Materials Data on InOF2 by Materials Project
InOF2 crystallizes in the monoclinic C2 space group. The structure is three-dimensional. In is bonded to two equivalent O and four equivalent F atoms to form distorted corner-sharing InO2F4 pentagonal pyramids. Both In–O bond lengths are 2.14 Å. There are two shorter (2.13 Å) and two longer (2.17 Å) In–F bond lengths. O is bonded in a bent 150 degrees geometry to two equivalent In atoms. F is bonded in a bent 150 degrees geometry to two equivalent In atoms.