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Raman Lidar Measurements during the International HZO Project: Instrumentation and Analysis Techniques, Popular Summary - 1

The amount of water vapor in the atmosphere helps to determine the likelihood that severe storms may develop. The concentration of water vapor, though, is highly variable in space and time. And yet small changes in water vapor concentration over a short period of time or over a short spatial distance can determine whether a storm may or may not develop. Therefore, in order to improve the ability to forecast severe weather such as thunderstorms it is important to measure water vapor in the atmosphere with high spatial and temporal resolution. One of the most attractive research tools for measuring water vapor in the atmosphere with high spatial and temporal resolution is a Raman lidar. A Raman lidar consists of a laser transmitter, a telescope receiver and optics and electronics for processing opticand electronic signals. A laser pulse is emitted into the atmosphere and it interacts with molecules in the atmosphere causing them to become excited and to emit, through the Raman process, photons of different wavelength than emitted by the laser. The molecule that emitted these emitted. This is the way that a Raman lidar identifies water vapor molecules in the atmosphere. can be identified based on the wavelength of the photons One of the great challenges in Raman lidar measurements has been to make useful daytime measurements of the water vapor profile under bright daytime conditions. In this first of two papers, we describe the instrumentation and analysis of the first documented Raman lidar that is able to measure water vapor in the daytime with sufficient quality to permit the study of developing storm systems.

Whiteman, D. N.↗

Interaction of the Magnetospheric Ions with the Surfaces of the Icy Satellites of Saturn

The extraordinary connection between the compositions of the surfaces of the satellites and ring particles and the composition of the magnetospheric plasmas in which they are embedded is examined. What may be even more exciting is this connection is being developed and understood via a combination of laboratory and satellite measurements. This interaction has stimulated new research on radiation effects in materials which will be technologically useful. Laboratory measurements have begun to characterize the changes induced in ice by ion and electron bombardment. Most attention was paid to measurements of the atoms and molecules ejected via ion bombardment, but work was initiated on changes in the spectral character of the ice. Recent results on CH4 and mixtures of HZO and CH4 indicate that a considerable amount of chemistry is induced in such ices via bombardment.

Johnson, R. E.↗

A Liquid-Liquid Transition in an Undercooled Ti-Zr-Ni Liquid

If crystallization can be avoided, liquids enter a metastable (undercooled) state below their equilibrium liquidus temperatures, TI, finally freezing into a glass below a characteristic temperature called the glass transition temperature, T,. In rare cases, the undercooled liquid may undergo a liquid-liquid phase transition (liquid polymorphism) before entering the glassy state. This has been suggested from experimental studies of HzO and Si4. Such phase transitions have been predicted in some stable liquids, i.e. above TI at atmospheric pressure, for Si02 and BeF;, but these have not been verified experimentally. They have been observed in liquids of P7, Sis and C9, but only under high pressure. All of these transitions are driven by an anomalous density change, i.e. change in local structure, with temperature or pressure. In this letter we present the first experimental evidence for a phase transition in a low viscosity liquid that is not driven by an anomalous density change, but by an approach to a constant configuration state. A maximum in the specific heat at constant pressure, similar to what is normally observed near T,, is reported here for undercooled low viscosity liquids of quasicrystal- forming Ti-Zr-Ni alloys. that includes cooperativity, by incorporating a temperature dependent excitation energy fits the data well, signaling a phase transition.

Lee, G. W.↗