Materials Data on Ge3O by Materials Project
(Ge)2GeO crystallizes in the tetragonal I4/mmm space group. The structure is two-dimensional and consists of two Ge sheets oriented in the (0, 0, 1) direction and two GeO sheets oriented in the (0, 0, 1) direction. In each Ge sheet, Ge is bonded in a distorted square co-planar geometry to four equivalent Ge atoms. All Ge–Ge bond lengths are 2.60 Å. In each GeO sheet, Ge is bonded in a distorted square co-planar geometry to four equivalent O atoms. All Ge–O bond lengths are 2.60 Å. O is bonded in a square co-planar geometry to four equivalent Ge atoms.