On the solubility of potassium ozonide in liquefied ammonia nh3 - ko3 system o rast- vorimosti ozonida kaliya v szhizhennom ammi- ake
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Marakov, S. Z.↗
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Synthesis of calcium superoxide
Efforts to prepare Ca(O2) sub 2 from reactions of calcium compounds with 100% O3 and with O(D-1) atoms generated by photolysis of O3 at 2537 A are described. Samples of Ca(OH) sub 2, CaO, CaO2, Ca metal, and mixtures containing suspected impurities to promote reaction have been treated with excess O3 under static and flow conditions in the presence and absence of UV irradiation. Studies with KO2 suggest that the superoxide anion is stable to radiation at 2537 A but reacts with oxygen atoms generated by the photolysis of O3 to form KO3. Calcium superoxide is expected to behave in an analogous.
Rewick, R. T.↗