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At least 19 records

Multi-model Mean Nitrogen and Sulfur Deposition from the Atmospheric Chemistry and Climate Model Intercomparison Project (ACCMIP): Evaluation of Historical and Projected Future Changes

We present multi-model global datasets of nitrogen and sulfate deposition covering time periods from 1850 to 2100, calculated within the Atmospheric Chemistry and Climate Model Intercomparison Project (ACCMIP). The computed deposition fluxes are compared to surface wet deposition and ice-core measurements. We use a new dataset of wet deposition for 2000-2002 based on critical assessment of the quality of existing regional network data. We show that for present-day (year 2000 ACCMIP time-slice), the ACCMIP results perform similarly to previously published multi-model assessments. The analysis of changes between 1980 and 2000 indicates significant differences between model and measurements over the United States, but less so over Europe. This difference points towards misrepresentation of 1980 NH3 emissions over North America. Based on ice-core records, the 1850 deposition fluxes agree well with Greenland ice cores but the change between 1850 and 2000 seems to be overestimated in the Northern Hemisphere for both nitrogen and sulfur species. Using the Representative Concentration Pathways to define the projected climate and atmospheric chemistry related emissions and concentrations, we find large regional nitrogen deposition increases in 2100 in Latin America, Africa and parts of Asia under some of the scenarios considered. Increases in South Asia are especially large, and are seen in all scenarios, with 2100 values more than double 2000 in some scenarios and reaching >1300 mgN/m2/yr averaged over regional to continental scale regions in RCP 2.6 and 8.5, ~30-50% larger than the values in any region currently (2000). Despite known issues, the new ACCMIP deposition dataset provides novel, consistent and evaluated global gridded deposition fields for use in a wide range of climate and ecological studies.

ACCMIP↗

Building a Solar Powered Home in a Historic Neighborhood. A Case Study with CVF Homes, the City of San Antonio Office of Historic Preservation and the Lavaca Neighborhood Association

A Texas collaboration is working to streamline and enable an increase in photovoltaic capacity. The City of San Antonio has made tremendous progress in recent years in the area of solar energy installations on residences. These projects have been great successes, though not without the usual challenges associated with solar energy installations. The City has also seen an increased interest in solar energy systems in official “historic” neighborhoods. These installations have a potential for added challenges, as neighborhoods designated “historic” have additional restrictions, aside from standard building codes, about what changes and upgrades can be done to the exterior. This is in an effort to maintain the historic qualities of the homes and preserve the historical nature of the neighborhoods in which they are present. The purpose of this case study was to examine the construction of a new, single family home, with an included solar energy system, in an official historic neighborhood in San Antonio. Build San Antonio Green hoped to uncover what specific additional challenges the builder faced when working in a historic neighborhood and how those challenges were overcome, to serve as a model for other builders wishing to install solar energy systems in historic neighborhoods. This is of particular importance, as the City of San Antonio has more than 20 officially designated historic neighborhoods, and without proper knowledge of how to comply with the additional regulations, contractors, builders, and solar installers could potentially miss out on tremendous opportunities.

14 SOLAR ENERGY↗

Implementing Solar PV Projects on Historic Buildings and in Historic Districts

Many municipalities, particularly in older communities of the United States, have a large amount of historic buildings and districts. In addition to preserving these historic assets, many municipalities have goals or legislative requirements to procure a certain amount of energy from renewable sources and to become more efficient in their energy use; often, these requirements do not exempthistoric buildings. This paper details findings from a workshop held in Denver, Colorado, in June 2010 that brought together stakeholders from both the solar and historic preservation industries. Based on these findings, this paper identifies challenges and recommends solutions for developing solar photovoltaic (PV) projects on historic buildings and in historic districts in such a way as to notaffect the characteristics that make a building eligible for historic status.

14 SOLAR ENERGY↗

Decommissioning of a facility in a historical reactor at SRS: achieving both historical significance preservation and effective in-situ decommissioning - 15275

The Savannah River Site (SRS) is an 802 square-kilometer United States Department of Energy (US DOE) nuclear facility located along the Savannah River near Aiken, South Carolina, where Management and Operations are performed by Savannah River Nuclear Solutions, LLC (SRNS). In 2004, US DOE recognized SRS as a structure within the Cold War Historic District of national, state and local significance because it is composed of the first generation of facilities constructed and operated from 1950 through 1989 to produce plutonium and tritium for our nation's defense. US DOE agreed to manage the SRS 105-C Reactor Facility as a potentially historic property due to its significance in supporting the U.S. Cold War Mission and for potential for future interpretation. The Disassembly Basin (DB) in C Reactor was evaluated for action under CERCLA. Data indicated there were over 830 curies of radioactivity associated with the basin sediments and approximately 9.1 million (M) liters (L) of contaminated water, not including a large quantity of activated reactor equipment, scrap metal, and debris on the basin floor. The release of DB water could potentially migrate to the aquifer and contaminate groundwater. The need for an action was identified to reduce risks to personnel in the facility and to eliminate the possible release of contaminants into the environment. In-situ decommissioning was selected as the remedy. The remedial action proceeded in stages: -Above-grade modifications to the interior of DB building -Relocation of irradiated scrap and reactor components to the deepest segments of the DB - Construction of a metal building to house evaporators - Forced evaporation of the DB's radiologically contaminated water - Grouting with special hybrid grouts - Removal of the evaporators and temporary building. Since the building itself was not demolished and will remain unchanged in appearance with the exception of filling the DB with grout, this ISD removal action/methodology did not adversely impact the historical significance of the 105-C Reactor Building, in accordance with the National Historic Preservation Act, nor did it adversely affect the ability to determine the full extent and details of preservation at some later date. Both special hybrid grout materials met all requirements. Overall average 7-day compressive strength for the dry area mix was 1.54 MPa (223 psi) and for the underwater mix 2.94 MPa (427 psi).Overall 28-day compressive strength for the dry area mix was 2.88 MPa (417 psi) and for the underwater mix 4.99 MPa (724 psi). A limited amount of testing was also performed at 91 days, where the overall compressive strength for the dry area mix was found to be 9.40 MPa (1363 psi) and for the underwater mix 13.98 MPa (2028 psi). All compressive strength values far exceeded the 0.34 MPa (50 psi) minimum requirements. The special, flowable-fill grouts designed and used for P- and R-Reactor ISD and used again for this 105-C ISD removal action resulted in considerable labor, cost, and schedule savings versus conventional materials. As an added bonus/benefit, the CO{sub 2} footprint of the SRS C-Reactor DB ISD was minimized by using a small amount of cement and byproduct material to produce the structural fill materials. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Cascadia Burning: The historic, but not historically unprecedented, 2020 wildfires in the Pacific Northwest, USA

Abstract Wildfires devastated communities in Oregon and Washington in September 2020, burning almost as much forest west of the Cascade Mountain crest (“the westside”) in 2 weeks (~340,000 ha) as in the previous five decades (~406,00 ha). Unlike dry forests of the interior western United States, temperate rain forests of the Pacific Northwest have experienced limited recent fire activity, and debates surrounding what drove the 2020 fires, and management strategies to adapt to similar future events, necessitate a scientific evaluation of the fires. We evaluate five questions regarding the 2020 Labor Day fires: (1) How do the 2020 fires compare with historical fires? (2) How did the roles of weather and antecedent climate differ geographically and from the recent past (1979–2019)? (3) How do fire size and severity compare to other recent fires (1985–2019), and how did forest management and prefire forest structure influence burn severity? (4) What impact will these fires have on westside landscapes? and (5) How can we adapt to similar fires in the future? Although 5 of the 2020 fires were much larger than any others in the recent past and burned ~10 times the area in high‐severity patches >10,000 ha, the 2020 fires were remarkably consistent with historical fires. Reports from the early 1900s, along with paleo‐ and dendro‐ecological records, indicate similar and potentially even larger wildfires over the past millennium, many of which shared similar seasonality (late August/early September), weather conditions, and even geographic locations. Consistent with the largest historical fires, strong east winds and anomalously dry conditions drove the rapid spread of high‐severity wildfire in 2020. We found minimal difference in burn severity among stand structural types related to previous management in the 2020 fires. Adaptation strategies for similar fires in the future could benefit by focusing on ignition prevention, fire suppression, and community preparedness, as opposed to fuel treatments that are unlikely to mitigate fire severity during extreme weather. While scientific uncertainties remain regarding the nature of infrequent, high‐severity fires in westside forests, particularly under climate change, adapting to their future occurrence will require different strategies than those in interior, dry forests.

Reilly, Matthew J.↗

Large historical growth in global terrestrial gross primary production

Growth in terrestrial gross primary production (GPP) may provide a negative feedback for climate change. It remains uncertain, however, to what extent biogeochemical processes can suppress global GPP growth. In consequence, model estimates of terrestrial carbon storage and carbon cycle –climate feedbacks remain poorly constrained. Here we present a global, measurement-based estimate of GPP growth during the twentieth century based on long-term atmospheric carbonyl sulphide (COS) records derived from ice core, firn, and ambient air samples. Here, we interpret these records using a model that simulates changes in COS concentration due to changes in its sources and sinks, including a large sink that is related to GPP. We find that the COS record is most consistent with climate-carbon cycle model simulations that assume large GPP growth during the twentieth century (31% ± 5%; mean ± 95% confidence interval). Finally, while this COS analysis does not directly constrain estimates of future GPP growth it provides a global-scale benchmark for historical carbon cycle simulations.

54 ENVIRONMENTAL SCIENCES↗

The role of environmental driving factors in historical and projected carbon dynamics of wetland ecosystems in Alaska

Abstract Wetlands are critical terrestrial ecosystems in Alaska, covering ~177,000 km 2 , an area greater than all the wetlands in the remainder of the United States. To assess the relative influence of changing climate, atmospheric carbon dioxide (CO 2 ) concentration, and fire regime on carbon balance in wetland ecosystems of Alaska, a modeling framework that incorporates a fire disturbance model and two biogeochemical models was used. Spatially explicit simulations were conducted at 1‐km resolution for the historical period (1950–2009) and future projection period (2010–2099). Simulations estimated that wetland ecosystems of Alaska lost 175 Tg carbon (C) in the historical period. Ecosystem C storage in 2009 was 5,556 Tg, with 89% of the C stored in soils. The estimated loss of C as CO 2 and biogenic methane (CH 4 ) emissions resulted in wetlands of Alaska increasing the greenhouse gas forcing of climate warming. Simulations for the projection period were conducted for six climate change scenarios constructed from two climate models forced under three CO 2 emission scenarios. Ecosystem C storage averaged among climate scenarios increased 3.94 Tg C/yr by 2099, with variability among the simulations ranging from 2.02 to 4.42 Tg C/yr. These increases were driven primarily by increases in net primary production (NPP) that were greater than losses from increased decomposition and fire. The NPP increase was driven by CO 2 fertilization (~5% per 100 parts per million by volume increase) and by increases in air temperature (~1% per °C increase). Increases in air temperature were estimated to be the primary cause for a projected 47.7% mean increase in biogenic CH 4 emissions among the simulations (~15% per °C increase). Ecosystem CO 2 sequestration offset the increase in CH 4 emissions during the 21st century to decrease the greenhouse gas forcing of climate warming. However, beyond 2100, we expect that this forcing will ultimately increase as wetland ecosystems transition from being a sink to a source of atmospheric CO 2 because of (1) decreasing sensitivity of NPP to increasing atmospheric CO 2 , (2) increasing availability of soil C for decomposition as permafrost thaws, and (3) continued positive sensitivity of biogenic CH 4 emissions to increases in soil temperature.

Lyu, Zhou↗

Historical Building Stability Monitoring by Means of a Cosmic Ray Tracking System

Cosmic ray radiation is mostly composed, at sea level, by high energy muons, which are highly penetrating particles capable of crossing kilometers of rock. The ubiquitous and steady presence at the Earth's surface and the high penetration capability have motivated the use of cosmic ray radiation also in fields beyond particle physics, from geology, archaeology, speleology to industrial applications and homeland security. In particular, in recent years, the novel technique of muon tomography has been proposed, with the aim of performing non invasive inspection of large non accessible volumes, material atomic number Z and density discrimination, and three dimension image reconstruction of the inspected volume. In the present paper, after a short recall of the physical principles and mathematical formalism on which muon tomography is based, a number of examples of application of the novel technique in industry and homeland security issues is given. Moreover, a new application of cosmic rays detection techniques in the field of civil engineering is proposed. The aim is the monitoring of the stability of large structures, in particular the static monitoring of historical buildings, where conservation constraints are more severe and the time evolution of the deformation phenomena under study may be of the order of months or years. The new technique may be seen, in some way, as the reverse problem of muon tomography. As a significant case study, the monitoring of the wooden vaulted roof of the Palazzo della Loggia in the town of Brescia, in Italy, has been considered. The feasibility as well as the performances and limitations of a monitoring system based on cosmic ray tracking have been studied by Monte Carlo simulation and discussed in comparison with more traditional monitoring systems. (authors)

42 ENGINEERING↗

Noninvasive Synchrotron-Based X-ray Raman Scattering Discriminates Carbonaceous Compounds in Ancient and Historical Materials [ In situ synchrotron-based X-Ray Raman scattering discriminates carbonaceous compounds in ancient and historical materials]

Carbon compounds are ubiquitous and occur in a diversity of chemical forms in many systems including ancient and historic materials ranging from cultural heritage to paleontology. Determining their speciation cannot only provide unique information on their origin but may also elucidate degradation processes. Synchrotron-based X-ray absorption near-edge structure (XANES) spectroscopy at the carbon K-edge (280–350 eV) is a very powerful method to probe carbon speciation. However, the short penetration depth of soft X-rays imposes stringent constraints on sample type, preparation, and analytical environment. A hard X-ray probe such as X-ray Raman scattering (XRS) can overcome many of these difficulties. Here we report the use of XRS at ~6 keV incident energy to collect carbon K-edge XANES data and probe the speciation of organic carbon in several specimens relevant to cultural heritage and natural history. This methodology enables the measurement to be done in a nondestructive way, in air, and provides information that is not compromised by surface contamination by ensuring that the dominant signal contribution is from the bulk of the probed material. Using the backscattering geometry at large photon momentum transfer maximizes the XRS signal at the given X-ray energy and enhances nondipole contributions compared to conventional XANES, thereby augmenting the speciation sensitivity. The capabilities and limitations of the technique are discussed. As a result, we show that despite its small cross section, for a range of systems the XRS method can provide satisfactory signals at realistic experimental conditions. XRS constitutes a powerful complement to FT-IR, Raman, and conventional XANES spectroscopy, overcoming some of the limitations of these techniques.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Reaction of Pb(II) and Zn(II) with Ethyl Linoleate To Form Structured Hybrid Inorganic–Organic Complexes: A Model for Degradation in Historic Paint Films

To investigate soap formation in drying oils in historic paints, the reaction between metal acetates (K + , Zn 2+ , Pb 2+ ) and ethyl linoleate (EL) was studied using optical microscopy, X-ray powder diffraction, and electron microscopy. Pb(II) and Zn(II) react rapidly with EL to form highly structured, spherulitic, luminescent crystallites that aggregate. Evidence from Fourier transform infrared (FTIR) and scanning electron microscopy/energy dispersive X-ray analysis and high-resolution synchrotron powder X-ray diffraction indicates that these are organic–inorganic hybrid complexes or coordination polymers. FTIR absorbance peaks at ca. 1540 cm –1 for Pb(II) and ca. 1580 cm –1 for Zn(II) are consistent with the formation of carboxylate complexes. The complexes formed offer insight into the degradation processes observed in oil paint films, suggesting that soap formation is rapid when metal ions are solubilized and can occur with unsaturated fatty acids that are present in fresh oils. These complexes may account for the atypical luminescence observed in lead-containing cured oil paint films.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Complete Genome Sequences of Historic Clostridioides difficile Food-Dwelling Ribotype 078 Strains in Canada Identical to That of the Historic Human Clinical Strain M120 in the United Kingdom

Here, Clostridioides (Clostridium) difficile is a spore-forming anaerobic bacterium that causes severe intestinal diseases in humans. Here, we report the complete genome sequence of the first C. difficile foodborne type strain (PCR ribotype 078) isolated from food animals in Canada in 2004, which has 100% similarity to the genome sequence of the historic human clinical strain M120.

59 BASIC BIOLOGICAL SCIENCES↗

Historic Buildings Report: Five-Year Preservation Planning for Manhattan Project National Historical Park Sites

This report offers a preservation maintenance plan for the next five years for buildings and structures included in or eligible for inclusion in the Manhattan Project National Historical Park at Los Alamos National Laboratory. There are twenty-three buildings, structures, and ruins of previously standing buildings covered within this report. Many of the preservation maintenance issues addressed here concern problems with health and live safety of staff and visitors alike, and also structural concerns that affect the long-term preservation of these important buildings.

42 ENGINEERING↗

Historic American engineering record. Nevada national security site, Bren Tower Complex. Written historical and descriptive data and field records

The BREN (Bare Reactor Experiment, Nevada) Tower Complex is significant for its role in the history of nuclear testing, radiation dosimetry studies, and early field testing of the Strategic Missile Defense System designs. At the time it was built in 1962, the 1,527 ft (465 m) BREN Tower was the tallest structure west of the Mississippi River and exceeded the height of the Empire State Building by 55 ft (17 m). It remains the tallest ever erected specifically for scientific purposes and was designed and built to facilitate the experimental dosimetry studies necessary for the development of accurate radiation dose rates for the survivors of Hiroshima and Nagasaki. The tower was a key component of the Atomic Bomb Casualty Commission’s (ABCC) mission to predict the health effects of radiation exposure. Moved to its current location in 1966, the crucial dosimetry studies continued with Operation HENRE (High Energy Neutron Reactions Experiment). These experiments and the data they generated became the basis for a dosimetry system called the Tentative 1965 Dose or more commonly the T65D model. Used to estimate radiation doses received by individuals, the T65D model was applied until the mid-1980s when it was replaced by a new dosimetry system known as DS86 based on the Monte Carlo method of dose rate calculation. However, the BREN Tower data are still used for verification of the validity of the DS86 model. In addition to its importance in radiation heath effects research, the BREN Tower Complex is also significant for its role in the Brilliant Pebbles research project, a major component of the Strategic Defense Initiative popularly known as the “Star Wars” Initiative. Instigated under the Reagan Administration, the program’s purpose was to develop a system to shield the United States and allies from a ballistic missile attack. The centerpiece of the Strategic Defense System was space-based, kinetic-kill vehicles. In 1991, BREN Tower was used for the tether tests of the Brilliant Pebbles prototype vehicle at the earth’s surface prior to the more costly space testing program. The success of these tests established the Brilliant Pebbles program as an essential component of America’s space-based missile defense system even after the dismantling of the Soviet Union. Data from the Brilliant Pebbles research program continues to inspire current missile defense system research (Independent Working Group 2009).

54 ENVIRONMENTAL SCIENCES↗