Materials Data on GeN2OF6 by Materials Project
N2GeOF6 crystallizes in the cubic Fm-3m space group. The structure is three-dimensional and consists of eight ammonia molecules and one GeOF6 framework. In the GeOF6 framework, Ge4+ is bonded to six equivalent F1- atoms to form GeF6 octahedra that share corners with six equivalent OF6 octahedra. The corner-sharing octahedral tilt angles are 0°. All Ge–F bond lengths are 1.84 Å. O2- is bonded to six equivalent F1- atoms to form OF6 octahedra that share corners with six equivalent GeF6 octahedra. The corner-sharing octahedral tilt angles are 0°. All O–F bond lengths are 2.26 Å. F1- is bonded in a distorted linear geometry to one Ge4+ and one O2- atom.
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