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LiHg2Ga crystallizes in the orthorhombic Immm space group. The structure is one-dimensional and consists of two LiHg2Ga ribbons oriented in the (0, 1, 0) direction. Li is bonded in a linear geometry to two equivalent Hg atoms. Both Li–Hg bond lengths are 2.70 Å. Hg is bonded in a linear geometry to one Li and one Ga atom. The Hg–Ga bond length is 2.84 Å. Ga is bonded in a linear geometry to two equivalent Hg atoms.
Li2HgGa crystallizes in the orthorhombic Immm space group. The structure is one-dimensional and consists of two Li2HgGa ribbons oriented in the (0, 1, 0) direction. Li is bonded in a linear geometry to one Hg and one Ga atom. The Li–Hg bond length is 2.85 Å. The Li–Ga bond length is 2.72 Å. Hg is bonded in a linear geometry to two equivalent Li atoms. Ga is bonded in a linear geometry to two equivalent Li atoms.