Materials Data on HoC3S3(O2F)9 by Materials Project
HoO9(CF3)3(SO3)3 crystallizes in the hexagonal P6_3/m space group. The structure is zero-dimensional and consists of six fluoroform molecules, six sulfur trioxide molecules, and two HoO9 clusters. In each HoO9 cluster, Ho is bonded in a 9-coordinate geometry to nine O atoms. There are six shorter (2.30 Å) and three longer (2.31 Å) Ho–O bond lengths. There are two inequivalent O sites. In the first O site, O is bonded in a single-bond geometry to one Ho atom. In the second O site, O is bonded in a single-bond geometry to one Ho atom.
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