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Results for “H-Rb-S”

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DOE OSTI2020

Materials Data on RbHS by Materials Project

RbSH crystallizes in the monoclinic C2 space group. The structure is two-dimensional and consists of two RbSH sheets oriented in the (1, 0, 0) direction. Rb1+ is bonded in a 1-coordinate geometry to two equivalent H1+ atoms. There are one shorter (2.85 Å) and one longer (3.15 Å) Rb–H bond lengths. H1+ is bonded in a 4-coordinate geometry to two equivalent Rb1+ and two equivalent S2- atoms. Both H–S bond lengths are 1.69 Å. S2- is bonded in a distorted linear geometry to two equivalent H1+ atoms.

36 MATERIALS SCIENCE↗

DOE OSTI2020

Materials Data on RbHS by Materials Project

RbSH crystallizes in the monoclinic P2_1/m space group. The structure is three-dimensional. Rb1+ is bonded in a 6-coordinate geometry to three equivalent H1+ and six equivalent S2- atoms. All Rb–H bond lengths are 3.14 Å. There are a spread of Rb–S bond distances ranging from 3.44–3.56 Å. H1+ is bonded in a single-bond geometry to three equivalent Rb1+ and one S2- atom. The H–S bond length is 1.35 Å. S2- is bonded in a distorted single-bond geometry to six equivalent Rb1+ and one H1+ atom.

36 MATERIALS SCIENCE↗