Materials Data on Hg(C2F3)2 by Materials Project
Hg(CF)2(CF2)2 crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two difluoromethane molecules and one Hg(CF)2 cluster. In the Hg(CF)2 cluster, Hg2+ is bonded in a distorted linear geometry to two equivalent C1+ atoms. Both Hg–C bond lengths are 2.09 Å. C1+ is bonded in a distorted single-bond geometry to one Hg2+ and one F1- atom. The C–F bond length is 1.38 Å. F1- is bonded in a single-bond geometry to one C1+ atom.