Materials Data on Ge3(MoO6)2 by Materials Project
Ge3(MoO6)2 crystallizes in the cubic Ia-3d space group. The structure is three-dimensional. Mo6+ is bonded to six equivalent O2- atoms to form MoO6 octahedra that share corners with six equivalent GeO4 tetrahedra. All Mo–O bond lengths are 1.94 Å. Ge4+ is bonded to four equivalent O2- atoms to form GeO4 tetrahedra that share corners with four equivalent MoO6 octahedra. The corner-sharing octahedral tilt angles are 42°. All Ge–O bond lengths are 1.77 Å. O2- is bonded in a distorted bent 150 degrees geometry to one Mo6+ and one Ge4+ atom.