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Materials Data on K2RuBr5NO by Materials Project

(K)2RuON(Br)5 crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of twenty hydrobromic acid molecules, eight kalium molecules, and four RuON clusters. In each RuON cluster, Ru2+ is bonded in a single-bond geometry to one N3- atom. The Ru–N bond length is 1.74 Å. N3- is bonded in a linear geometry to one Ru2+ and one O2- atom. The N–O bond length is 1.17 Å. O2- is bonded in a single-bond geometry to one N3- atom.

36 MATERIALS SCIENCE↗