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At least 19 records

The ionization of the diffuse ionized gas

The diffuse ionized gas (DIG), responsible for producing the faint but pervasive H(sub alpha), requires 15% of the power of all Galactic O stars for its ionization. No other source of ionization seems practical. The spectrum is strong in low stages of ionization (N II, SII), weak in (O III), and very weak in (O I) lambda 6300, at least in one well-observed direction, all significantly different from denser H II regions. We give low-density, low-excitation photoionization models that explain the observed spectrum. The lambda 6300 observation eliminates the simplest models for the DIG (Mathis 1986), in which neutral H extends beyond the edge of the very dilute stellar radiation field. Our present models include two components. One, representing the edges of interstellar H I clouds, extends to the point where H becomes neutral. In the second, the fraction of H(sup o) is not allowed to exceed 0.05 to 0.1. Both have very low values of the ionization parameter, or ratio of the number densities of ionizing photons to electrons. The ionization parameter required by our models is shown to be compatible with observed values of photon and electron densities in the diffuse interstellar medium. Interstellar dust is not important in either model. Predictions of the model are that the Galaxy is leaking about 4% of the ionizing radiation of at least the local O stars into the intergalactic medium, that (O II) lambda 3727 approximately equals 1.1 H(sub alpha), and that He(sup +)/H (sup +)) approximately equals 0.6 He/H. A major difficul ty of this picture is having ionizing radiation propagate from the ionizing stars in the plane of the Galaxy to the DIG. We suggest, as do Miller & Cox (1993), that the ionizing radiation from O stars produces holes or tunnels in the distribution of neutral H as seen from their positions, while we see a sky covered with H I sheets or filaments because we are not near a source of ionizing radiation. With our models, several interfaces between ionized and neutral gas are allowed before the observational limit on lambda 6300 is exceeded. Another difficulty is the gas-phase N(S(sup +))/N(H(sup o)) ratio toward the high-latitude star HD 93521 (Spitzer & Fitzpatrick 1993). We require (S/H) to be somewhat lower than solar, either because of depletion onto grains or a Galactic abundance gradient, so that the S(sup +) can be produced in each of separate H(sup o) and H(sup +) regions.

Domgorgen, H.

Ionization Processes in the Atmosphere of Titan (Research Note). III. Ionization by High-Z Nuclei Cosmic Rays

Context. The Cassini-Huygens mission has revealed the importance of particle precipitation in the atmosphere of Titan thanks to in-situ measurements. These ionizing particles (electrons, protons, and cosmic rays) have a strong impact on the chemistry, hence must be modeled. Aims. We revisit our computation of ionization in the atmosphere of Titan by cosmic rays. The high-energy high-mass ions are taken into account to improve the precision of the calculation of the ion production profile. Methods. The Badhwahr and O Neill model for cosmic ray spectrum was adapted for the Titan model. We used the TransTitan model coupled with the Planetocosmics model to compute the ion production by cosmic rays. We compared the results with the NAIRAS/HZETRN ionization model used for the first time for a body that differs from the Earth. Results. The cosmic ray ionization is computed for five groups of cosmic rays, depending on their charge and mass: protons, alpha, Z = 8 (oxygen), Z = 14 (silicon), and Z = 26 (iron) nucleus. Protons and alpha particles ionize mainly at 65 km altitude, while the higher mass nucleons ionize at higher altitudes. Nevertheless, the ionization at higher altitude is insufficient to obscure the impact of Saturn s magnetosphere protons at a 500 km altitude. The ionization rate at the peak (altitude: 65 km, for all the different conditions) lies between 30 and 40/cu cm/s. Conclusions. These new computations show for the first time the importance of high Z cosmic rays on the ionization of the Titan atmosphere. The updated full ionization profile shape does not differ significantly from that found in our previous calculations (Paper I: Gronoff et al. 2009, 506, 955) but undergoes a strong increase in intensity below an altitude of 400 km, especially between 200 and 400 km altitude where alpha and heavier particles (in the cosmic ray spectrum) are responsible for 40% of the ionization. The comparison of several models of ionization and cosmic ray spectra (in intensity and composition) reassures us about the stability of the altitude of the ionization peak (65 km altitude) with respect to the solar activity.

Gronoff, G.

Atmospheric pressure chemical ionization studies of non-polar isomeric hydrocarbons using ion mobility spectrometry and mass spectrometry with different ionization techniques

The ionization pathways were determined for sets of isomeric non-polar hydrocarbons (structural isomers, cis/trans isomers) using ion mobility spectrometry and mass spectrometry with different techniques of atmospheric pressure chemical ionization to assess the influence of structural features on ion formation. Depending on the structural features, different ions were observed using mass spectrometry. Unsaturated hydrocarbons formed mostly [M - 1]+ and [(M - 1)2H]+ ions while mainly [M - 3]+ and [(M - 3)H2O]+ ions were found for saturated cis/trans isomers using photoionization and 63Ni ionization. These ionization methods and corona discharge ionization were used for ion mobility measurements of these compounds. Different ions were detected for compounds with different structural features. 63Ni ionization and photoionization provide comparable ions for every set of isomers. The product ions formed can be clearly attributed to the structures identified. However, differences in relative abundance of product ions were found. Although corona discharge ionization permits the most sensitive detection of non-polar hydrocarbons, the spectra detected are complex and differ from those obtained with 63Ni ionization and photoionization. c. 2002 American Society for Mass Spectrometry.

Non-NASA Center

Molecular Data for a Biochemical Model of DNA Radiation Damage: Electron Impact Ionization and Dissociative Ionization of DNA Bases and Sugar-Phosphate Backbone

As part of the database for building up a biochemical model of DNA radiation damage, electron impact ionization cross sections of sugar-phosphate backbone and DNA bases have been calculated using the improved binary-encounter dipole (iBED) model. It is found that the total ionization cross sections of C3'- and C5'-deoxyribose-phospate, two conformers of the sugar-phosphate backbone, are close to each other. Furthermore, the sum of the ionization cross sections of the separate deoxyribose and phosphate fragments is in close agreement with the C3'- and C5'-deoxyribose-phospate cross sections, differing by less than 10%. Of the four DNA bases, the ionization cross section of guanine is the largest, then in decreasing order, adenine, thymine, and cytosine. The order is in accordance with the known propensity of oxidation of the bases by ionizing radiation. Dissociative ionization (DI), a process that both ionizes and dissociates a molecule, is investigated for cytosine. The DI cross section for the formation of H and (cytosine-Hl)(+), with the cytosine ion losing H at the 1 position, is also reported. The threshold of this process is calculated to be 17.1 eV. Detailed analysis of ionization products such as in DI is important to trace the sequential steps in the biochemical process of DNA damage.

Dateo, Christopher E.

Weakly ionized cosmic gas: Ionization and characterization

Since collective plasma behavior may determine important transport processes (e.g., plasma diffusion across a magnetic field) in certain cosmic environments, it is important to delineate the parameter space in which weakly ionized cosmic gases may be characterized as plasmas. In this short note, we do so. First, we use values for the ionization fraction given in the literature, wherein the ionization is generally assumed to be due primarily to ionization by cosmic rays. We also discuss an additional mechanism for ionization in such environments, namely, the photoelectric emission of electrons from cosmic dust grains in an interstellar Far Ultra Violet (FUV) radiation field. Simple estimates suggest that under certain conditions this mechanism may dominate cosmic ray ionization, and possibly also the photoionization of metal atoms by the interstellar FUV field, and thereby lead to an enhanced ionization level.

Rosenberg, M.

The Contribution of Ionizing Starts to the Far-Infrared and Radio Emission in the Milky Way: Evidence for a Swept-up Shell and Diffuse Ionized Halo Around the W4 Chimney/Supershell

Normandeau have proposed that W4 is a galactic chimney, the only chimney to-date identified in our Galaxy. Using the recent approx. 1 min resolution IGA (Infrared Galaxy Atlas) and DRAO (Dominion Royal Astrophysical Observatory) CGPS (Canadian Galactic Plane Survey) galactic plane surveys we analyze the far-infrared and radio structure of the W 4 chimney/supershell. We show W4 has a swept-up partially ionized shell of gas and dust which is powered by the OCl 352 star cluster. Analysis of the dust column density establishes there is dense interstellar material below the shell, directly showing the dense material which caused the lower shell expansion to stall. Due to much lower densities above the Galactic plane, the upper W4 shell achieved 'breakout' to form a Galactic chimney. Although the shell appears ionization bounded, it is very inhomogenous and an ionized halo provides evidence of significant Lyman continuum leakage. A large fraction of the OCl 352 cluster photons escape to large distances and are available to ionize the WIM (warm ionized medium) component of the interstellar medium.

Terebey, Susan

Iron ionization and recombination rates and ionization equilibrium

In the past few years important progress has been made on the knowledge of ionization and recombination rates of iron, an astrophysically abundant heavy element and a major impurity in laboratory fusion devices. We make a critical review of the existing data on ionization and dielectronic recombination and present new computations of radiative recombination rate coefficients of Fe(+14) through Fe(+25) using the photoionization cross sections of Clark et al. (1986). We provide analytical fits to the recommended data (direct ionization and excitation-autoionization cross sections; radiative and dielectronic recombination rate coefficients). Finally we determine the iron ionic fractions at ionization equilibrium and compare them with previous computations as well as with observational data.

Arnaud, M.

Electron-Impact Ionization and Dissociative Ionization of Biomolecules

It is well recognized that secondary electrons play an important role in radiation damage to humans. Particularly important is the damage of DNA by electrons, potentially leading to mutagenesis. Molecular-level study of electron interaction with DNA provides information on the damage pathways and dominant mechanisms. Our study of electron-impact ionization of DNA fragments uses the improved binary-encounter dipole model and covers DNA bases, sugar phosphate backbone, and nucleotides. An additivity principle is observed. For example, the sum of the ionization cross sections of the separate deoxyribose and phosphate fragments is in close agreement with the C3(sup prime)- and C5 (sup prime)-deoxyribose-phospate cross sections, differing by less than 5%. Investigation of tandem double lesion initiated by electron-impact dissociative ionization of guanine, followed by proton reaction with the cytosine in the Watson-Crick pair, is currently being studied to see if tandem double lesion can be initiated by electron impact. Up to now only OH-induced tandem double lesion has been studied.

Huo, Winifred M.

Electron Impact Ionization and Dissociative Ionization of C2H2

By utilizing a crossed electron beam collision geometry, a combination of time-of-flight (TOF) and quadrupole mass spectrometers, and the relative flow technique1 normalized values of cross sections and appearance energies (AP) were obtained for the formation of singly and multiply ionized species resulting from the ionization and dissociation of C2H2. Details ont he apparatus and technique have been published previously.2,3.

Electron Ionization

New ionization fractions for the lithium- and helium-like ionization stages of calcium and iron

A reinterpretation of the high resolution X-ray spectra of Ca XIX and Fe XXV, observed during a solar flare on March 25, 1979, is presented. New ionization fractions for Ca XVIII, Ca XIX, Fe XXIV, and Fe XXV are used, and it is shown that the new calculations substantially change the interpretation of the spectra. It is implied that the flare plasma was ionizing during the early phases of the flare, and recombining during the decay phase.

Doyle, J. G.

Simulation study of the ionizing front in the critical ionization velocity phenomenon

The simulation of the critical ionization velocity for a neutral gas cloud moving across the static magnetic field is presented. A low-beta plasma is studied, using a two and a half-dimensional electrostatic code linked with the Plasma and Neutral Interaction Code (Goertz and Machida, 1987). The physics of the ionizing front and the instabilities which occur there are discussed. Results are presented from four numerical runs designed so that the effects of the charge separation field can be distinguished from the wave heating.

Machida, S.

Modeling of the initiation and evolution of a laser-ionized column in the lower atmosphere - 314.5 nm wavelength resonant multiphoton ionization of naturally occurring argon

A 3+1 resonant multiphoton ionization process in naturally occurring argon is studied at 314.5 nm as a candidate for providing a long ionized channel through the atmosphere. Results are presented which indicate peak electron densities up to 10 exp 8/cu cm can be created using laser intensities on the order of 10 exp 8 W/sq cm.

Fetzer, G. J.

Oxygen ionization rates at Mars and Venus - Relative contributions of impact ionization and charge exchange

Oxygen ion production rates above the ionopauses of Venus and Mars are calculated for photoionization, charge exchange, and solar wind electron impact ionization processes. The latter two require the use of the Spreiter and Stahara (1980) gas dynamic model to estimate magnetosheath velocities, densities, and temperatures. The results indicate that impact ionization is the dominant mechanism for the production of O(+) ions at both Venus and Mars. This finding might explain both the high ion escape rates measured by Phobos 2 and the greater mass loading rate inferred for Venus from the bow shock positions.

Zhang, M. H. G.

Ionized absorbers, ionized emitters, and the X-ray spectrum of active galactic nuclei

Broad absorption features are common in the X-ray spectrum of low-luminosity AGNs. The features have been modeled by leaky neutral absorbers or by highly ionized gas that completely occult the continuum source. Such models are incomplete since they do not take into account all the physical processes in the gas. In particular, no previous model included the X-ray emission by the ionized absorbing gas and the reflection of the continuum source radiation. The present work discusses the emission, absorption, and reflection properties of photoionized gases with emphasis on conditions thought to prevail in AGNs. It shows that such gas is likely to produce intense X-ray line and continuum radiation and to reflect a sizable fraction of the nonstellar continuum at all energies. If such gas is indeed responsible for the observed X-ray absorption, then absorption edges are much weaker than commonly assumed, and some residual X-ray continuum is likely to be observed even if the line of sight is completely blocked. Moreover, X-ray emission features may show up in sources not showing X-ray absorption. This has immense consequences for medium-resolution X-ray missions, such as BBXRT and Astro-D, and for the planned high-resolution experiments on board XMM and AXAF.

Netzer, Hagai