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Infrared absorption spectra of metal carbides, nitrides and sulfides

The infrared absorption spectra of 12 kinds of metal carbides, 11 kinds of nitrides, and 7 kinds of sulfides, a total of 30 materials, were measured and the application of the infrared spectra of these materials to analytical chemistry was discussed. The measurements were done in the frequency (wave length) range of (1400 to 400/cm (7 to 25 mu). The carbides Al4C3, B4C, the nitrides AlN, BN, Si3N4, WB, and the sulfides Al2S3, FeS2, MnS, NiS and PbS were noted to have specific absorptions in the measured region. The sensitivity of Boron nitride was especially good and could be detected at 2 to 3 micrograms in 300 mg of potassium bromide.

Kammori, O.↗

Elevated Temperature Deformation of Cr3Si Alloyed with Mo

Four-point bend, constant load compressive creep and constant engineering strain rate tests were conducted on arc-melted and powder-metallurgy (PM) processed Cr40Mo30Si30 specimens in the temperature range 1400 and 1700 K. This is a two phase alloy consisting of (CrMo)3Si and (Cr,Mo)5Si3 phases. The PM specimens, which were substantially weaker than the arc-melted materials, exhibited a stress exponent n, of about 2 and an apparent activation energy for creep, Q(sub 3), of 485 kJ/mol. The mechanism in these specimens appeared to be controlled by creep of a glassy phase. In the case of arc-melted specimens for which nis approximately 3 and Q(sub 3) is approximately 430 kJ/mol, the rate-controlling creep mechanism appeared to be that dominant in the (Cr,Mo)5Si3 phase. In this case, it is suggested that the Nabarro creep mechanism, where dislocation climb is controlled by Bardeen-Herring vacancy sources, is the dominant creep mechanism. Finally, an analysis of the present and literature data on Cr3Si alloyed with Mo appeared to suggest that the creep rate decreases sharply with an increase in the Mo/Si ratio.

Raj, S. V.↗