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HoGe crystallizes in the orthorhombic Cmcm space group. The structure is three-dimensional. Ho is bonded in a 5-coordinate geometry to seven equivalent Ge atoms. There are a spread of Ho–Ge bond distances ranging from 2.95–3.21 Å. Ge is bonded in a 5-coordinate geometry to seven equivalent Ho and two equivalent Ge atoms. Both Ge–Ge bond lengths are 2.70 Å.
Ho4LiGe4 crystallizes in the orthorhombic Pnma space group. The structure is three-dimensional. Li is bonded in a distorted T-shaped geometry to five Ge atoms. There are a spread of Li–Ge bond distances ranging from 2.70–3.17 Å. There are two inequivalent Ho sites. In the first Ho site, Ho is bonded in a 7-coordinate geometry to seven Ge atoms. There are a spread of Ho–Ge bond distances ranging from 2.97–3.38 Å. In the second Ho site, Ho is bonded in a 6-coordinate geometry to six Ge atoms. There are a spread of Ho–Ge bond distances ranging from 2.85–3.03 Å. There are three inequivalent Ge sites. In the first Ge site, Ge is bonded in a 9-coordinate geometry to two equivalent Li, six Ho, and one Ge atom. The Ge–Ge bond length is 2.56 Å. In the second Ge site, Ge is bonded in a 9-coordinate geometry to one Li, seven Ho, and one Ge atom. The Ge–Ge bond length is 2.67 Å. In the third Ge site, Ge is bonded in a 8-coordinate geometry to one Li, six Ho, and one Ge atom.
The remote sensing of phycoerythrin-containing phytoplankton by ocean color was evaluated. Phycoerythrin (PE) can be remotely sensed by three methods: surface reflectance (Sathyendranath et al. 1994), by laser-activated fluorescence (Hoge and Swift 1986) and by passive fluorescence (Letelier et al. 1996). In collaboration with Dr. Frank Hoge and Robert Swift during Dr. Maria Vernet's tenure as Senior Visiting Scientist at Wallops Island, the active and passive methods were studied, in particular the detection of PE fluorescence and spectral reflectance from airborne LIDAR (AOL). Airborne instrumentation allows for more detailed and flexible sampling of the ocean surface than satellites thus providing the ideal platform to test model and develop algorithms than can later be applied to ocean color by satellites such as TERRA and AQUA. Dr. Vernet's contribution to the Wallops team included determination of PE in the water column, in conjunction with AOL flights in the North Atlantic Bight. In addition, a new flow-through fluorometer for PE determination by fluorescence was tested and calibrated. Results: several goals were achieved during this period. Cruises to the California Current, North Atlantic Bight, Gulf of Maine and Chesapeake Bay provided sampling under different oceanographic and optical conditions. The ships carried the flow-through fluorometer and samples for the determination of PE were obtained from the flow-through flow. The AOL was flown over the ship's track, usually several flights during the cruise, weather permitting.
The new siloxy-germoxy ligand HOGe[OSi(O t Bu) 3 ] 3 generates Mn-, Fe-, and Cr-containing precursors suitable for thermolytic molecular precursor routes to quaternary oxides.
The energy spectrum of cosmic rays above 2.5 EeV has been measured across the declination range - 9 0 ° ≤ δ ≤ + 44.8 ° using ∼ 310 000 events accrued at the Pierre Auger Observatory from an exposure of ( 104 900 ± 3 100 ) km 2 sr yr . No significant variations of energy spectra with declination are observed, after allowing or not for nonuniformities across the sky arising from the well-established dipolar anisotropies in the arrival directions of ultrahigh-energy cosmic rays. Here, the instep feature in the spectrum at ≃ 10 EeV reported previously is now established at a significance above 5 σ . Within the statistics, the energy spectra are indistinguishable across declinations so disfavoring an origin for the instep from a few distinctive sources.
Legume crops establish beneficial associations with rhizobial bacteria that perform biological nitrogen fixation, providing nitrogen to plants without the economic and greenhouse gas emission costs of chemical nitrogen inputs. Here, we examine the influence of three environmental factors that vary in agricultural fields on strain relative fitness in nodules.
Counting rate computer electronics for a rocketborne spectroscopic telescope
Integrated electro-optical microwave radar and laser /lidar/ systems for earth oriented, environmental and domestic applications
A timing discriminator whose output is relatively insensitive to input pulse width and amplitude is described. The video-handling technique is known as slope reversal processing and is based on tapped delay line estimation methods. The concept, design, breadboard construction, and preliminary laboratory test results are reviewed. The processor system features (1) a peak input voltage dynamic range of 80x starting at 100 microvolts; (2) a four stage preamplifier/line-driver having a voltage gain of 2400x; (3) a tapped delay-line estimator implemented for slope reversal triggering by differential comparison; (4) a nominal plus or minus 2.5 nsec shift of the output trigger leading edge over the entire input voltage range, (5) up to 7 dB discrimination against pulse widths less than 35 nsec; and (6) up to one order of magnitude reduction in the false alarm rate compared to a constant fraction system.
A laser satellite ranging system that is mounted upon and integrated with a microwave tracking radar is reported. The 1-pulse/sec ruby laser transmitter is attached directly to the radar's elevation axis and radiates through a new opening in the radar's parabolic dish. The laser photomultiplier tube receiver utilizes the radar's existing 20-cm diam f/11 boresight telescope and observes through a similar symmetrically located opening in the dish. The laser system possesses separate ranging system electronics but shares the radar's timing, computer, and data handling/recording systems. The basic concept of the laser/radar is outlined together with a listing of the numerous advantages over present singular laser range-finding systems. The developmental laser hardware is described along with preliminary range-finding results and expectations.
The higher accuracy and extended coverage of the SEASAT-A altimeter allows for the determinations of a highly refined geoid, of open ocean currents and circulations, of ocean subsurface topography, and of earth surface topography. The radar altimeter on SEASAT-A is also considered as a tracking station in orbit for range and range rate tracking work.
The first successful depth-resolved remote sensing measurements of subsurface ocean water temperature were obtained by spectral analysis of the 3400 per cm O-H stretching Raman band of liquid water. Raman spectral data were obtained from a research vessel at various depths from the surface to 10 meters below the surface in a tidal estuary. The temperature inferred from the spectra was consistent with ground truth temperature to within the shot noise limited accuracy of plus or minus 2 C. The performance of a future fully developed airborne laser Raman water temperature measurement system is estimated on the basis of these first tests.
The characteristics of an Airborne Oceanographic Lidar (AOL) are given. The AOL system is described and its potential for various measurement applications including bathymetry and fluorosensing is discussed.
The Airborne Oceanographic Lidar (AOL), a spatially scanning range-gated device installed on board a NASA C-54 aircraft, is described. The AOL system is capable of measuring topographical relief or water depth (bathymetry) with a range resolution of plus or minus 0.3 m in the vertical dimension. The system may also be used to measure fluorescent spectral signatures from 3500 to 8000 A with a resolution of 100 A. Potential applications of the AOL, including sea state measurements, water transparency assessments, oil spill identification, effluent identification and crop cover assessment are also mentioned.
The goal of HYTID was to provide a cost effective hypersonic vehicle constructed of near-state-of art systems and structure with sufficient margins to assure no vehicle flight development problems, and to permit concentration of flight operations on hypersonic research with a broad series of experiments carried in a dedicated payload bay or on the exposed surface of the lower aft fuselage.
The application of Raman scattering to remote sensing of subsurface water temperature and salinity is considered, and both theoretical and experimental aspects of the technique are discussed. Recent experimental field measurements obtained in coastal waters and on a trans-Atlantic/Mediterranean research cruise are correlated with theoretical expectations. It is concluded that the Raman technique for remote sensing of subsurface water temperature has been brought from theoretical and laboratory stages to the point where practical utilization can now be developed.
The paper presents the water depth measurement using an airborne pulsed neon laser system. The results of initial base-line field test results of NASA airborne oceanographic lidar in the bathymetry mode are given, with water-truth measurements of depth and beam attenuation coefficients by boat taken at the same time as overflights to aid in determining the system's operational performance. The nadir-angle tests and field-of-view data are presented; this laser bathymetry system is an improvement over prior models in that (1) the surface-to-bottom pulse waveform is digitally recorded on magnetic tape, and (2) wide-swath mapping data may be routinely acquired using a 30 deg full-angle conical scanner.
A coaxial dual-channel laser system has been developed for the measurement of extinction coefficients of highly absorbing liquids. An empty wedge-shaped sample cell is first translated laterally through a He-Ne laser beam to measure the differential thickness using interference fringes in reflection. The wedge cell is carefully filled with the oil sample and translated through the coaxially positioned dye laser beam for the differential attenuation or extinction measurement. Optional use of the instrumentation as a single-channel extinction measurement system and also as a refractometer is detailed. The system and calibration techniques were applied to the measurement of two crude oils whose extinction values were required to complete the analysis of airborne laser data gathered over four controlled spills.