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International Symposium on Combustion, 14th, Pennsylvania State University, University Park, Pa., August 20-25, 1972, Proceedings.

Some elementary steps for the formation and destruction of nitric oxide in the H-N-O system, high-temperature oxidation of hydrogen by nitrous oxide in shock waves, and high-temperature fast-flow reactor studies of metal-atom oxidation kinetics are among the topics covered in papers concerned with elementary reactions in combustion. Other areas covered include oscillatory, turbulent, and supersonic combustion; flames in furnaces and combustors; and pollutant formation and destruction in flames. Individual items are announced in this issue.

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Materials Data on H4N2O3 by Materials Project

NH4NO3 crystallizes in the orthorhombic Pmmn space group. The structure is zero-dimensional and consists of two ammonium molecules and two nitric acid molecules.

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Materials Data on H2NO2 by Materials Project

NH2O2 crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four NH2O2 clusters. there are two inequivalent N sites. In the first N site, N is bonded in a trigonal planar geometry to three O atoms. There is one shorter (1.25 Å) and two longer (1.28 Å) N–O bond length. In the second N site, N is bonded in a tetrahedral geometry to three H and one O atom. There is one shorter (1.04 Å) and two longer (1.05 Å) N–H bond length. The N–O bond length is 1.42 Å. There are four inequivalent H sites. In the first H site, H is bonded in a single-bond geometry to two O atoms. There is one shorter (1.01 Å) and one longer (1.72 Å) H–O bond length. In the second H site, H is bonded in a single-bond geometry to one N atom. In the third H site, H is bonded in a single-bond geometry to one N atom. In the fourth H site, H is bonded in a single-bond geometry to one N atom. There are four inequivalent O sites. In the first O site, O is bonded in a distorted bent 120 degrees geometry to one N and one H atom. In the second O site, O is bonded in a single-bond geometry to one N atom. In the third O site, O is bonded in a water-like geometry to one N and one H atom. In the fourth O site, O is bonded in a single-bond geometry to one N atom.

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Materials Data on H5(NO)3 by Materials Project

N2H5NO3 crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four ammonia molecules, four ammonia molecules, and four nitric acid molecules.

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Materials Data on H5NO2 by Materials Project

NH(H2O)2 crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four ammonia molecules and eight water molecules.

36 MATERIALS SCIENCE↗

Materials Data on H5NO2 by Materials Project

NH(H2O)2 is Magnesium tetraboride-derived structured and crystallizes in the monoclinic Pc space group. The structure is zero-dimensional and consists of four ammonia molecules and eight water molecules.

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Materials Data on HNO by Materials Project

NHO crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four 1,1-dihydroxyhydrazine molecules. there are two inequivalent N1+ sites. In the first N1+ site, N1+ is bonded in a 3-coordinate geometry to one N1+ and two equivalent O2- atoms. The N–N bond length is 1.17 Å. Both N–O bond lengths are 1.45 Å. In the second N1+ site, N1+ is bonded in a single-bond geometry to one N1+ atom. H1+ is bonded in a single-bond geometry to one O2- atom. The H–O bond length is 0.99 Å. O2- is bonded in a distorted water-like geometry to one N1+ and one H1+ atom.

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Materials Data on HNO by Materials Project

NHO crystallizes in the monoclinic Cc space group. The structure is one-dimensional and consists of two NHO ribbons oriented in the (1, 0, 1) direction. there are two inequivalent N1+ sites. In the first N1+ site, N1+ is bonded in a 2-coordinate geometry to one N1+ and two O2- atoms. The N–N bond length is 1.19 Å. There is one shorter (1.40 Å) and one longer (1.42 Å) N–O bond length. In the second N1+ site, N1+ is bonded in a distorted bent 120 degrees geometry to one N1+ and one H1+ atom. The N–H bond length is 1.79 Å. There are two inequivalent H1+ sites. In the first H1+ site, H1+ is bonded in a single-bond geometry to one O2- atom. The H–O bond length is 0.99 Å. In the second H1+ site, H1+ is bonded in a single-bond geometry to one N1+ and one O2- atom. The H–O bond length is 1.01 Å. There are two inequivalent O2- sites. In the first O2- site, O2- is bonded in a distorted water-like geometry to one N1+ and one H1+ atom. In the second O2- site, O2- is bonded in a distorted water-like geometry to one N1+ and one H1+ atom.

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Materials Data on H4N2O3 by Materials Project

NH4NO3 crystallizes in the monoclinic C2 space group. The structure is zero-dimensional and consists of two ammonia molecules; two hydroxylamine, n-hydroxy- molecules; and two water molecules.

36 MATERIALS SCIENCE↗

Materials Data on H4N2O3 by Materials Project

NH4NO3 crystallizes in the monoclinic C2 space group. The structure is zero-dimensional and consists of two ammonia molecules, two nitrous acid molecules, and two water molecules.

36 MATERIALS SCIENCE↗

Materials Data on H4N2O3 by Materials Project

NH4NO3 crystallizes in the orthorhombic Pna2_1 space group. The structure is zero-dimensional and consists of four ammonia molecules and four ncimech_000224 molecules.

36 MATERIALS SCIENCE↗

Materials Data on H5NO by Materials Project

NH4OH is alpha Np structured and crystallizes in the orthorhombic P2_12_12_1 space group. The structure is zero-dimensional and consists of four ammonia molecules and four water molecules.

36 MATERIALS SCIENCE↗

Materials Data on H4N2O3 by Materials Project

NH4NO3 crystallizes in the orthorhombic Pmmn space group. The structure is one-dimensional and consists of two NH4NO3 ribbons oriented in the (1, 0, 0) direction. there are two inequivalent N1+ sites. In the first N1+ site, N1+ is bonded in a rectangular see-saw-like geometry to four H1+ atoms. There is two shorter (1.05 Å) and two longer (1.11 Å) N–H bond length. In the second N1+ site, N1+ is bonded in a trigonal planar geometry to three O2- atoms. There is two shorter (1.26 Å) and one longer (1.28 Å) N–O bond length. There are two inequivalent H1+ sites. In the first H1+ site, H1+ is bonded in a single-bond geometry to one N1+ atom. In the second H1+ site, H1+ is bonded in a linear geometry to one N1+ and one O2- atom. The H–O bond length is 1.51 Å. There are two inequivalent O2- sites. In the first O2- site, O2- is bonded in a single-bond geometry to one N1+ atom. In the second O2- site, O2- is bonded in a bent 150 degrees geometry to one N1+ and one H1+ atom.

36 MATERIALS SCIENCE↗

Materials Data on H3NO4 by Materials Project

NH3O4 crystallizes in the orthorhombic Pna2_1 space group. The structure is two-dimensional and consists of two NH3O4 sheets oriented in the (0, 1, 0) direction. N5+ is bonded in a trigonal planar geometry to three O2- atoms. All N–O bond lengths are 1.27 Å. There are three inequivalent H1+ sites. In the first H1+ site, H1+ is bonded in a linear geometry to two O2- atoms. There is one shorter (1.04 Å) and one longer (1.51 Å) H–O bond length. In the second H1+ site, H1+ is bonded in a linear geometry to two O2- atoms. There is one shorter (1.03 Å) and one longer (1.57 Å) H–O bond length. In the third H1+ site, H1+ is bonded in a linear geometry to two O2- atoms. There is one shorter (1.03 Å) and one longer (1.56 Å) H–O bond length. There are four inequivalent O2- sites. In the first O2- site, O2- is bonded in a bent 120 degrees geometry to one N5+ and one H1+ atom. In the second O2- site, O2- is bonded in a bent 120 degrees geometry to one N5+ and one H1+ atom. In the third O2- site, O2- is bonded in a bent 120 degrees geometry to one N5+ and one H1+ atom. In the fourth O2- site, O2- is bonded in a trigonal non-coplanar geometry to three H1+ atoms.

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Materials Data on H3NO by Materials Project

NH2OH crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of two ammonia molecules, one hydrogen molecule, one nitrogen molecule, and four water molecules.

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Materials Data on H4N2O3 by Materials Project

NH4NO3 is Tetraauricupride structured and crystallizes in the tetragonal P-42_1m space group. The structure is zero-dimensional and consists of two ammonium molecules and two nitric acid molecules.

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Materials Data on H4N2O3 by Materials Project

NH4NO3 crystallizes in the orthorhombic Pmmn space group. The structure is zero-dimensional and consists of two ammonium molecules and two nitric acid molecules.

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Materials Data on H8(NO2)3 by Materials Project

(NH4)4(NO3)2(O2)3 crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of two ammonium molecules, one peroxynitrous acid molecule, and one trioxidane molecule.

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