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Bibliometric Analysis of Critical Materials Innovation Hub Publications 2013–2022

The Critical Materials Innovation Hub (the CMI Hub, formerly known as the Critical Materials Institute or CMI) is a U.S. Department of Energy (DOE) Energy Innovation Hub led by Ames National Laboratory and supported by DOE. Established in 2013, the CMI Hub focuses on “technologies that make better use of materials and eliminate the need for materials that are subject to supply disruptions” (Ames National Laboratory 2024). The CMI Hub researchers regularly publish articles that describe their research and its results. Nexight Group conducted a bibliographic analysis of the CMI Hub’s publications to develop a profile of the CMI Hub’s research community, identify growing and emerging research fronts in critical materials, and describe the impact the CMI Hub’s publications have had on the research community. The analysis focused on 475 the CMI Hub publications from 2013 through 2022 that were covered by the Scopus database. Citation counts and other information on each publication (authors, author affiliation, keywords, references, etc.) were downloaded from Scopus in early December 2022.

36 MATERIALS SCIENCE↗

An Evaluation of the Patent Portfolio Funded by the U.S. Department of Energy's Critical Materials Innovation Hub

This report describes the results of an analysis of critical materials research funded by the U.S. Department of Energy Critical Materials Innovation Hub (CMI Hub, formerly the Critical Materials Institute). The purpose of the report is to assess various characteristics of patents awarded for CMI Hub-funded innovations in critical materials technology and to determine the extent to which CMI Hub-funded research has influenced subsequent technological developments both within and beyond critical materials.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Exotic Optical Fibers and Glasses: Innovative Material Processing Opportunities in Earth's Orbit

Exotic optical fibers and glasses are the platform material for photonics applications, primarily due to their superior signal transmission (speed, low attenuation), with extending bandwidth deep into the infrared, exceeding that of silica fibers. Gravitational effects (convection sedimentation) have a direct impact on the phase diagram of these materials and influence melting properties, crystallization temperatures, and viscosity of the elemental mix during the manufacturing process. Such factors constitute limits to the yield, transmission quality, and strength and value of these fibers; they also constrain the range of applications. Manufacturing in a gravity-free environment such as the Earth’s Orbit also helps with other aspects of the fabrication process (i.e., improved form factor of the manufacturing unit, sustainability). In this article, revolutionary developments in the field of photonics over the past decade merge with the paradigm shift in the privatization of government-owned capabilities supporting a more diverse infrastructure (parabolic, suborbital, orbital), reduced price, and increased frequency to access space and the microgravity environment. With the increased dependence on data (demand, bandwidth, efficiency), space and the microgravity environment provide opportunities for optimized performance of these exotic optical fibers and glasses underlying the development of enabling technologies to meet future data demand. Existing terrestrial markets (Internet, telecommunications, market transactions) and emerging space markets (onorbit satellite servicing, space manufacturing, space resources, space communications, etc.) seem to converge, and this innovative material processing opportunity of exotic optical fibers and glasses might just be that ‘‘killer app’’: technologically competitive, economically viable, and with the ability to close the business case.

Ioana Cozmuta↗

Networks and interfaces as catalysts for polymer materials innovation

Autonomous experimental systems offer a compelling glimpse into a future where closed-loop, iterative cycles—performed by machines and guided by artificial intelligence (AI) and machine learning (ML)—play a foundational role in materials research and development. This perspective draws attention to the roles of networks and interfaces—of and between humans and machines—for the purpose of generating knowledge and accelerating innovation. Polymers, a class of materials with massive global impact, present a unique opportunity for the application of informatics and automation to pressing societal challenges. To develop these networks and interfaces in polymer science, the Community Resource for Innovation in Polymer Technology (CRIPT)—a polymer data ecosystem based on novel polymer data model, representation, search, and visualization technologies—is introduced. The ongoing co-design efforts engage stakeholders in industry, academia, and government to uncover rapidly actionable, high-impact opportunities to build networks, bridge interfaces, and catalyze innovation in polymer technology.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Bi‐Continuous W‐Rich Refractory High Entropy Alloy‐Cu Composite: Toward Material Innovation of Nuclear Reactor Coolant System

Abstract Refractory high‐entropy alloys (RHEAs) are considered promising candidate materials for next‐generation nuclear reactors due to their superior mechanical strength, irradiation resistance, and thermal stability at high temperatures. However, the significant positive heat of mixing between refractory alloying elements and Cu, commonly used in cooling systems, poses challenges in forming composite structures. This study addresses the issue using a liquid metal dealloying (LMD) process. A precursor alloy (WTaVTi) with a directional dendrite‐interdendrite structure is fabricated and reacted with molten Cu at 1200 °C for 96 h. This approach produced a RHEA‐Cu composite with a stable interface between RHEA (W 31.5 Ta 30.9 V 21.4 Ti 14.3 ) and Cu, featuring a spontaneously formed W‐rich interlayer that enhances interfacial bonding. The composite showed excellent irradiation resistance, with 30% less swelling under α‐ion irradiation than pure W. It also exhibited low thermal conductivity at room temperature, but reached ≈120 W m −1 ·K −1 at ≈650 °C, surpassing pure W. This temperature‐dependent rise in κ, with a positive gradient of +0.075 W m −1 ·K − 2 , is attributed to decreasing diffuse mismatch at elevated temperatures. The large‐scale reaction and stable microstructure achieved through LMD process highlight its industrial potential. This work offers a strategy for developing high‐performance materials by combining RHEA's radiation resistance with Cu's thermal conductivity for extreme environments.

Chemistry↗

Effective Selective Area Doping for GaN Vertical Power Transistors Enabled by Innovative Materials Engineering

GaN vertical power transistors have emerged as promising candidates for future high efficiency high power electronic applications, with the potential to outperform conventional GaN lateral power devices in terms of power, breakdown, and avalanche characteristics. However, the development of current GaN vertical power transistors is seriously hindered by the poor materials performance of selective area doped p-n junctions. A mechanistic understanding of these fundamental materials issues is essential in order to achieve high performance selective area doped p-n junctions and consequently to advance the GaN vertical power transistor technology. To address this challenge, we carried out a comprehensive research program that advance fundamental knowledge in the selective area doping for GaN materials, and which will lead to the development of high performance GaN vertical power transistors. First, we developed innovative fabrication processes, including novel surface etching, surface passivation, and metalorganic chemical vapor deposition (MOCVD) growth, which provided enhanced opportunities for solving the unique challenges of selective area doping in GaN materials. Second, we performed a fundamental materials study using powerful characterization methods including transmission electron microscopy (TEM), ultraviolet (UV-), x-ray and angle-resolved photoelectron spectroscopy (UPS/XPS/ARPES), electron holography, and cathodoluminescence (CL); Third, we investigated several related issues, including Mg incorporation, polarization effects in carrier transport, and non-ideal material effects, which have rarely been explored so far. At the end of this project, we successfully demonstrated (1) fundamental understanding of selective area etching, regrowth, and doping of GaN, and associated knowledge on defects, interface, and breakdown properties. (2) Effective etch and regrowth processing recipes to achieve etch/regrowth GaN p-n diodes with very low leakage of 3.5 nA at 600 V, which meets the ARPA-E target. (2) High performance vertical GaN p-n didoes and vertical junction termination extension (JTE) devices with breakdown voltage of ~ 2 kV, and breakdown electric field of ~ 3.5 MV/cm, which are close to the performance limit of GaN. The successful outcome has resulted in new fundamental understandings in the selective area doping and regrowth process for GaN, which will lead to groundbreaking GaN vertical transistors for high performance next generation power electronics.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Return on Investment and Sustainability of HVDC Links: Role of Diagnostics, Condition Monitoring, and Material Innovations

HVDC cable systems are becoming an upscaled technical option, compared to AC, because of various factors, including easier interconnections, lower losses, and longer transmission distances. In addition, renewables providing direct DC energy, electrified transportation, and aerospace where DC can be favored because of higher carried specific power all point in the direction of broad future usage of HV and MV DC links. However, contrary to AC, there is little return from on-field installation as regards long-term cable reliability and aging processes. This gap must be covered by intensive research, and contributing to this research is the purpose of this paper. The focus is on key points for HVDC (and MVDC) cable reliability and sustainability, from design modeling able to account for voltage transients and extrinsic aging (such as that caused by partial discharges) to the impact of aging on insulation conductivity (which rules the electric field distribution, thus aging rate). Also, recyclable and nanostructured materials, as well as health conditions, are considered. It is shown how cable design can account for accelerated aging due to voltage transients, as well as for aging-time dependence of conductivity, and how design can be free of extrinsic aging caused by PDs. Algorithms for health condition evaluations, which have additional value in a relatively new technology such as HVDC polymeric cables, are applied to insulation system aging under partial discharges, showing how they can provide an indication of insulation degradation globally or locally (weak spots) and of possible maintenance times. All of this can effectively contribute to reducing the risk of major cable breakdown and damage under operation, which would significantly affect the return on investment (ROI).

Montanari, Gian Carlo (ORCID:0000000320258693)↗

Innovative Materials for Aircraft Morphing

Reported herein is an overview of the research being conducted within the Materials Division at NASA Langley Research Center on the development of smart material technologies for advanced airframe systems. The research is a part of the Aircraft Morphing Program which is a new six-year research program to develop smart components for self-adaptive airframe systems. The fundamental areas of materials research within the program are computational materials; advanced piezoelectric materials; advanced fiber optic sensing techniques; and fabrication of integrated composite structures. This paper presents a portion of the ongoing research in each of these areas of materials research.

Simpson, J. O.↗

Exotic Materials and Innovative Concepts for Photovoltaics

The current forum issue is related to the contributions to the European Materials Research Society Spring Meeting 2021 (E-MRS), Symposium E "Exotic Materials and Innovative Concepts for Photovoltaics", organized by Thomas Fix, David Ginley, Mutsumi Sugiyama, and Marin Alexe. This symposium was designed to address fundamental and applied research on innovative photovoltaics materials and concepts, as well as device integration. The focus was on nonconventional photovoltaics, or conventional photovoltaics but with a radically new approach.

exotic materials↗

Innovative Nuclear Materials Outboard-A Project Specimen Preparation Guide

The Innovative Nuclear Materials (INM) Program was recently established by the U.S. Department of Energy (DOE) to develop advanced material technologies for use in nuclear reactors. The INM program is presently focused on researching in-core non-fueled materials for application in fast spectrum nuclear reactors. The widespread deployment of fast reactors continues to be a prominent aspiration for advanced nuclear technology developers. However, companies working to license these reactors have no choice but to rely on historic material technologies since further optimization and advancement of these materials is impeded by the lack of fast neutron irradiation test facilities. INM-OA is a non-fueled drop-in experiment which will irradiate material specimens of interest to fast reactor applications. This experiment will be irradiated at Idaho National Laboratory (INL) in the Advanced Test Reactor (ATR) outboard-A (OA) position during normal and high temperature steady state (HTSS) cycles. It will include material specimens supplied by members of the INM program and will utilize a cadmium-lined basket to filter out incident thermal neutrons, thus simulating a faster neutron energy spectrum. Material specimens will undergo post-irradiation examination including microscopy and mechanical testing. In addition to absorption reactions, fast neutrons cause microstructural damage in materials by atom displacement, which can cause exacerbated changes in physical properties and behavior. Thus, the data obtained from the INM-OA experiment will be crucial for understanding the engineering-scale behavior of reactor materials. This document is intended for the Principal Investigators providing samples for this project. Topics included are a general description of the experiment, the irradiation experiment/capsule design, sample geometries, number of samples to be provided, documentation to be provided, a brief list potentially useful characterization methods that can be leveraged at INL, and other miscellaneous requirements specific to this project. This document is intended for informational use only.

innovative nuclear materials↗

Down-selection of Innovative Fusion Materials

The goal of this proposal is to develop and fundamentally understand the microstructure of refractory multi-component alloys (MCA) as fusion-relevant plasma facing and structural materials, a step to down-select innovative fusion materials prior to the process of advancing their technology readiness level (TRL). Developing materials is paramount to enable fusion as energy source since no existing material is capable of coping with such extreme conditions. We will aim at understanding the role of chemistry and microstructure in these complex multi-component alloys systematically comparing their performance with pure tungsten materials in terms of mechanical properties and manufacturability. Such understanding will open opportunities to optimize MCAs for fusion applications and has a potential of attracting industry partnership.

36 MATERIALS SCIENCE↗

Ultrafast materials synthesis and manufacturing techniques for emerging energy and environmental applications

Energy and environmental issues have attracted increasing attention globally, where sustainability and low-carbon emissions are seriously considered and widely accepted by government officials. In response to this situation, the development of renewable energy and environmental technologies is urgently needed to complement the usage of traditional fossil fuels. While a big part of advancement in these technologies relies on materials innovations, new materials discovery is limited by sluggish conventional materials synthesis methods, greatly hindering the advancement of related technologies. To address this issue, this review introduces and comprehensively summarizes emerging ultrafast materials synthesis methods that could synthesize materials in times as short as nanoseconds, significantly improving research efficiency. We discuss the unique advantages of these methods, followed by how they benefit individual applications for renewable energy and the environment. We also highlight the scalability of ultrafast manufacturing towards their potential industrial utilization. Finally, we provide our perspectives on challenges and opportunities for the future development of ultrafast synthesis and manufacturing technologies. Here, we anticipate that fertile opportunities exist not only for energy and the environment but also for many other applications.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗