PHOTOMETRY OF THE INFRARED SPECTRUM OF VENUS, 1-2.5 MICRONS
Infrared spectrum of venus investigated by photometric means, providing information on the carbon dioxide abundance in the planet
VENUS↗
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The infrared spectrum of solid chlorotrifluoromethane
The infrared spectrum of solid chlorotrifluoromethane (CF3Cl) has been studied and compared with that of matrix-isolated CF3Cl. Crystal field splitting patterns of the strongest modes nu1 and nu4 suggest the crystal structure to be orthorhombic with a C(2v) factor group and two molecules per unit cell located on C(s) sites.
Frazier, D. O.↗
The infrared spectrum of Jupiter
The principal characteristics of Jupiter's infrared spectrum are reviewed with emphasis on their significance for our understanding of the composition and temperature structure of the Jovian upper atmosphere. The spectral region from 1 to 40 microns divides naturally into three regimes: the reflecting region, thermal emission from below the cloud deck (5-micron hot spots), and thermal emission from above the clouds. Opaque parts of the Jovian atmosphere further subdivide these regions into windows, and each is discussed in the context of its past or potential contributions to our knowledge of the planet. Recent results are incorporated into a table of atmospheric composition and abundance which includes positively identified constituents as well as several which require verification. The limited available information about spatial variations of the infrared spectrum is presented
Ridgway, S. T.↗
Far-infrared spectrum of IRC + 10216
Far-infrared observations of IRC + 10216 in the wavelength range 20-160 microns are presented. The observations were performed simultaneously in four bands with effective wavelengths of 21, 42, 73, and 135 microns, respectively. The scan profile across the source at 21 microns is found to be wider than that for a point source. Interpreting the far-infrared spectrum on the basis of a model in which circumstellar grains are heated by a central source, the radial density dependence is r exp -2, and the emissivity dependence is lambda exp -n, it is found that n = 1-1.2. Time variations of a smaller magnitude at longer wavelengths as compared to the variation at near-infrared wavelengths can also be understood on the basis of this model. Using the mass-loss rate derived from CO observations, the mass absorption coefficient of the grains at 100 microns is found to be not less than 40/sq cm g.
Rengarajan, T. N.↗
The ground state far infrared spectrum of NH3
The NH3 far infrared spectrum is particularly useful for the study of planetary composition and atmospheric dynamics. Studies of this spectrum were conducted by Dowling (1969), Helminger et al. (1971), and Urban et al. (1981). Sattler et al. (1981) have reported measurements of a few nu2 lines with tunable diode lasers. By using simple sum rules, these lines and accurate ground state inversion lines considered by Poynter and Kakar (1975) have been employed in the present investigation to deduce a few of the far infrared ground state transitions. An extensive set of high signal/noise, high resolution (0.0048 per cm) scans of the nu2 bands of NH3 from about 600 per cm through about 1300 per cm ait a series of low pressures have been made in order to accurately determine both the line positions and strengths. The obtained data provide line positions with an absolute accuracy of about 0.0001 per cm in the more favorable cases.
Poynter, R. L.↗
Interpretation of the 3- to 4-Micron Infrared Spectrum of Mars
Infrared reflection spectra have been recorded for a large number of inorganic and organic samples, including minerals and biological specimens, for the purpose of interpreting the 3- to 4-micron spectrum of Mars. A previous suggestion that the Martian bands indicated the presence of carbohydrates is shown not to be a required conclusion. However, no satisfactory explanation is advanced and the problem remains unresolved.
INORGANIC COMPOUND↗
Nickel, argon and cobalt in the infrared spectrum of SN1987A - The core becomes visible
Infrared spectra of supernova 1987A taken in April and November 1987 are presented, showing two distinctly different stages in the evolution of the expanding gas shell. The optical and infrared spectrum in April originated from the hydrogen envelope and show weak hydrogen lines rising above a 5,000-K photospheric continuum. The November spectrum was dominated by strong emission lines from heavy elements as well as many lines from highly excited levels of hydrogen, with peak flux levels in the lines at or slightly above the level of the continuum in April. It is concluded that the inner regions of the supernova were just becoming visible in early 1988. It is expected that these regions contain heavy elements produced by advanced nuclear burning stages in the progenitor star and in the shock wave that ejected all material external to the iron core.
Rank, D. M.↗
Collision-induced absorption in the far infrared spectrum of Titan
The effects of collision-induced absorption on the far infrared spectrum of Titan have been investigated. After a review of the procedure for the theoretical calculation of the N2 translation-rotational spectrum, new results for the temperature range o 70 to 120 K are reported. These are used as input data for a simple atmospheric model in order to compute the far infrared radiance, brightness temperature, and specral limb function. This source of opacity alone is not capable of explaining the Voyager results. When the collision-induced methane is included, the results are in closer agreement in the range between 200 and 300/cm, suggesting that a more complete treatment of collision-induced absorption including particularly CH4-N2, N2-H2, and H2-H2 results, may provide sufficient opacity to reduce or obviate the need for opacities due to clouds or aerosols in order to explain the observed spectra.
Hunt, J. L.↗
Infrared spectrum of mars /lambda 1.1-4.1mu/ <infrakrasnyy spektr marsa lambda 1.1-4.1mu<
Infrared spectrum of mars using diffraction and prism type spectrometers
MARS /PLANET/↗
Observations and interpretation of the infrared spectrum of HD 44179
Infrared spectra of HD 44179 have been obtained for the 3040-, 1150-, and 890-kayser emission features. The strengths of the features put constraints on the possible constituents of the materials responsible for each emission feature. The 3040-kayser feature can be due to emission either from a solid (if it arises from a different region than the 890-kayser feature) or from a gas-phase molecule. The 8-13-micron spectrum is fitted with a simple model employing carbonates plus a dielectric in emission and silicates in absorption. It is suggested that amorphous carbon is the dielectric responsible for the featureless underlying continuum.
Bregman, J. D.↗
Infrared Spectrum of the Pyrene Anion in the CH Stretching Region
In this work, we report the infrared spectrum of pyrene anion, measured using messenger tagging with up to three Ar atoms. We assign the spectrum using density functional theory and vibrational perturbation theory. Additionally, we discuss our results in the context of computed and experimental spectra from the literature as well as recent observations from astronomical sources, addressing the question whether PAH anions could contribute to the strong infrared emission bands at 3.29 μm from carbon- rich regions of space.
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
The infrared spectrum of asteroid 433 Eros
The mineralogical composition of asteroid Eros has been determined from its infrared spectrum (0.9-2.7 micrometers; 28/cm resolution). Major minerals include metallic Ni-Fe and pyroxene; no spectroscopic evidence for olivine or plagioclase feldspar was found. The IR spectrum of Eros is most consistent with a stony-iron composition.
Larson, H. P.↗
Foreign-gas collision broadening of the far-infrared spectrum of water vapor
The far-infrared rotational spectrum of H2(O-16) has been studied in the spectral range 25-112/cm to measure the foreign-gas collision-broadened linewidths. Measurements of 17 lines broadened by nitrogen and 21 lines broadened by oxygen are reported. The measurements were made at 297 K. From these data, the widths due to air broadening are obtained. The experimental results are compared with recent theoretical calculations and with the case of a constant linewidth, equal to the average experimental width. There is some correlation between the relative experimental linewidths and the theoretical predictions. However, the simple assumption of a constant value for the collision-broadened linewidths gives a better representation for the case of N2- and O2-broadened linewidths than do present detailed theoretical calculations.
Gasster, Samuel D.↗
Diatomic molecules in the solar infrared spectrum from ATMOS-SL 3 high resolution observations
The ATMOS Fourier Transform Spectrometer has observed, for the first time, the solar infrared spectrum, from 2 to 16 microns, free of any telluric absorption. A very large number of molecular lines are present on these high quality spectra: vibration-rotation lines of CO (Delta-v = 1 and 2; including the isotopic species C-13, O-18 and O-17), CH, NH, OH and pure rotation lines of OH. The analysis of these lines will allow to derive accurate values for the solar abundances of C, N and O and the isotopic ratios C-13/C-12, O-18/O-16, and O-17/O-16, to test the photospheric model from high to deep layers, to test the electric dipole moment functions of the different molecules and to derive much better molecular constants for CH.
Grevesse, Nicolas↗
The infrared spectrum of carbon suboxide. Part 1 - Region 1-2.5 microns. Part 2 - Region 2-15 microns. Part 3 - Classification of carbon suboxide vibrational bands
Laboratory tests of infrared spectrum of carbon suboxide, to determine presence in Venus and Mars atmospheres
Cruikshank, D. P.↗
Limb-atmospheric infrared spectrum observed on the satellite Ohzora
The Institute of Space and Astronautical Science (ISAS) launched the 9th scientific satellite Ohzora at 17:00 JST on February 14, 1984. This satellite bears the spectrometer, which measures the infrared spectrum of the solar radiation passing the limb atmosphere in the wavelength region of 2 to 10 m. The spectrometer is based on multichannel spectroscopy by using image sensors. Since the wavelength is scanned electronically, it can measure the spectrum unaffected by the satellite motion. A definite axis, i.e., the Z-axis of the satellite, which coincides to the optical axis of the spectrometer, is controlled to the direction of the Sun, and the finer control to introduce the solar light into the spectrometer is made with a 2-axes-controlled mirror. This solar tracking equipment is derived fast enough to measure the spectra in a moment after sunrise. The solar light introduced into the spectrometer is focused on the slits of the monochromators (f=100mm). For better altitude resolution, the horizontal slit is also used with the vertical slit, which is used for the separation of the dispersion. The dispersion light is detected with the pyroelectric array sensors. To obtain maximum dynamic range and spectral resolution, the three-stage polychromator is used.
Matsuzaki, A.↗
A high-resolution atlas of the infrared spectrum of the Sun and the Earth atmosphere from space. Volume 3: Key to identification of solar features
During the period April 29 through May 2, 1985, the Atmospheric Trace Molecule Spectroscopy (ATMOS) experiment was operated as part of the Spacelab-3 (SL-3) payload on the shuttle Challenger. The instrument, a Fourier transform spectrometer, recorded over 2000 infrared solar spectra from an altitude of 360 km. Although the majority of the spectra were taken through the limb of the Earth's atmosphere in order to better understand its composition, several hundred of the 'high-sun' spectra were completely free from telluric absorption. These high-sun spectra recorded from space are, at the present time, the only high-resolution infrared spectra ever taken of the Sun free from absorptions due to constituents in the Earth's atmosphere. Volumes 1 and 2 of this series provide a compilation of these spectra arranged in a format suitable for quick-look reference purposes and are the first record of the continuous high-resolution infrared spectrum of the Sun and the Earth's atmosphere from space. In the Table of Identifications, which constitutes the main body of this volume, each block of eight wavenumbers is given a separate heading and corresponds to a page of two panels in Volume 1 of this series. In addition, three separate blocks of data available from ATMOS from 622-630 cm(exp -1), 630-638 cm(exp -1) and 638-646 cm(exp -1), excluded from Volume 1 because of the low signal-to-noise ratio, have been included due to the certain identification of several OH and NH transitions. In the first column of the table, the corrected frequency is given. The second column identifies the molecular species. The third and fourth columns represent the assigned transition. The fifth column gives the depth of the molecular line in millimeters. Also included in this column is a notation to indicate whether the line is a blend or lies on the shoulder(s) of another line(s). The final column repeats a question mark if the line is unidentified.
Geller, Murray↗