinate geometry to ten O atoms. There are a spread of K–O bond distances ranging from 2.83–3.23 Å. S is bonded in a distorted tetrahedral geometry to four O atoms. There are a spread of S–O bond distances ranging from 1.44–1.86 Å. There are six inequivalent O sites. In the first O site, O is bonded in a single-bond geometry to one K atom. In the second O site, O is bonded in a distorted single-bond geometry to three equivalent K and one S atom. In the third O site, O is bonded in a 1-coordinate geometry to one K, one S, and one O atom. The O–O bond length is 1.32 Å. In the fourth O site, O is bonded in a 2-coordinate geometry to two equivalent K and one O atom. In the fifth O site, O is bonded in a single-bond geometry to one S atom. In the sixth O site, O is bonded in a distorted single-bond geometry to three equivalent K and one S atom.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Materials Data on K3Sb7(SO3)3 by Materials Project

K3Sb7(SO3)3 crystallizes in the hexagonal P6_3 space group. The structure is three-dimensional. K1+ is bonded to one S2- and six O2- atoms to form distorted corner-sharing KSO6 hexagonal pyramids. The K–S bond length is 3.22 Å. There are a spread of K–O bond distances ranging from 2.78–3.02 Å. There are three inequivalent Sb3+ sites. In the first Sb3+ site, Sb3+ is bonded in a distorted T-shaped geometry to three O2- atoms. There are two shorter (2.00 Å) and one longer (2.03 Å) Sb–O bond lengths. In the second Sb3+ site, Sb3+ is bonded in a 3-coordinate geometry to three O2- atoms. There are a spread of Sb–O bond distances ranging from 2.01–2.05 Å. In the third Sb3+ site, Sb3+ is bonded in a trigonal non-coplanar geometry to three equivalent S2- atoms. All Sb–S bond lengths are 2.45 Å. S2- is bonded in a 2-coordinate geometry to one K1+ and one Sb3+ atom. There are three inequivalent O2- sites. In the first O2- site, O2- is bonded in a 2-coordinate geometry to two equivalent K1+ and two Sb3+ atoms. In the second O2- site, O2- is bonded to two equivalent K1+ and two Sb3+ atoms to form a mixture of distorted corner and edge-sharing OK2Sb2 tetrahedra. In the third O2- site, O2- is bonded to two equivalent K1+ and two Sb3+ atoms to form a mixture of distorted corner and edge-sharing OK2Sb2 tetrahedra.

36 MATERIALS SCIENCE↗