Materials Data on Ru(IN3)2 by Materials Project
Ru(N3I)2 crystallizes in the cubic Fm-3m space group. The structure is three-dimensional. Ru4+ is bonded to six equivalent N+0.33- atoms to form RuN6 octahedra that share faces with eight equivalent IN12 cuboctahedra. All Ru–N bond lengths are 1.96 Å. N+0.33- is bonded in a single-bond geometry to one Ru4+ and four equivalent I1- atoms. All N–I bond lengths are 2.74 Å. I1- is bonded to twelve equivalent N+0.33- atoms to form IN12 cuboctahedra that share corners with twelve equivalent IN12 cuboctahedra, faces with six equivalent IN12 cuboctahedra, and faces with four equivalent RuN6 octahedra.
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