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Giant nonreciprocity of current-voltage characteristics of noncentrosymmetric superconductor–normal metal–superconductor junctions

Here we develop a theory of nonreciprocal current-voltage (I-U) characteristics in noncentrosymmetric superconductor-normal metal-superconductor junctions. We show that at small voltages the nonreciprocal features of the I-U characteristics can be expressed entirely in terms of the dependence of the nonreciprocal part of the quasiparticle density of states in the normal metal part of the junction on the order parameter phase difference chi across the junction. The amplitude of the nonreciprocity in this regime is proportional to the inelastic quasiparticle relaxation time $\tau_{in}$, and can be much larger than that in normal materials, where it is proportional to the elastic relaxation time $\tau_{el}$. At low bias the I-U characteristics possess additional symmetry not present in normal conductors; they remain invariant under simultaneous reversal of current, voltage, and the magnetic field.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Materials Data on UI3 by Materials Project

UI3 crystallizes in the orthorhombic Cmcm space group. The structure is two-dimensional and consists of two UI3 sheets oriented in the (0, 1, 0) direction. U3+ is bonded in a 8-coordinate geometry to eight I1- atoms. There are a spread of U–I bond distances ranging from 3.12–3.44 Å. There are two inequivalent I1- sites. In the first I1- site, I1- is bonded in a distorted trigonal non-coplanar geometry to three equivalent U3+ atoms. In the second I1- site, I1- is bonded in an L-shaped geometry to two equivalent U3+ atoms.

36 MATERIALS SCIENCE↗

Materials Data on UI4 by Materials Project

UI4 crystallizes in the monoclinic C2/c space group. The structure is one-dimensional and consists of two UI4 ribbons oriented in the (0, 0, 1) direction. U4+ is bonded to six I1- atoms to form edge-sharing UI6 octahedra. There are a spread of U–I bond distances ranging from 2.88–3.13 Å. There are two inequivalent I1- sites. In the first I1- site, I1- is bonded in a single-bond geometry to one U4+ atom. In the second I1- site, I1- is bonded in an L-shaped geometry to two equivalent U4+ atoms.

36 MATERIALS SCIENCE↗