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HgTlIn2 crystallizes in the orthorhombic Immm space group. The structure is one-dimensional and consists of two HgTlIn2 ribbons oriented in the (1, 0, 0) direction. Hg is bonded in a linear geometry to two equivalent In atoms. Both Hg–In bond lengths are 3.03 Å. Tl is bonded in a linear geometry to two equivalent In atoms. Both Tl–In bond lengths are 2.95 Å. In is bonded in a linear geometry to one Hg and one Tl atom.
Hg2TlIn crystallizes in the orthorhombic Immm space group. The structure is one-dimensional and consists of two Hg2TlIn ribbons oriented in the (1, 0, 0) direction. Hg is bonded in a linear geometry to one Tl and one In atom. The Hg–Tl bond length is 3.11 Å. The Hg–In bond length is 3.03 Å. Tl is bonded in a linear geometry to two equivalent Hg atoms. In is bonded in a linear geometry to two equivalent Hg atoms.