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Materials Data on SrHg2 by Materials Project

SrHg2 is hexagonal omega structure-like structured and crystallizes in the hexagonal P6/mmm space group. The structure is three-dimensional. Sr is bonded to twelve equivalent Hg atoms to form a mixture of edge and face-sharing SrHg12 cuboctahedra. All Sr–Hg bond lengths are 3.57 Å. Hg is bonded in a 9-coordinate geometry to six equivalent Sr and three equivalent Hg atoms. All Hg–Hg bond lengths are 2.94 Å.

36 MATERIALS SCIENCE↗

Materials Data on Sr3Hg2 by Materials Project

Sr3Hg2 crystallizes in the tetragonal P4/mbm space group. The structure is three-dimensional. there are two inequivalent Sr sites. In the first Sr site, Sr is bonded in a square co-planar geometry to four equivalent Hg atoms. All Sr–Hg bond lengths are 3.49 Å. In the second Sr site, Sr is bonded to six equivalent Hg atoms to form a mixture of distorted face, edge, and corner-sharing SrHg6 pentagonal pyramids. There are two shorter (3.46 Å) and four longer (3.53 Å) Sr–Hg bond lengths. Hg is bonded in a 8-coordinate geometry to eight Sr atoms.

36 MATERIALS SCIENCE↗

Materials Data on SrHg by Materials Project

SrHg is Tetraauricupride structured and crystallizes in the cubic Pm-3m space group. The structure is three-dimensional. Sr is bonded in a body-centered cubic geometry to eight equivalent Hg atoms. All Sr–Hg bond lengths are 3.49 Å. Hg is bonded in a body-centered cubic geometry to eight equivalent Sr atoms.

36 MATERIALS SCIENCE↗

Materials Data on SrHg2 by Materials Project

SrHg2 crystallizes in the orthorhombic Imma space group. The structure is three-dimensional. Sr is bonded in a 12-coordinate geometry to twelve equivalent Hg atoms. There are a spread of Sr–Hg bond distances ranging from 3.48–3.66 Å. Hg is bonded in a 10-coordinate geometry to six equivalent Sr and four equivalent Hg atoms. There are a spread of Hg–Hg bond distances ranging from 2.97–3.25 Å.

36 MATERIALS SCIENCE↗

Materials Data on SrHg3 by Materials Project

SrHg3 is beta Cu3Ti structured and crystallizes in the orthorhombic Pmmn space group. The structure is three-dimensional. Sr is bonded to twelve Hg atoms to form a mixture of face, edge, and corner-sharing SrHg12 cuboctahedra. There are a spread of Sr–Hg bond distances ranging from 3.38–3.53 Å. There are two inequivalent Hg sites. In the first Hg site, Hg is bonded in a 4-coordinate geometry to four equivalent Sr atoms. In the second Hg site, Hg is bonded in a 4-coordinate geometry to four equivalent Sr atoms.

36 MATERIALS SCIENCE↗

Materials Data on SrHg3 by Materials Project

SrHg3 crystallizes in the orthorhombic Cmcm space group. The structure is three-dimensional. Sr is bonded to twelve Hg atoms to form a mixture of face and corner-sharing SrHg12 cuboctahedra. There are a spread of Sr–Hg bond distances ranging from 3.41–3.58 Å. There are two inequivalent Hg sites. In the first Hg site, Hg is bonded in a 4-coordinate geometry to four equivalent Sr atoms. In the second Hg site, Hg is bonded in a distorted rectangular see-saw-like geometry to four equivalent Sr atoms.

36 MATERIALS SCIENCE↗

Materials Data on SrHg11 by Materials Project

SrHg11 crystallizes in the cubic Pm-3m space group. The structure is three-dimensional. Sr is bonded to twelve Hg atoms to form SrHg12 cuboctahedra that share corners with four equivalent HgHg12 cuboctahedra and corners with eight equivalent SrHg12 cuboctahedra. There are four shorter (3.76 Å) and eight longer (3.82 Å) Sr–Hg bond lengths. There are four inequivalent Hg sites. In the first Hg site, Hg is bonded to twelve equivalent Hg atoms to form distorted HgHg12 cuboctahedra that share corners with twelve equivalent SrHg12 cuboctahedra. All Hg–Hg bond lengths are 3.41 Å. In the second Hg site, Hg is bonded in a 6-coordinate geometry to six Hg atoms. There are three shorter (3.10 Å) and three longer (3.12 Å) Hg–Hg bond lengths. In the third Hg site, Hg is bonded in a distorted q6 geometry to two equivalent Sr and eight Hg atoms. All Hg–Hg bond lengths are 3.21 Å. In the fourth Hg site, Hg is bonded in a 5-coordinate geometry to one Sr and five Hg atoms.

36 MATERIALS SCIENCE↗

Materials Data on SrHg3 by Materials Project

SrHg3 crystallizes in the orthorhombic Cmcm space group. The structure is three-dimensional. Sr is bonded to twelve Hg atoms to form a mixture of corner and face-sharing SrHg12 cuboctahedra. There are a spread of Sr–Hg bond distances ranging from 3.43–3.52 Å. There are two inequivalent Hg sites. In the first Hg site, Hg is bonded in a distorted see-saw-like geometry to four equivalent Sr atoms. In the second Hg site, Hg is bonded in a distorted see-saw-like geometry to four equivalent Sr atoms.

36 MATERIALS SCIENCE↗

Materials Data on Sr3Hg by Materials Project

Sr3Hg is Uranium Silicide structured and crystallizes in the cubic Pm-3m space group. The structure is three-dimensional. Sr is bonded in a distorted square co-planar geometry to four equivalent Hg atoms. All Sr–Hg bond lengths are 3.90 Å. Hg is bonded to twelve equivalent Sr atoms to form a mixture of corner and face-sharing HgSr12 cuboctahedra.

36 MATERIALS SCIENCE↗

Materials Data on Sr3Hg by Materials Project

Sr3Hg is Cementite structured and crystallizes in the orthorhombic Pnma space group. The structure is two-dimensional and consists of two Sr3Hg sheets oriented in the (0, 0, 1) direction. there are two inequivalent Sr sites. In the first Sr site, Sr is bonded in a distorted water-like geometry to two equivalent Hg atoms. There are one shorter (3.37 Å) and one longer (3.41 Å) Sr–Hg bond lengths. In the second Sr site, Sr is bonded in a bent 150 degrees geometry to two equivalent Hg atoms. There are one shorter (3.28 Å) and one longer (3.32 Å) Sr–Hg bond lengths. Hg is bonded in a 6-coordinate geometry to six Sr atoms.

36 MATERIALS SCIENCE↗