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NH3 is Ammonia structured and crystallizes in the cubic P2_13 space group. The structure is zero-dimensional and consists of four ammonia molecules. N3- is bonded in a trigonal non-coplanar geometry to three equivalent H1+ atoms. All N–H bond lengths are 1.03 Å. H1+ is bonded in a single-bond geometry to one N3- atom.
NH3 is Ammonia-like structured and crystallizes in the orthorhombic P2_12_12_1 space group. The structure is zero-dimensional and consists of four ammonia molecules. N3- is bonded in a trigonal non-coplanar geometry to three H1+ atoms. All N–H bond lengths are 1.03 Å. There are two inequivalent H1+ sites. In the first H1+ site, H1+ is bonded in a single-bond geometry to one N3- atom. In the second H1+ site, H1+ is bonded in a single-bond geometry to one N3- atom.
Li(NH3)4 is Silicon tetrafluoride-derived structured and crystallizes in the cubic I-43d space group. The structure is zero-dimensional and consists of sixteen Li(NH3)4 clusters. Li1+ is bonded in a tetrahedral geometry to four N+2.75- atoms. There are three shorter (2.12 Å) and one longer (2.13 Å) Li–N bond lengths. There are two inequivalent N+2.75- sites. In the first N+2.75- site, N+2.75- is bonded to one Li1+ and three equivalent H+0.83+ atoms to form distorted corner-sharing NLiH3 tetrahedra. All N–H bond lengths are 1.03 Å. In the second N+2.75- site, N+2.75- is bonded to one Li1+ and three H+0.83+ atoms to form distorted corner-sharing NLiH3 tetrahedra. All N–H bond lengths are 1.03 Å. There are four inequivalent H+0.83+ sites. In the first H+0.83+ site, H+0.83+ is bonded in a single-bond geometry to one N+2.75- atom. In the second H+0.83+ site, H+0.83+ is bonded in a single-bond geometry to one N+2.75- atom. In the third H+0.83+ site, H+0.83+ is bonded in a single-bond geometry to one N+2.75- atom. In the fourth H+0.83+ site, H+0.83+ is bonded in a single-bond geometry to one N+2.75- atom.
(Li(NH3)4)3(P)11(NH3)5 crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of ten ammonia molecules, six Li(NH3)4 clusters, and two P clusters. In two of the Li(NH3)4 clusters, Li is bonded in a tetrahedral geometry to four N atoms. There are a spread of Li–N bond distances ranging from 2.04–2.10 Å. There are four inequivalent N sites. In the first N site, N is bonded to one Li and three H atoms to form distorted corner-sharing NLiH3 tetrahedra. All N–H bond lengths are 1.03 Å. In the second N site, N is bonded to one Li and three H atoms to form distorted corner-sharing NLiH3 tetrahedra. There is two shorter (1.02 Å) and one longer (1.03 Å) N–H bond length. In the third N site, N is bonded to one Li and three H atoms to form distorted corner-sharing NLiH3 tetrahedra. All N–H bond lengths are 1.03 Å. In the fourth N site, N is bonded to one Li and three H atoms to form distorted corner-sharing NLiH3 tetrahedra. All N–H bond lengths are 1.03 Å. There are twelve inequivalent H sites. In the first H site, H is bonded in a single-bond geometry to one N atom. In the second H site, H is bonded in a single-bond geometry to one N atom. In the third H site, H is bonded in a single-bond geometry to one N atom. In the fourth H site, H is bonded in a single-bond geometry to one N atom. In the fifth H site, H is bonded in a single-bond geometry to one N atom. In the sixth H site, H is bonded in a single-bond geometry to one N atom. In the seventh H site, H is bonded in a single-bond geometry to one N atom. In the eighth H site, H is bonded in a single-bond geometry to one N atom. In the ninth H site, H is bonded in a single-bond geometry to one N atom. In the tenth H site, H is bonded in a single-bond geometry to one N atom. In the eleventh H site, H is bonded in a single-bond geometry to one N atom. In the twelfth H site, H is bonded in a single-bond geometry to one N atom. In four of the Li(NH3)4 clusters, Li is bonded in a tetrahedral geometry to four N atoms. There are a spread of Li–N bond distances ranging from 2.05–2.07 Å. There are four inequivalent N sites. In the first N site, N is bonded to one Li and three H atoms to form distorted corner-sharing NLiH3 tetrahedra. There is one shorter (1.02 Å) and two longer (1.03 Å) N–H bond length. In the second N site, N is bonded to one Li and three H atoms to form distorted corner-sharing NLiH3 tetrahedra. There is two shorter (1.02 Å) and one longer (1.03 Å) N–H bond length. In the third N site, N is bonded to one Li and three H atoms to form distorted corner-sharing NLiH3 tetrahedra. There is two shorter (1.02 Å) and one longer (1.03 Å) N–H bond length. In the fourth N site, N is bonded to one Li and three H atoms to form distorted corner-sharing NLiH3 tetrahedra. There is one shorter (1.02 Å) and two longer (1.03 Å) N–H bond length. There are twelve inequivalent H sites. In the first H site, H is bonded in a single-bond geometry to one N atom. In the second H site, H is bonded in a single-bond geometry to one N atom. In the third H site, H is bonded in a single-bond geometry to one N atom. In the fourth H site, H is bonded in a single-bond geometry to one N atom. In the fifth H site, H is bonded in a single-bond geometry to one N atom. In the sixth H site, H is bonded in a single-bond geometry to one N atom. In the seventh H site, H is bonded in a single-bond geometry to one N atom. In the eighth H site, H is bonded in a single-bond geometry to one N atom. In the ninth H site, H is bonded in a single-bond geometry to one N atom. In the tenth H site, H is bonded in a single-bond geometry to one N atom. In the eleventh H site, H is bonded in a single-bond geometry to one N atom. In the twelfth H site, H is bonded in a single-bond geometry to one N atom. In each P cluster, there are eleven inequivalent P sites. In the first P site, P is bonded in a trigonal non-coplanar geometry to three P atoms. There are a spread of P–P bond distances ranging from 2.17–2.27 Å. In the second P site, P is bonded in a trigonal non-coplanar geometry to three P atoms. There are a spread of P–P bond distances ranging from 2.17–2.26 Å. In the third P site, P is bonded in a trigonal non-coplanar geometry to three P atoms. There are a spread of P–P bond distances ranging from 2.18–2.27 Å. In the fourth P site, P is bonded in a trigonal non-coplanar geometry to three P atoms. There are one shorter (2.17 Å) and one longer (2.28 Å) P–P bond lengths. In the fifth P site, P is bonded in a trigonal non-coplanar geometry to three P atoms. There are one shorter (2.18 Å) and one longer (2.26 Å) P–P bond lengths. In the sixth P site, P is bonded in a trigonal non-coplanar geometry to three P atoms. There are one shorter (2.18 Å) and one longer (2.27 Å) P–P bond lengths. In the seventh P site, P is bonded in a trigonal non-coplanar geometry to three P atoms. In the eighth P site, P is bonded in an L-shaped geometry to two P atoms. In the ninth P site, P is bonded in an L-shaped geometry to two P atoms. In the tenth P site, P is bonded in a trigonal non-coplanar geometry to three P atoms. In the eleventh P site, P is bonded in an L-shaped geometry to two P atoms.
Rb4(NH3)5(Ge)9 crystallizes in the monoclinic P2_1/c space group. The structure is two-dimensional and consists of thirty-six germanium molecules and two Rb4(NH3)5 sheets oriented in the (0, 0, 1) direction. In each Rb4(NH3)5 sheet, there are four inequivalent Rb1+ sites. In the first Rb1+ site, Rb1+ is bonded in a 5-coordinate geometry to four N3- and three H+0.47- atoms. There are a spread of Rb–N bond distances ranging from 3.09–3.41 Å. There are a spread of Rb–H bond distances ranging from 3.07–3.28 Å. In the second Rb1+ site, Rb1+ is bonded in a bent 150 degrees geometry to one N3- and one H+0.47- atom. The Rb–N bond length is 2.98 Å. The Rb–H bond length is 3.01 Å. In the third Rb1+ site, Rb1+ is bonded in a 1-coordinate geometry to three N3- and four H+0.47- atoms. There are one shorter (3.18 Å) and two longer (3.25 Å) Rb–N bond lengths. There are a spread of Rb–H bond distances ranging from 3.04–3.24 Å. In the fourth Rb1+ site, Rb1+ is bonded in a 3-coordinate geometry to one N3- and two H+0.47- atoms. The Rb–N bond length is 3.13 Å. There are one shorter (2.90 Å) and one longer (3.05 Å) Rb–H bond lengths. There are five inequivalent N3- sites. In the first N3- site, N3- is bonded in a trigonal non-coplanar geometry to two Rb1+ and three H+0.47- atoms. All N–H bond lengths are 1.03 Å. In the second N3- site, N3- is bonded in a trigonal non-coplanar geometry to one Rb1+ and three H+0.47- atoms. All N–H bond lengths are 1.03 Å. In the third N3- site, N3- is bonded in a trigonal non-coplanar geometry to one Rb1+ and three H+0.47- atoms. There is one shorter (1.02 Å) and two longer (1.03 Å) N–H bond length. In the fourth N3- site, N3- is bonded in a trigonal non-coplanar geometry to two Rb1+ and three H+0.47- atoms. All N–H bond lengths are 1.03 Å. In the fifth N3- site, N3- is bonded in a trigonal non-coplanar geometry to three Rb1+ and three H+0.47- atoms. There is one shorter (1.02 Å) and two longer (1.03 Å) N–H bond length. There are fifteen inequivalent H+0.47- sites. In the first H+0.47- site, H+0.47- is bonded in a single-bond geometry to one Rb1+ and one N3- atom. In the second H+0.47- site, H+0.47- is bonded in a single-bond geometry to one N3- atom. In the third H+0.47- site, H+0.47- is bonded in a single-bond geometry to one Rb1+ and one N3- atom. In the fourth H+0.47- site, H+0.47- is bonded in a single-bond geometry to one N3- atom. In the fifth H+0.47- site, H+0.47- is bonded in a single-bond geometry to one Rb1+ and one N3- atom. In the sixth H+0.47- site, H+0.47- is bonded in a single-bond geometry to one Rb1+ and one N3- atom. In the seventh H+0.47- site, H+0.47- is bonded in a single-bond geometry to one N3- atom. In the eighth H+0.47- site, H+0.47- is bonded in a single-bond geometry to one Rb1+ and one N3- atom. In the ninth H+0.47- site, H+0.47- is bonded in a single-bond geometry to two Rb1+ and one N3- atom. In the tenth H+0.47- site, H+0.47- is bonded in a single-bond geometry to one N3- atom. In the eleventh H+0.47- site, H+0.47- is bonded in a single-bond geometry to one Rb1+ and one N3- atom. In the twelfth H+0.47- site, H+0.47- is bonded in a single-bond geometry to one N3- atom. In the thirteenth H+0.47- site, H+0.47- is bonded in a single-bond geometry to one N3- atom. In the fourteenth H+0.47- site, H+0.47- is bonded in a single-bond geometry to one Rb1+ and one N3- atom. In the fifteenth H+0.47- site, H+0.47- is bonded in a single-bond geometry to one Rb1+ and one N3- atom.
Li(NH3)4Te is Silicon tetrafluoride-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one ditellurium molecule and two Li(NH3)4 clusters. In each Li(NH3)4 cluster, Li1+ is bonded in a tetrahedral geometry to four N3- atoms. There are a spread of Li–N bond distances ranging from 2.05–2.12 Å. There are four inequivalent N3- sites. In the first N3- site, N3- is bonded to one Li1+ and three H1+ atoms to form distorted corner-sharing NLiH3 tetrahedra. All N–H bond lengths are 1.03 Å. In the second N3- site, N3- is bonded to one Li1+ and three H1+ atoms to form distorted corner-sharing NLiH3 tetrahedra. There is one shorter (1.02 Å) and two longer (1.03 Å) N–H bond length. In the third N3- site, N3- is bonded to one Li1+ and three H1+ atoms to form distorted corner-sharing NLiH3 tetrahedra. All N–H bond lengths are 1.03 Å. In the fourth N3- site, N3- is bonded to one Li1+ and three H1+ atoms to form distorted corner-sharing NLiH3 tetrahedra. There is one shorter (1.02 Å) and two longer (1.03 Å) N–H bond length. There are twelve inequivalent H1+ sites. In the first H1+ site, H1+ is bonded in a single-bond geometry to one N3- atom. In the second H1+ site, H1+ is bonded in a single-bond geometry to one N3- atom. In the third H1+ site, H1+ is bonded in a single-bond geometry to one N3- atom. In the fourth H1+ site, H1+ is bonded in a single-bond geometry to one N3- atom. In the fifth H1+ site, H1+ is bonded in a single-bond geometry to one N3- atom. In the sixth H1+ site, H1+ is bonded in a single-bond geometry to one N3- atom. In the seventh H1+ site, H1+ is bonded in a single-bond geometry to one N3- atom. In the eighth H1+ site, H1+ is bonded in a single-bond geometry to one N3- atom. In the ninth H1+ site, H1+ is bonded in a single-bond geometry to one N3- atom. In the tenth H1+ site, H1+ is bonded in a single-bond geometry to one N3- atom. In the eleventh H1+ site, H1+ is bonded in a single-bond geometry to one N3- atom. In the twelfth H1+ site, H1+ is bonded in a single-bond geometry to one N3- atom.
NH3 is Ammonia-like structured and crystallizes in the cubic P2_13 space group. The structure is zero-dimensional and consists of four ammonia molecules. N3- is bonded in a trigonal non-coplanar geometry to three equivalent H1+ atoms. All N–H bond lengths are 1.02 Å. H1+ is bonded in a single-bond geometry to one N3- atom.
Mn(NH3)6(Te)4 crystallizes in the monoclinic P2_1/c space group. The structure is one-dimensional and consists of four Mn(NH3)6 clusters and two Te ribbons oriented in the (1, 0, 0) direction. In each Mn(NH3)6 cluster, Mn2+ is bonded in an octahedral geometry to six N3- atoms. There are a spread of Mn–N bond distances ranging from 2.24–2.30 Å. There are six inequivalent N3- sites. In the first N3- site, N3- is bonded in a distorted trigonal non-coplanar geometry to one Mn2+ and three H1+ atoms. All N–H bond lengths are 1.03 Å. In the second N3- site, N3- is bonded in a distorted trigonal non-coplanar geometry to one Mn2+ and three H1+ atoms. There is one shorter (1.02 Å) and two longer (1.03 Å) N–H bond length. In the third N3- site, N3- is bonded in a distorted trigonal non-coplanar geometry to one Mn2+ and three H1+ atoms. There is one shorter (1.02 Å) and two longer (1.03 Å) N–H bond length. In the fourth N3- site, N3- is bonded in a distorted trigonal non-coplanar geometry to one Mn2+ and three H1+ atoms. All N–H bond lengths are 1.03 Å. In the fifth N3- site, N3- is bonded in a distorted trigonal non-coplanar geometry to one Mn2+ and three H1+ atoms. All N–H bond lengths are 1.03 Å. In the sixth N3- site, N3- is bonded in a distorted trigonal non-coplanar geometry to one Mn2+ and three H1+ atoms. All N–H bond lengths are 1.03 Å. There are eighteen inequivalent H1+ sites. In the first H1+ site, H1+ is bonded in a single-bond geometry to one N3- atom. In the second H1+ site, H1+ is bonded in a single-bond geometry to one N3- atom. In the third H1+ site, H1+ is bonded in a single-bond geometry to one N3- atom. In the fourth H1+ site, H1+ is bonded in a single-bond geometry to one N3- atom. In the fifth H1+ site, H1+ is bonded in a single-bond geometry to one N3- atom. In the sixth H1+ site, H1+ is bonded in a single-bond geometry to one N3- atom. In the seventh H1+ site, H1+ is bonded in a single-bond geometry to one N3- atom. In the eighth H1+ site, H1+ is bonded in a single-bond geometry to one N3- atom. In the ninth H1+ site, H1+ is bonded in a single-bond geometry to one N3- atom. In the tenth H1+ site, H1+ is bonded in a single-bond geometry to one N3- atom. In the eleventh H1+ site, H1+ is bonded in a single-bond geometry to one N3- atom. In the twelfth H1+ site, H1+ is bonded in a single-bond geometry to one N3- atom. In the thirteenth H1+ site, H1+ is bonded in a single-bond geometry to one N3- atom. In the fourteenth H1+ site, H1+ is bonded in a single-bond geometry to one N3- atom. In the fifteenth H1+ site, H1+ is bonded in a single-bond geometry to one N3- atom. In the sixteenth H1+ site, H1+ is bonded in a single-bond geometry to one N3- atom. In the seventeenth H1+ site, H1+ is bonded in a single-bond geometry to one N3- atom. In the eighteenth H1+ site, H1+ is bonded in a single-bond geometry to one N3- atom. In each Te ribbon, there are four inequivalent Te+0.50- sites. In the first Te+0.50- site, Te+0.50- is bonded in a distorted water-like geometry to three Te+0.50- atoms. There are a spread of Te–Te bond distances ranging from 2.79–3.90 Å. In the second Te+0.50- site, Te+0.50- is bonded in a distorted linear geometry to two Te+0.50- atoms. There are one shorter (2.92 Å) and one longer (3.27 Å) Te–Te bond lengths. In the third Te+0.50- site, Te+0.50- is bonded in a distorted water-like geometry to two Te+0.50- atoms. In the fourth Te+0.50- site, Te+0.50- is bonded in a distorted water-like geometry to two Te+0.50- atoms.
Li(NH2)4BH4 crystallizes in the orthorhombic Pca2_1 space group. The structure is zero-dimensional and consists of four BH4 clusters and four Li(NH2)4 clusters. In each BH4 cluster, B3+ is bonded in a tetrahedral geometry to four H+0.67+ atoms. There is two shorter (1.23 Å) and two longer (1.24 Å) B–H bond length. There are four inequivalent H+0.67+ sites. In the first H+0.67+ site, H+0.67+ is bonded in a single-bond geometry to one B3+ atom. In the second H+0.67+ site, H+0.67+ is bonded in a single-bond geometry to one B3+ atom. In the third H+0.67+ site, H+0.67+ is bonded in a single-bond geometry to one B3+ atom. In the fourth H+0.67+ site, H+0.67+ is bonded in a single-bond geometry to one B3+ atom. In each Li(NH2)4 cluster, Li1+ is bonded in a distorted tetrahedral geometry to four N3- atoms. There are a spread of Li–N bond distances ranging from 2.06–2.14 Å. There are four inequivalent N3- sites. In the first N3- site, N3- is bonded in a distorted water-like geometry to one Li1+ and two H+0.67+ atoms. There is one shorter (1.02 Å) and one longer (1.03 Å) N–H bond length. In the second N3- site, N3- is bonded in a distorted water-like geometry to one Li1+ and two H+0.67+ atoms. Both N–H bond lengths are 1.03 Å. In the third N3- site, N3- is bonded in a distorted water-like geometry to one Li1+ and two H+0.67+ atoms. Both N–H bond lengths are 1.03 Å. In the fourth N3- site, N3- is bonded in a distorted water-like geometry to one Li1+ and two H+0.67+ atoms. Both N–H bond lengths are 1.03 Å. There are eight inequivalent H+0.67+ sites. In the first H+0.67+ site, H+0.67+ is bonded in a single-bond geometry to one N3- atom. In the second H+0.67+ site, H+0.67+ is bonded in a single-bond geometry to one N3- atom. In the third H+0.67+ site, H+0.67+ is bonded in a single-bond geometry to one N3- atom. In the fourth H+0.67+ site, H+0.67+ is bonded in a single-bond geometry to one N3- atom. In the fifth H+0.67+ site, H+0.67+ is bonded in a single-bond geometry to one N3- atom. In the sixth H+0.67+ site, H+0.67+ is bonded in a single-bond geometry to one N3- atom. In the seventh H+0.67+ site, H+0.67+ is bonded in a single-bond geometry to one N3- atom. In the eighth H+0.67+ site, H+0.67+ is bonded in a single-bond geometry to one N3- atom.
(Zn(NH3)4)2(Te)15 crystallizes in the monoclinic P2_1/c space group. The structure is three-dimensional and consists of four Zn(NH3)4 clusters and one Te framework. In each Zn(NH3)4 cluster, Zn2+ is bonded in a tetrahedral geometry to four N3- atoms. There are one shorter (2.03 Å) and three longer (2.04 Å) Zn–N bond lengths. There are four inequivalent N3- sites. In the first N3- site, N3- is bonded to one Zn2+ and three H1+ atoms to form distorted corner-sharing NZnH3 tetrahedra. All N–H bond lengths are 1.03 Å. In the second N3- site, N3- is bonded to one Zn2+ and three H1+ atoms to form distorted corner-sharing NZnH3 tetrahedra. All N–H bond lengths are 1.03 Å. In the third N3- site, N3- is bonded to one Zn2+ and three H1+ atoms to form distorted corner-sharing NZnH3 tetrahedra. All N–H bond lengths are 1.03 Å. In the fourth N3- site, N3- is bonded to one Zn2+ and three H1+ atoms to form distorted corner-sharing NZnH3 tetrahedra. All N–H bond lengths are 1.03 Å. There are twelve inequivalent H1+ sites. In the first H1+ site, H1+ is bonded in a single-bond geometry to one N3- atom. In the second H1+ site, H1+ is bonded in a single-bond geometry to one N3- atom. In the third H1+ site, H1+ is bonded in a single-bond geometry to one N3- atom. In the fourth H1+ site, H1+ is bonded in a single-bond geometry to one N3- atom. In the fifth H1+ site, H1+ is bonded in a single-bond geometry to one N3- atom. In the sixth H1+ site, H1+ is bonded in a single-bond geometry to one N3- atom. In the seventh H1+ site, H1+ is bonded in a single-bond geometry to one N3- atom. In the eighth H1+ site, H1+ is bonded in a single-bond geometry to one N3- atom. In the ninth H1+ site, H1+ is bonded in a single-bond geometry to one N3- atom. In the tenth H1+ site, H1+ is bonded in a single-bond geometry to one N3- atom. In the eleventh H1+ site, H1+ is bonded in a single-bond geometry to one N3- atom. In the twelfth H1+ site, H1+ is bonded in a single-bond geometry to one N3- atom. In the Te framework, there are eight inequivalent Te+0.27- sites. In the first Te+0.27- site, Te+0.27- is bonded in a 4-coordinate geometry to four Te+0.27- atoms. There are two shorter (3.10 Å) and two longer (3.33 Å) Te–Te bond lengths. In the second Te+0.27- site, Te+0.27- is bonded in a distorted single-bond geometry to one Te+0.27- atom. The Te–Te bond length is 2.82 Å. In the third Te+0.27- site, Te+0.27- is bonded in a 4-coordinate geometry to four Te+0.27- atoms. There are a spread of Te–Te bond distances ranging from 2.85–3.69 Å. In the fourth Te+0.27- site, Te+0.27- is bonded in a distorted water-like geometry to two Te+0.27- atoms. The Te–Te bond length is 2.80 Å. In the fifth Te+0.27- site, Te+0.27- is bonded in a 2-coordinate geometry to three Te+0.27- atoms. The Te–Te bond length is 2.89 Å. In the sixth Te+0.27- site, Te+0.27- is bonded in a 2-coordinate geometry to two Te+0.27- atoms. The Te–Te bond length is 2.89 Å. In the seventh Te+0.27- site, Te+0.27- is bonded in a distorted bent 120 degrees geometry to two Te+0.27- atoms. The Te–Te bond length is 2.82 Å. In the eighth Te+0.27- site, Te+0.27- is bonded in a 2-coordinate geometry to three Te+0.27- atoms.
BP(NH3)3 crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four BP(NH3)3 clusters. B3- is bonded in a distorted tetrahedral geometry to one P5+ and three H+0.78+ atoms. The B–P bond length is 1.89 Å. All B–H bond lengths are 1.22 Å. P5+ is bonded in a distorted tetrahedral geometry to one B3- and three N3- atoms. There is one shorter (1.67 Å) and two longer (1.68 Å) P–N bond length. There are three inequivalent N3- sites. In the first N3- site, N3- is bonded in a trigonal non-coplanar geometry to one P5+ and two H+0.78+ atoms. Both N–H bond lengths are 1.02 Å. In the second N3- site, N3- is bonded in a distorted trigonal non-coplanar geometry to one P5+ and two H+0.78+ atoms. Both N–H bond lengths are 1.02 Å. In the third N3- site, N3- is bonded in a distorted trigonal planar geometry to one P5+ and two H+0.78+ atoms. Both N–H bond lengths are 1.02 Å. There are nine inequivalent H+0.78+ sites. In the first H+0.78+ site, H+0.78+ is bonded in a single-bond geometry to one B3- atom. In the second H+0.78+ site, H+0.78+ is bonded in a single-bond geometry to one B3- atom. In the third H+0.78+ site, H+0.78+ is bonded in a single-bond geometry to one B3- atom. In the fourth H+0.78+ site, H+0.78+ is bonded in a single-bond geometry to one N3- atom. In the fifth H+0.78+ site, H+0.78+ is bonded in a single-bond geometry to one N3- atom. In the sixth H+0.78+ site, H+0.78+ is bonded in a single-bond geometry to one N3- atom. In the seventh H+0.78+ site, H+0.78+ is bonded in a single-bond geometry to one N3- atom. In the eighth H+0.78+ site, H+0.78+ is bonded in a single-bond geometry to one N3- atom. In the ninth H+0.78+ site, H+0.78+ is bonded in a single-bond geometry to one N3- atom.
(Li(NH3)4)2(P)7NH3 crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two ammonia molecules, fourteen phosphine molecules, and four Li(NH3)4 clusters. In two of the Li(NH3)4 clusters, Li1+ is bonded in a tetrahedral geometry to four N3- atoms. There are a spread of Li–N bond distances ranging from 2.07–2.09 Å. There are four inequivalent N3- sites. In the first N3- site, N3- is bonded to one Li1+ and three H+0.78+ atoms to form distorted corner-sharing NLiH3 tetrahedra. There is one shorter (1.02 Å) and two longer (1.03 Å) N–H bond length. In the second N3- site, N3- is bonded to one Li1+ and three H+0.78+ atoms to form distorted corner-sharing NLiH3 tetrahedra. There is one shorter (1.02 Å) and two longer (1.03 Å) N–H bond length. In the third N3- site, N3- is bonded to one Li1+ and three H+0.78+ atoms to form distorted corner-sharing NLiH3 tetrahedra. There is two shorter (1.02 Å) and one longer (1.03 Å) N–H bond length. In the fourth N3- site, N3- is bonded to one Li1+ and three H+0.78+ atoms to form distorted corner-sharing NLiH3 tetrahedra. There is one shorter (1.02 Å) and two longer (1.03 Å) N–H bond length. There are twelve inequivalent H+0.78+ sites. In the first H+0.78+ site, H+0.78+ is bonded in a single-bond geometry to one N3- atom. In the second H+0.78+ site, H+0.78+ is bonded in a single-bond geometry to one N3- atom. In the third H+0.78+ site, H+0.78+ is bonded in a single-bond geometry to one N3- atom. In the fourth H+0.78+ site, H+0.78+ is bonded in a single-bond geometry to one N3- atom. In the fifth H+0.78+ site, H+0.78+ is bonded in a single-bond geometry to one N3- atom. In the sixth H+0.78+ site, H+0.78+ is bonded in a single-bond geometry to one N3- atom. In the seventh H+0.78+ site, H+0.78+ is bonded in a single-bond geometry to one N3- atom. In the eighth H+0.78+ site, H+0.78+ is bonded in a single-bond geometry to one N3- atom. In the ninth H+0.78+ site, H+0.78+ is bonded in a single-bond geometry to one N3- atom. In the tenth H+0.78+ site, H+0.78+ is bonded in a single-bond geometry to one N3- atom. In the eleventh H+0.78+ site, H+0.78+ is bonded in a single-bond geometry to one N3- atom. In the twelfth H+0.78+ site, H+0.78+ is bonded in a single-bond geometry to one N3- atom. In two of the Li(NH3)4 clusters, Li1+ is bonded in a tetrahedral geometry to four N3- atoms. There are two shorter (2.06 Å) and two longer (2.08 Å) Li–N bond lengths. There are four inequivalent N3- sites. In the first N3- site, N3- is bonded to one Li1+ and three H+0.78+ atoms to form distorted corner-sharing NLiH3 tetrahedra. There is one shorter (1.02 Å) and two longer (1.03 Å) N–H bond length. In the second N3- site, N3- is bonded to one Li1+ and three H+0.78+ atoms to form distorted corner-sharing NLiH3 tetrahedra. There is two shorter (1.02 Å) and one longer (1.03 Å) N–H bond length. In the third N3- site, N3- is bonded to one Li1+ and three H+0.78+ atoms to form distorted corner-sharing NLiH3 tetrahedra. There is two shorter (1.02 Å) and one longer (1.03 Å) N–H bond length. In the fourth N3- site, N3- is bonded to one Li1+ and three H+0.78+ atoms to form distorted corner-sharing NLiH3 tetrahedra. There is two shorter (1.02 Å) and one longer (1.03 Å) N–H bond length. There are twelve inequivalent H+0.78+ sites. In the first H+0.78+ site, H+0.78+ is bonded in a single-bond geometry to one N3- atom. In the second H+0.78+ site, H+0.78+ is bonded in a single-bond geometry to one N3- atom. In the third H+0.78+ site, H+0.78+ is bonded in a single-bond geometry to one N3- atom. In the fourth H+0.78+ site, H+0.78+ is bonded in a single-bond geometry to one N3- atom. In the fifth H+0.78+ site, H+0.78+ is bonded in a single-bond geometry to one N3- atom. In the sixth H+0.78+ site, H+0.78+ is bonded in a single-bond geometry to one N3- atom. In the seventh H+0.78+ site, H+0.78+ is bonded in a single-bond geometry to one N3- atom. In the eighth H+0.78+ site, H+0.78+ is bonded in a single-bond geometry to one N3- atom. In the ninth H+0.78+ site, H+0.78+ is bonded in a single-bond geometry to one N3- atom. In the tenth H+0.78+ site, H+0.78+ is bonded in a single-bond geometry to one N3- atom. In the eleventh H+0.78+ site, H+0.78+ is bonded in a single-bond geometry to one N3- atom. In the twelfth H+0.78+ site, H+0.78+ is bonded in a single-bond geometry to one N3- atom.
Cs3P11(NH3)3 crystallizes in the monoclinic P2_1/c space group. The structure is three-dimensional. there are three inequivalent Cs1+ sites. In the first Cs1+ site, Cs1+ is bonded in a 2-coordinate geometry to four P+0.09-, one N3-, and one H+0.78+ atom. There are a spread of Cs–P bond distances ranging from 3.75–4.06 Å. The Cs–N bond length is 3.09 Å. The Cs–H bond length is 3.31 Å. In the second Cs1+ site, Cs1+ is bonded in a 9-coordinate geometry to eight P+0.09- and one N3- atom. There are a spread of Cs–P bond distances ranging from 3.74–4.06 Å. The Cs–N bond length is 3.55 Å. In the third Cs1+ site, Cs1+ is bonded in a 2-coordinate geometry to seven P+0.09-, one N3-, and three H+0.78+ atoms. There are a spread of Cs–P bond distances ranging from 3.66–4.09 Å. The Cs–N bond length is 3.14 Å. There are a spread of Cs–H bond distances ranging from 3.02–3.45 Å. There are eleven inequivalent P+0.09- sites. In the first P+0.09- site, P+0.09- is bonded in a 6-coordinate geometry to three Cs1+ and three P+0.09- atoms. There are a spread of P–P bond distances ranging from 2.17–2.26 Å. In the second P+0.09- site, P+0.09- is bonded in a 5-coordinate geometry to two Cs1+ and three P+0.09- atoms. There are a spread of P–P bond distances ranging from 2.17–2.26 Å. In the third P+0.09- site, P+0.09- is bonded to three Cs1+ and two P+0.09- atoms to form a mixture of distorted edge and corner-sharing PCs3P2 square pyramids. There are one shorter (2.17 Å) and one longer (2.18 Å) P–P bond lengths. In the fourth P+0.09- site, P+0.09- is bonded to two equivalent Cs1+ and three P+0.09- atoms to form distorted PCs2P3 trigonal bipyramids that share a cornercorner with one PCs3P2 square pyramid, an edgeedge with one PCs3P2 square pyramid, and an edgeedge with one PCs2P3 trigonal bipyramid. There are a spread of P–P bond distances ranging from 2.17–2.27 Å. In the fifth P+0.09- site, P+0.09- is bonded in a 3-coordinate geometry to one Cs1+ and three P+0.09- atoms. There are one shorter (2.18 Å) and one longer (2.27 Å) P–P bond lengths. In the sixth P+0.09- site, P+0.09- is bonded in a 2-coordinate geometry to two Cs1+ and two P+0.09- atoms. In the seventh P+0.09- site, P+0.09- is bonded in a 3-coordinate geometry to one Cs1+ and three P+0.09- atoms. The P–P bond length is 2.28 Å. In the eighth P+0.09- site, P+0.09- is bonded in a distorted trigonal non-coplanar geometry to three P+0.09- atoms. In the ninth P+0.09- site, P+0.09- is bonded in a 4-coordinate geometry to one Cs1+ and three P+0.09- atoms. The P–P bond length is 2.27 Å. In the tenth P+0.09- site, P+0.09- is bonded in a 4-coordinate geometry to three Cs1+ and two P+0.09- atoms. In the eleventh P+0.09- site, P+0.09- is bonded in a 4-coordinate geometry to one Cs1+ and three P+0.09- atoms. There are three inequivalent N3- sites. In the first N3- site, N3- is bonded in a trigonal non-coplanar geometry to one Cs1+ and three H+0.78+ atoms. There is one shorter (1.02 Å) and two longer (1.03 Å) N–H bond length. In the second N3- site, N3- is bonded in a trigonal non-coplanar geometry to one Cs1+ and three H+0.78+ atoms. There is two shorter (1.02 Å) and one longer (1.03 Å) N–H bond length. In the third N3- site, N3- is bonded in a trigonal non-coplanar geometry to one Cs1+ and three H+0.78+ atoms. There is one shorter (1.02 Å) and two longer (1.03 Å) N–H bond length. There are nine inequivalent H+0.78+ sites. In the first H+0.78+ site, H+0.78+ is bonded in a single-bond geometry to one N3- atom. In the second H+0.78+ site, H+0.78+ is bonded in a single-bond geometry to one Cs1+ and one N3- atom. In the third H+0.78+ site, H+0.78+ is bonded in a single-bond geometry to two Cs1+ and one N3- atom. In the fourth H+0.78+ site, H+0.78+ is bonded in a single-bond geometry to one N3- atom. In the fifth H+0.78+ site, H+0.78+ is bonded in a single-bond geometry to one N3- atom. In the sixth H+0.78+ site, H+0.78+ is bonded in a single-bond geometry to one N3- atom. In the seventh H+0.78+ site, H+0.78+ is bonded in a single-bond geometry to one Cs1+ and one N3- atom. In the eighth H+0.78+ site, H+0.78+ is bonded in a single-bond geometry to one N3- atom. In the ninth H+0.78+ site, H+0.78+ is bonded in a single-bond geometry to one N3- atom.
Cs3Ge9(NH3)2 crystallizes in the monoclinic P2_1/c space group. The structure is three-dimensional. there are three inequivalent Cs sites. In the first Cs site, Cs is bonded in a 5-coordinate geometry to five Ge atoms. There are a spread of Cs–Ge bond distances ranging from 3.83–4.22 Å. In the second Cs site, Cs is bonded in a 1-coordinate geometry to six Ge and one N atom. There are a spread of Cs–Ge bond distances ranging from 3.88–4.34 Å. The Cs–N bond length is 3.39 Å. In the third Cs site, Cs is bonded in a 1-coordinate geometry to two Ge and one N atom. There are one shorter (3.94 Å) and one longer (4.03 Å) Cs–Ge bond lengths. The Cs–N bond length is 3.21 Å. There are nine inequivalent Ge sites. In the first Ge site, Ge is bonded in a 6-coordinate geometry to one Cs and five Ge atoms. There are a spread of Ge–Ge bond distances ranging from 2.56–2.68 Å. In the second Ge site, Ge is bonded in a 7-coordinate geometry to two Cs and five Ge atoms. There are a spread of Ge–Ge bond distances ranging from 2.62–2.81 Å. In the third Ge site, Ge is bonded in a 5-coordinate geometry to one Cs and four Ge atoms. There are a spread of Ge–Ge bond distances ranging from 2.63–2.69 Å. In the fourth Ge site, Ge is bonded in a 5-coordinate geometry to one Cs and four Ge atoms. The Ge–Ge bond length is 2.59 Å. In the fifth Ge site, Ge is bonded in a 5-coordinate geometry to one Cs and four Ge atoms. There are two shorter (2.61 Å) and one longer (2.63 Å) Ge–Ge bond lengths. In the sixth Ge site, Ge is bonded in a 7-coordinate geometry to two Cs and five Ge atoms. There are a spread of Ge–Ge bond distances ranging from 2.57–2.88 Å. In the seventh Ge site, Ge is bonded in a 7-coordinate geometry to two Cs and five Ge atoms. In the eighth Ge site, Ge is bonded in a distorted pentagonal bipyramidal geometry to three Cs and four Ge atoms. The Ge–Ge bond length is 2.68 Å. In the ninth Ge site, Ge is bonded in a 5-coordinate geometry to five Ge atoms. There are two inequivalent N sites. In the first N site, N is bonded in a trigonal non-coplanar geometry to one Cs and three H atoms. All N–H bond lengths are 1.03 Å. In the second N site, N is bonded in a trigonal non-coplanar geometry to one Cs and three H atoms. All N–H bond lengths are 1.03 Å. There are six inequivalent H sites. In the first H site, H is bonded in a single-bond geometry to one N atom. In the second H site, H is bonded in a single-bond geometry to one N atom. In the third H site, H is bonded in a single-bond geometry to one N atom. In the fourth H site, H is bonded in a single-bond geometry to one N atom. In the fifth H site, H is bonded in a single-bond geometry to one N atom. In the sixth H site, H is bonded in a single-bond geometry to one N atom.