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At least 19 records
All sourcesNASA NTRSDOE OSTI
NASA NTRS1995

Radiative and Nonradiative Transitions of the Rare-Earth Ions Tm(3+) and Ho(3+) in Y3AI5O12 and LiYF4

The optical spectra of rare earth ions in solids arise primarily from electric and magnetic dipole transitions between stark split multiplets of the 4f(sup N) electronic configuration. Electric dipole transitions are parity forbidden between levels of the 4f(sup N) configuration, while those of magnetic dipole origin are allowed. It is known from experiment, however, that the significant contributions to the intensities of most transitions are electric dipole in nature. Judd and Ofelt developed the theory of forced electric dipole transitions of rare-earth ions. This study is devoted to determining electric dipole transition probabilities and branching ratios for Tm(3+) and Ho(3+) ions in Yttrium Aluminum Garnet (YAG) and Yttrium Lithium Fluoride (YLF) using the theory of Judd and Ofelt. The radiative rates determined from the Judd-Ofelt analysis are used with measured lifetimes to find nonradiative rates of relaxation.

Walsh, Brian M.↗
NASA NTRS1991

Energy transfer processes between Tm(3+) and Ho(3+) in LiYF4

The spectroscopic properties of the crystal LiYF4 doped with Thulium (Tm) and Holmium (Ho) ions are studied. The basic processes are discussed that regulate the transfer of energy between these two ions in this crystal. In this system Tm is considered the donor ion and the Ho the acceptor ion. Spectral data were obtained on three samples available: LiYF4:Tm(3+) (0.5 percent), LiYF4:Ho(3+) (1 percent), and LiYF4:Tm(3+) (5 percent), Ho(3+) (0.2 percent). Spectral data, which include absorption, luminescence, excitation, and the response to pulsed excitation in a wide range of temperatures, allowed to look at the energy transfer processes by considering the kinetic evolution of the emission of the two ions (donor and acceptor) involved in the process and the basic spectroscopic properties related to them. This inclusive approach has led to the validation of the physical model.

Oezen, Goenuel↗
NASA NTRS1995

Spectroscopy and excitation dynamics of the trivalent lanthanides Tm(3+) and Ho(3+) in LiYF4

A detailed study of the spectroscopy and excitation dynamics Tm3+ and Ho3+ in yttrium lithium fluoride, LiYF4 (YLF), has been done. Absorption spectroscopy is utilized in the Judd-Ofelt theory to determine radiative transition rates of spontaneous emission. Luminescence spectroscopy is studied under cw diode laser excitation at 785nm. The effect of dopant ion concentration and excitation power on the observed luminescence are considered in these measurements. An analysis of these measurements have been used to determine channels of energy transfer between Tm3+ and Ho3+ ions. The temporal response of Tm and Ho in singly and co-doped YLF to pulsed laser excitation with a Ti:Al2O3 laser and a CoMgF2 laser turned to various wavelengths have also been studied. The energy transfer mechanisms of cross relaxation, upconversion, and resonant energy transfer between Tm3+ and Ho3+ ions have been modeled, and the model parameters extracted by a fitting procedure to the measured temporal response curves. Rate equation approaches to modeling are presented that result in predictions of rate constants for energy transfer processes, as well as more conventional approaches to modeling such as the Forster-Dexter models, which give the interaction strengths in terms of microscopic interaction parameters.

Walsh, Brian M.↗
NASA NTRS1991

Theoretical branching ratios for the 5I7 to 5I7 levels of Ho(3+) in the garnets A3B2C3O12 (A = Y,La,Lu,Gd; B = Al,Lu,Sc,Ga; C = Al,Ga)

Results are reported from an experimental study investigating triply ionized holmium in 10 garnets using the point-change model to predict theoretical energy levels and temperature-dependent branching ratios for the 5I7 to 5I8 manifolds for temperatures between 50 and 400 K. Plots were made for the largest lines at 300 K. YScAG was plotted twice, once for each set of X-ray data available. Energy levels are predicted based on theoretical crystal-field parameters, and good agreement to experiment is found. It is suggested that the present set of theoretical crystal-field parameters provides good estimates of the energy levels for the other hosts on which there are no experimental optical data. X-ray and index-of-refraction data are used to evaluate the performance of 10 lasers via a quantum mechanical model to predict the position of the energy levels and the temperature-dependent branching rations of the 5I7 to 5I8 levels of holmium. The fractional population inversion required for threshold is also evaluated.

Filer, Elizabeth D.↗
NASA NTRS1995

Thermal Line Shift and Broadening of Ho(3+) in Y3AI5O12 and Lu3AIO12

The interaction between the active ion and the host lattice manifests itself in two distinct ways: the static interaction with the crystal field that causes the splitting of the free ion energy levels and the active interaction through the surrounding phonon system that produces temperature dependent characteristics in the optical spectrum of the ion (e.g. line broadening and line shift). The strength of the splitting depends heavily on the electronic configuration of the atom. The model give by McCumber and Sturge describes the thermal effects on line width and position above 77 K with Raman scattering of Debye model phonons. These processes predict a Lorentzian line shape. However, below 77 K the principal contributions are from crystal inhomogeneities that result in a Gaussian line shape. We have investigated the experimental Stark levels as well as the thermal effects on the line width and the position of trivalent holmium ions in both yttrium aluminum garnet, Y3Al5O12 (YAG) and lutetium aluminum garnet, Lu3Al5O12 (LuAG) crystals. We have compared the Stark levels of the (5)I(6) state, and the thermal line shift and broadening of an isolated transition (Z2 to X13) between the (5)I(8) and (5)I(6) stark levels in these crystals. This transition occurs in the near infrared region at approximately 1117 nm.

Snoke, Elizabeth R.↗
NASA NTRS1989

Development of flashlamp-pumped Q-switched Ho:Tm:Cr:YAG lasers for mid-infrared LIDAR application

A flashlamp-pumped 2.1 micron Ho:Tm:Cr:YAG laser was studied for both normal mode and Q-switched operations under a wide variety of experimental conditions in order to optimize performance. Laser output energy, slope efficiency, threshold and pulselength were determined as a function of operating temperature, output mirror reflectivity, input electrical energy and Q-switch opening time. The measured normal-mode laser thresholds of a Ho(3+) (0.45 atomic percent):Tm(3+) (2.5 atomic percent):Cr(3+) (0.8 atomic percent):YAG crystal ranged form 26 to 50 J between 120 and 200 K with slope efficiencies up to 0.36 percent with a 60 percent reflective output mirror. Under Q-switched operation the slope efficiency was 90 percent of the normal-mode result. Development of solid state lasers with Ho(3+), Tm(3+) and/or Er(3+) doped crystals has been pursued by NASA for eye-dafe mid-infrared LIDAR (light detection and ranging) application. As a part of the project, the authors have been working on evaluating Ho(3+):Tm(3+):Cr(3+):YAG crystals for normal-mode and Q-switched 2.1 micron laser operations in order to determine an optimum Tm(3+) concentration under flashlamp pumping conditions. Lasing properties of the Ho(3+) in the mid-infrared region have been studied by many research groups since the early 1960's. However, the technology of those lasers is still premature for lidar application. In order to overcome the inefficiency related to narrow absorption bands of the Ho(3+), Tm(3+) and Er(3+), the erbium has been replaced by chromium. The improvement in flashlamp-pumped Ho(3+) laser efficiency has been demonstrated recently by several research groups by utilizing the broad absorption spectrum of Cr(3+) which covers the flashlamp's emission spectrum. Efficient energy transfer to the Tm(3+) and then the Ho(3+) occurs subsequently. It is known that high Tm(3+) concentration and low Ho(3+) concentration are preferred to achieve a quantum efficiency approaching two and to avoid large reabsorption losses. However, determination of the optimum Tm(3+) concentration required to ensure efficient energy transfer from Cr(3+) to Tm(3+) and from Tm(3+) to Ho(3+) has not been made in the Ho:Tm:CR:YAG crystal. The results obtained so far are given.

Choi, Young S.↗
NASA NTRS1994

Development of infrared sensors using energy transfer/energy upconversion processes: Study of laser excited fluorescence in rare Earth ion doped crystals

A summary is presented of the spectroscopic study of three systems: LaF3:Ho(3+), LaF3:Er(3+) and CaF2:Nd(3+). When the D levels of Ho(3+) in LaF3 were resonantly excited with a laser beam of 640 nm, upconverted emissions were detected from J (416 nm), F (485 nm), and E (546 nm) levels. Energy upconverted emissions were also observed from F and E levels of Ho(3+) when the material was excited with an 800 nm near infrared laser. When the D levels of Er(3+) in LaF3 were resonantly excited with a laser beam of 637 nm, upconverted emissions were detected from the E (540 nm) and P (320, 400, and 468 nm) levels. Energy upconverted emissions were also observed from F, E, and D levels of Er(3+) when the material was resonantly excited with an 804 nm near infrared laser. When the D levels of Nd(3+) in CaF2 were resonantly excited with a laser beam of 577 nm, upconverted emissions were detected from the L (360 and 382 nm), K (418 nm), and I (432 nm) levels. Very weak upconverted emissions were detected when this system was irradiated with a near infrared laser. The numbers in parentheses are the wavelengths of the emissions.

Nash-Stevenson, S. K.↗
NASA NTRS1989

Development of mid-infrared solid state lasers for spaceborne lidar

Laser performance of Ho(3+):Tm(3+):Cr(3+):YAG crystals was investigated under both Cr:GSAG laser and flashlamp pumping. A flashlamp pumped Cr:GSAG laser was built to simulate high power quasi-CW laser diode pumping of a 2.1 micrometer holmium laser. The 2.1 micrometer output laser energy exceeded more than 14 mJ, the highest value reported to date under laser pumping near 785 nm. This was obtained in a pulse length of nearly 650 microsec from a 3 x 3 mm Ho:Tm:Cr:YAG rod by using the flashlamp-pumped Cr:CSAG laser as a pumping source at the diode laser wavelength, 785 micrometers. In addition, Ho:Tm:Cr:YAG crystals with various Tm(3+) concentrations were evaluated for flashlamp-pumped normal mode and Q-switched 2.1 micrometer laser operations under a wide variety of experimental conditions in order to understand internal dynamic processes among the ions and to determine an optimum lasing condition. An increase of the laser slope efficiency was observed with the increase of the Tm(3+) concentration from 2.5 to 4.5 atomic percent. The thermal dependence of the laser performance was also investigated. Q-switched laser output energies corresponding to nearly 100 percent of the normal-mode laser energies were obtained in a strong single spike of 200 ns pulse length by optimizing the opening time of a lithium niobate Q-switch.

Whitney, Donald A.↗
NASA NTRS1990

Development of mid-infrared solid state lasers for spaceborne lidar

Researchers investigated laser performance of Ho(3+):Tm(3+):Cr(3+):YAG crystals under both Cr:GSAG laser and flashlamp pumping. A flashlamp pumped Cr:GSAG laser was built to simulate high power quasi-CW laser diode pumping of a 2.1 micron holmium laser. The 2.1 micron output laser energy exceeded more than 14 mJ, the highest value reported to date under laser pumping near 785 nm. This was obtained in a pulse length of nearly 650 microns from a 3 x 3 mm Ho:Tm:Cr:YAG rod by using the flashlamp-pumped Cr:GSAG laser as a pumping source at the diode laser wavelength, 785 microns. In addition, Ho:Tm:Cr:YAG crystals with various Tm(3+) concentrations have been evaluated for flashlamp-pumped normal mode and Q-switched 2.1 micron laser operations under a wide variety of experimental conditions in order to understand internal dynamic processes among the ions and to determine an optimum lasing condition. An increase of the laser slope efficiency was observed with the increase of the Tm(3+) concentration from 2.5 atomic percent to 4.5 atomic percent. The thermal dependence of the laser performance was also investigated. Q-switched laser output energies corresponding to nearly 100 percent of the normal-mode laser energies were obtained in a strong single spike of 200 ns pulse length by optimizing the opening time of a lithium niobate Q-switch.

Whitney, Donald A.↗
NASA NTRS1989

Development of mid-infrared solid state lasers for spaceborne lidar

The laser performance of a Ho(3+):Tm(3+):Cr(3+):YAG crystal was measured under flashlamp pumping at various operating temperatures. The normal mode laser thresholds of a Ho(3+)(0.45 at. percent):Tm(3+)(2.5 at. percent):Cr(3+)(1.5 at. percent ):YAG crystal were found to range from 26 to 50 J between 120 and 200 K with slope efficiencies up to 0.36 percent with a 60 percent reflective output mirror. From the Q-switched operations a slope efficiency corresponding to 90 percent of the normal mode operation was observed. Laser wavelengths were measured for various operating conditions and fluorescence spectra were obtained at various temperatures in order to help understand the dynamic energy processes among the Ho(3+), Tm(3+), and Cr(3+) ions. A pulse forming network for a flashlamp pumped Cr:GSAG laser, which is to be used as a high power laser diode simulator in rare earth laser pumping, was completed and tested. The network provided critically damped, 1 ms FWHM, square pulses with a rise time of about 160 micrometers at an input electrical energy of 300 J.

Whitney, Donald A.↗
NASA NTRS1995

Ho:Tm:Lu(3)Al(5)O(12) As An Infrared-Laser Material

Material selected on basis of quantum-mechanical modeling of lasing properties. Ho:Tm:Lu(3)Al(5)O(12) features relatively low thermal occupation of lower laser level because this level higher than corresponding levels of most other available laser materials. In addition, it has reasonably large effective cross section for stimulated emission because of contribution of several transitions around central strong transition. Yet another desirable property is its calculated rate of upconversion is lower than those of other laser materials. Inasmuch as upconversion detracts from efficiency of laser, this lower rate of upconversion is highly desirable.

Barnes, Norman P.↗
NASA NTRS1972

Space shuttle: Aerodynamic characteristics of various MDAC space shuttle ascent configurations with parallel burn pressure-fed and SRM boosters. Volume 1: Tanks T1 and T2 ascent configurations

Various space shuttle ascent configurations were tested in a trisonic wind tunnel to determine the aerodynamic characteristics. The ascent configuration consisted of a NASA/MSC 040 orbiter in combination with various HO centerline tank and booster geometries. The aerodynamic interference between components of the space shuttle and the effect on the orbiter aerodynamics was determined. The various aerodynamic configurations tested were: (1) centerline HO tanks T1 and T2, (2) centerline HO tank T3, and (3) centerline HO tank H4.

Jarrett, T. W.↗
NASA NTRS1986

Measurement of atmospheric HO by a chemical method

The parameters for a chemical technique can be outlined from the following set of desirable goals: (1) sufficient conversion of tracer species A to product B that B can be measured quantitatively in the presence of A and a great excess of air; (2) specificity of reaction such that A is converted to B only by reaction with HO; and (3) sufficient sensitivity for detection that the ambient concentration of HO is not seriously perturbed by the presence of A and B. This proposed study involves finding a chemical reaction specific enough for OH, and a measurement of the product formed. What one wants is a rate constant of about 10 to the -10th power cu cm/s, so that 0.1 percent of the OH will be converted in 100 s. Laboratory studies are needed to find a reaction which will fill this bill, yielding a product in quantity sufficient for precise measurement. This is an extremely fast constant and the search may be difficult. Again there is a question of perturbing the local environment, while still providing a sensitive measurement. Also the temperature and pressure dependence of the reaction rate is a complicated function for many of these species (that is, one must use a RRKM or Troe-based picture), and must be taken into account.

Iyer, R. Subramonia↗
NASA NTRS2006

Energy Levels and Intensity Parameters of Ho3(+) Ions in Y3Al5O12 and Lu3Al5O12

The energy levels of the trivalent lanthanide Ho(sup 3+) in Y3Al5O12 (YAG) and Lu3Al5O12 (LuAG) have been measured. The Stark split levels for the first nine Ho manifolds in these materials have been measured, and the results have been fit to a free ion plus crystal field Hamiltonian to generate a theoretical set of energy levels. Crystal field parameters were varied to determine the best fit between experimental and theoretical energy levels. The energy levels of Ho:LuAG are seen to be very similar to those in Ho:YAG. However, subtle changes resulting from replacing Y(sup 3+) with Lu(sup 3+) in the garnet crystal Y3Al5O12 result in different transition wavelengths in LuAG. This has implications for Ho (sup 5)I7yields (sup 5)I8 lasers operating at approximately 2.1 micrometers. Although the energy levels have been measured previously in Ho:YAG, they have not been measured in Ho:LuAG. A comparison of the energy levels in Ho:YAG measured here show some discrepancies with previous measurements. The consistency of the energy level placement between Ho:LuAG and Ho:YAG indicate that the earlier studies may have some errors in the assignments. Finally, a Judd-Ofelt analysis is performed on Ho:YAG and Ho:LuAG to determine the intensity parameters, and thus, the transition probabilities and branching ratios of the first eight excited manifolds.

Walsh, Brian M.↗
NASA NTRS2002

D-Wave Resonances in Positronium Hydride

The problem of calculating the position and width of the lowest-lying (L = 0, 1) resonances in the Ps + H scattering system has recently been re-examined by the authors [1]. In the model used, resonances axe assumed generated by bound Rydberg states in the closed re-arranged channel [e(+) + H(-)]. This infinite series of Coulomb bound states are shifted somewhat by the coupling with the open scattering channel [Ps + H]. Estimates using this approach, first carried out by one of the authors [2] using a simple form of scattering wavefunction, indicated an anticipated small shift of resonance away from the Rydberg energy in the S-wave (L = 0). More recent results by Ho and Yan [3] using the complex-rotation method showed unexpected significant shifting in the P (L = 1) and D (L = 2)-wave resonance energies from their respective unperturbed values. Our re-calculation of the resonances [I I for L = 0 and I indicates that, in each case, reasonably consistent resonance energies are obtained by coupling the two lowest lying states (IS and 2S for L = 0 and 2P and 3P for L = 1). For each L it is the higher state (2S and 3P, respectively) that produces the resonance. The lower state (1S and 2P, respectively) is effective only in increasing the non-resonant phase shift. In this work we extend the model to L = 2 (D-waves). Our results show that, unlike the S and P-waves, the 313-state alone produces a resonant energy that is very close to the result of Yan and Ho [3]. Inclusion of the 4D-state produces a second resonance in the scattering system shifted up slightly from its unperturbed Rydberg energy.

Drachman, Richard J.↗
NASA NTRS1987

Rare-earth substitution in (BiYCa)3(FeSiGe)5O12 bubble films

The substitution of Y by Sm, Tb, Gd, and Ho in (BiYCa)3 FeSiGe)5O12 bubble garnet is shown to have large effects on the growth-induced anisotropy (GIA). The presently accepted film composition intended for 6-or 8-micron-period bubble memory devices demands partial substitution of Y by Gd and Ho. However, comparing films grown under the same growth conditions, it is observed that YGdHoBilG films posess less (GIA) than their Gd, Ho-free counterparts. Thus, to satisfy (GIA) requirements, the supercooling during growth must be increased by 20 K to 80 K with undesirable effects on defect densities. A new film composition containing Sm, Tb, and Gd has been formulated to satisfy all known material property specifications for 6- or 8-micron-period memory devices. It can be grown with only 45-50 K supercooling.

Luther, L. C.↗
NASA NTRS2000

High Energy Directly Pumped Ho:YLF Laser

The most commonly used crystal architecture to produce 2 micrometer laser is co-doping Ho and Tm into a single host crystal. In this method, the stored energy transfer from the Tm (3)F4 to the Ho (5)I7 manifold is not fast enough to warrant high efficiency for short pulse applications. By separating the Ho and the Tm ions and doping the Tm in YALO3 and the Ho in YLF, we were able to directly pump the Ho (5)I7 manifold with 1.94 micrometers. The Ho:YLF laser has produced 33 mJ at 2.062 micrometers with a quantum efficiency of 0.88. The performance of each laser will be presented.

Petros, Mulugeta↗