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Materials Data on K3Cd by Materials Project

K3Cd is Uranium Silicide structured and crystallizes in the cubic Pm-3m space group. The structure is three-dimensional. K is bonded to eight equivalent K and four equivalent Cd atoms to form distorted KK8Cd4 cuboctahedra that share corners with twelve equivalent KK8Cd4 cuboctahedra, edges with eight equivalent CdK12 cuboctahedra, edges with sixteen equivalent KK8Cd4 cuboctahedra, faces with four equivalent CdK12 cuboctahedra, and faces with fourteen equivalent KK8Cd4 cuboctahedra. All K–K bond lengths are 4.21 Å. All K–Cd bond lengths are 4.21 Å. Cd is bonded to twelve equivalent K atoms to form CdK12 cuboctahedra that share corners with twelve equivalent CdK12 cuboctahedra, edges with twenty-four equivalent KK8Cd4 cuboctahedra, faces with six equivalent CdK12 cuboctahedra, and faces with twelve equivalent KK8Cd4 cuboctahedra.

36 MATERIALS SCIENCE↗

Materials Data on K3Cd by Materials Project

K3Cd is alpha bismuth trifluoride structured and crystallizes in the cubic Fm-3m space group. The structure is three-dimensional. there are two inequivalent K sites. In the first K site, K is bonded to four equivalent K and four equivalent Cd atoms to form a mixture of distorted corner, edge, and face-sharing KK4Cd4 tetrahedra. All K–K bond lengths are 4.06 Å. All K–Cd bond lengths are 4.06 Å. In the second K site, K is bonded in a body-centered cubic geometry to eight equivalent K atoms. Cd is bonded in a body-centered cubic geometry to eight equivalent K atoms.

36 MATERIALS SCIENCE↗

Materials Data on K3Cd by Materials Project

K3Cd is alpha bismuth trifluoride structured and crystallizes in the tetragonal I4/mmm space group. The structure is three-dimensional. there are two inequivalent K sites. In the first K site, K is bonded in a 8-coordinate geometry to four equivalent K and four equivalent Cd atoms. All K–K bond lengths are 4.16 Å. All K–Cd bond lengths are 4.16 Å. In the second K site, K is bonded in a body-centered cubic geometry to eight equivalent K atoms. Cd is bonded in a body-centered cubic geometry to eight equivalent K atoms.

36 MATERIALS SCIENCE↗