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LiPtHg2 crystallizes in the orthorhombic Immm space group. The structure is one-dimensional and consists of two LiPtHg2 ribbons oriented in the (0, 1, 0) direction. Li is bonded in a linear geometry to two equivalent Hg atoms. Both Li–Hg bond lengths are 2.65 Å. Pt is bonded in a linear geometry to two equivalent Hg atoms. Both Pt–Hg bond lengths are 2.69 Å. Hg is bonded in a linear geometry to one Li and one Pt atom.
Li2PtHg crystallizes in the orthorhombic Immm space group. The structure is one-dimensional and consists of two Li2PtHg ribbons oriented in the (1, 0, 0) direction. Li is bonded in a linear geometry to one Pt and one Hg atom. The Li–Pt bond length is 2.29 Å. The Li–Hg bond length is 2.73 Å. Pt is bonded in a linear geometry to two equivalent Li atoms. Hg is bonded in a linear geometry to two equivalent Li atoms.