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(NH4)2H2OSO3 crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of eight ammonium molecules, four sulfur trioxide molecules, and four water molecules.
NH3NH7O2SO2 crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four ammonia molecules, four azanium;dihydrate molecules, and four sulfur dioxide molecules.