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MgLa2In crystallizes in the orthorhombic Immm space group. The structure is one-dimensional and consists of two MgLa2In ribbons oriented in the (1, 0, 0) direction. Mg is bonded in a linear geometry to two equivalent La atoms. Both Mg–La bond lengths are 3.30 Å. La is bonded in a linear geometry to one Mg and one In atom. The La–In bond length is 2.97 Å. In is bonded in a linear geometry to two equivalent La atoms.
MgLaIn2 crystallizes in the orthorhombic Immm space group. The structure is one-dimensional and consists of two MgLaIn2 ribbons oriented in the (1, 0, 0) direction. Mg is bonded in a linear geometry to two equivalent In atoms. Both Mg–In bond lengths are 2.93 Å. La is bonded in a linear geometry to two equivalent In atoms. Both La–In bond lengths are 2.98 Å. In is bonded in a linear geometry to one Mg and one La atom.