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NASA NTRS2004

The Cretaceous/Paleogene Transition on the East Tasman Plateau, Southwestern Pacific

Ocean Drilling Program Leg 189 recovered a potentially complete shallow marine record of the Cretaceous-Paleogene boundary (KPB) at Site 1172 on the East Tasman Plateau. Here we present high-resolution (cm-scale) data from micropaleontology, geochemistry, sedimentology, and paleomagnetism that provide no evidence for a complete KPB, but instead suggest a boundary-spanning hiatus of at least 0.8 Ma. We interpret this hiatus to represent the sequence boundary between the uppermost Maastrichtian Tal.1 and lowermost Danian Ta1.2/ Da- 1 3rd-order sequence stratigraphic cycles. Microfloral assemblages indicate generally shallow paleodepths, restricted circulation, and eutrophic conditions through the section. Paleodepths progressively shallow through the late Maastrichtian, while more oceanic and warmer conditions dominate the early Danian. The Site 1172 KPB section is broadly comparable to other southern highlatitude sections in Antarctica and New Zealand, but appears to record a shallower and more restricted environment that permitted a eustatically-driven hiatus across the KPB mass extinction event.

Schellenberg, Stephen A.↗

NASA NTRS1982

Chemical composition of the Howardite Parent Body deduced from Kapoeta primary 'mafic' magmas

Chemical data are presented for three 'mafic' clasts extracted from the Kapoeta howardite. Bulk compositions and petrologic observations suggest that two of these lithic clasts represent olivine-plagioclase bearing orthopyroxenites. Chondrite-relative refractory large ion lithophile abundances of two of the clasts are inferred to represent primary Mg-rich magmas produced by extensive (greater than about 70%) partial melting of a source composition indistinguishable from the silicate fraction of average CH-CL ordinary chondrites, with the exception of the depletion of the alkalis Na and K by a factor of 13 + or - 1 in the source composition. A metal-free and volatile depleted Kapoeta Parent Body (KPB) is subsequently deduced and is shown to compare very well with other similarly derived Achondrite Parent Body and Howardite Parent Body estimates but not to parent body estimates derived from inferences based on eucrite phase equilibrium studies. Other implications suggest that the KPB is heterogeneous with respect to Fe/Mg ratios.

Smith, M. R.↗

NASA NTRS2018

Mid-infrared Spectroscopy of Pr-Doped Materials

Solid state lanthanide doped lasers primarily operate in the ultraviolet, visible, near infrared and short-wavelength infrared out to around 2.1 μm. At longer wavelengths, the transitions in conventional oxide crystal and glass materials become susceptible to multiphonon quenching due to their relatively large phonon energy. The use of low phonon materials can minimize the nonradiative quenching, opening up possibilities for solid state lanthanide lasers operating in the mid-infrared (MIR). This provides motivation to study the spectroscopy of lanthanide ions in bromide, chloride and fluoride materials, which have relatively low phonon energies. In this article, the MIR spectroscopy or praseodymium ions in five different host materials is studied, specifically KPb2Br5 (KPB), LaF3, KYF4 (KYF), BaY2F8 (BYF) and YLiF4 (YLF) host crystals. The MIR emission cross sections have been measured from 3 to 6 μm and reciprocity of absorption and emission is utilized to validate the results. The lifetime dynamics in the MIR are covered for various pump and emission wavelengths. Results are also presented on MIR emission from 6.5 to 8.5 μm in a Pr: KPB crystal, which, to the best of the authors knowledge, is the first such measurement of luminescence in this wavelength range that has been published.

Brian M Walsh↗