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Observation of gapped state in rare-earth monopnictide HoSb

The rare-earth monopnictide family is attracting an intense current interest driven by its unusual extreme magnetoresistance (XMR) property and the potential presence of topologically non-trivial surface states. The experimental observation of non-trivial surface states in this family of materials are not ubiquitous. Here, using high-resolution angle-resolved photoemission spectroscopy, magnetotransport, and parallel first-principles modeling, we examine the nature of electronic states in HoSb. Although we find the presence of bulk band gaps at the G and X-symmetry points of the Brillouin zone, we do not find these gaps to exhibit band inversion so that HoSb does not host a Dirac semimetal state. Our magnetotransport measurements indicate that HoSb can be characterized as a correlated nearly-complete electron-hole-compensated semimetal. Our analysis reveals that the nearly perfect electron-hole compensation could drive the appearance of non-saturating XMR effect in HoSb.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Materials Data on HoSb by Materials Project

HoSb is Halite, Rock Salt structured and crystallizes in the cubic Fm-3m space group. The structure is three-dimensional. Ho3+ is bonded to six equivalent Sb3- atoms to form a mixture of edge and corner-sharing HoSb6 octahedra. The corner-sharing octahedral tilt angles are 0°. All Ho–Sb bond lengths are 3.09 Å. Sb3- is bonded to six equivalent Ho3+ atoms to form a mixture of edge and corner-sharing SbHo6 octahedra. The corner-sharing octahedral tilt angles are 0°.

36 MATERIALS SCIENCE↗

Materials Data on HoSb by Materials Project

HoSb is Tetraauricupride structured and crystallizes in the cubic Pm-3m space group. The structure is three-dimensional. Ho3+ is bonded in a body-centered cubic geometry to eight equivalent Sb3- atoms. All Ho–Sb bond lengths are 3.28 Å. Sb3- is bonded in a body-centered cubic geometry to eight equivalent Ho3+ atoms.

36 MATERIALS SCIENCE↗