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Study of nanodiamond photocathodes for MPGD-based detectors of single photons

The proposed new Electron–Ion Collider poses a technical and intellectual challenge for the detector design to accommodate the long-term diverse physics goals envisaged by the program. This requires a 4π detector system capable of reconstructing the energy and momentum of final state particles with high precision. The Electron-Ion Collider also requires identification of particles of different masses over a wide momentum range. A diverse spectrum of Particle IDentification detectors has been proposed. Of the four types of detectors for hadron identification, three are based on Ring Imaging Cherenkov Counter technologies, and one is realized by the Time of Flight method. The quest for a novel photocathode, sensitive in the far vacuum ultraviolet wavelength range and more robust than cesium iodide, motivated an R&D programme to explore nano-diamond (ND) based photocathodes, started by a collaboration between INFN and CNR Bari and INFN Trieste. Systematic measurements of the photoemission in different Ar:CH 4 and Ar:CO 2 gas mixtures with various types of ND powders and Hydrogenated ND (H-ND) powders are reported. A first study of the response of THGEMs coated with different photocathode materials is presented. Additionally, the progress of this R&D programme and the results obtained so far by these exploratory studies are described.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Materials Data on NdH2 by Materials Project

NdH2 is Fluorite structured and crystallizes in the cubic Fm-3m space group. The structure is three-dimensional. Nd2+ is bonded in a body-centered cubic geometry to eight equivalent H1- atoms. All Nd–H bond lengths are 2.38 Å. H1- is bonded to four equivalent Nd2+ atoms to form a mixture of corner and edge-sharing HNd4 tetrahedra.

36 MATERIALS SCIENCE↗

Materials Data on Nd2H5 by Materials Project

Nd2H5 crystallizes in the tetragonal I4_1md space group. The structure is three-dimensional. there are two inequivalent Nd+2.50+ sites. In the first Nd+2.50+ site, Nd+2.50+ is bonded in a distorted body-centered cubic geometry to eleven H1- atoms. There are a spread of Nd–H bond distances ranging from 2.33–2.74 Å. In the second Nd+2.50+ site, Nd+2.50+ is bonded in a distorted body-centered cubic geometry to eleven H1- atoms. There are a spread of Nd–H bond distances ranging from 2.33–2.71 Å. There are two inequivalent H1- sites. In the first H1- site, H1- is bonded to four Nd+2.50+ atoms to form HNd4 tetrahedra that share corners with six equivalent HNd6 octahedra, corners with sixteen equivalent HNd4 tetrahedra, edges with six equivalent HNd4 tetrahedra, and faces with two equivalent HNd6 octahedra. The corner-sharing octahedra tilt angles range from 52–58°. In the second H1- site, H1- is bonded to six Nd+2.50+ atoms to form HNd6 octahedra that share corners with four equivalent HNd6 octahedra, corners with twenty-four equivalent HNd4 tetrahedra, edges with four equivalent HNd6 octahedra, and faces with eight equivalent HNd4 tetrahedra. The corner-sharing octahedra tilt angles range from 1–2°.

36 MATERIALS SCIENCE↗